Multifunctional formaldehyde resins as curing agent for epoxy resins

Formaldehyde resins (FR) at 1/1/2 molar ratios of monomers (Cl‐phenol/amino monomers/p‐formaldehyde) were synthesized under acid catalysis. The obtained resins were characterized using elemental analysis, FTIR and RMN spectroscopic methods, being used as crosslinking agents for epoxy resin formulations. The curing of epoxy resins with FR were investigated. The glass transition temperature (T_g) and decomposition behavior of crosslinked resins were studied by differential scanning calorimetry (DSC) and thermogravimetric (TGA) techniques. All DSC scans show two exothermic peaks, which implied the occurrence of cure reactions between epoxy ring and amine or carboxylic protons, in function of chemical structures of FR. The crosslinked products showed good thermal properties, high glass transitions, and low water absorption. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Phosphine functionalized polyaniline nanostructures

We study the problem of limited functionalization options for polyaniline through the surface attachment of phosphine coupling reagents. These studied linkers are P(CH₂OH)₃ and Ph₂PCH₂OH, and are attached to both conventional and nanostructured polyaniline. Additionally, model compounds are considered, extending the scope of our analysis. The successful attachment results indicate the potential for further functionalization, using the hydroxymethyl terminal groups of the phosphines for primary and secondary amine chemistry. These results should enable the development of sensitive and molecule-specific polyaniline-based devices.     

X-ray microbeam transmission/fluorescence method for non-destructive characterization of tungsten coated carbon materials

Tungsten erosion, its subsequent transport and redeposition are of great interest, because a full tungsten divertor is foreseen to be used during the deuterium–tritium operational phase of ITER. The erosion of tungsten and carbon marker layers was extensively studied in the outer divertor of ASDEX Upgrade (AUG), and work is currently in progress to completely replace the existing JET CFC tiles with tungsten-coated tiles within the JET ITER-like wall project. The need for fast and non-destructive method which allows the quantitative determination of the thickness of a tungsten coating on a carbon material on large areas led us to evaluate a combined absorption/fluorescence X-ray (XRTF) technique. The method can provide fast analysis, high spatial resolution and a material selective detection of deposited layers and inclusions. It was applied on W coated fine grain graphite (FGG) tiles from AUG's divertor. It is proved that the method is able to provide information about the uniformity of the tungsten coating on a graphite or CFC substrate whilst the technique can be used to determine the thickness of the tungsten and other marker materials coatings. It represents a unique instrument for the post-mortem analysis of the coatings.     

Polyethylene as an Additive for Mineral Oils — Part II: EHL Traction Behavior

In Part I of the paper ((1999), Trib. Trans., 42, pp. 851–859) we investigated the effect of the polyethylene concentration on the film forming properties in a rolling bearing. This second part presents the influence of the polymer additive concentration on the traction behavior experienced using a two-disk machine at different temperatures and contact pressures.

By using the traction data, a semi-empirical approach for determining the effective lubricant theological parameters in EHL contacts was performed. Using this approach, the effect of polymer concentration upon rheological parameters that appear in the Johnson and Tevaarwerk model with Eyring stress was quantified.     

Microwave-Assisted Synthesis of Phenothiazine and Quinoline Derivatives

Application of a dynamic microwave power system in the chemical synthesis of some phenothiazine and quinoline derivatives is described. Heterocyclic ring formation, aromatic nucleophilic substitution and heterocyclic aldehydes/ketones condensation reactions were performed on solid support, or under solvent free reaction conditions. The microwave-assisted Duff formylation of phenothiazine was achieved. Comparison of microwave-assisted synthesis with the conventional synthetic methods demonstrates advantages related to shorter reaction times and in some cases better reaction yields.     

Evaluation of the biocompatibility of resin composite‐based dental materials with gingival mesenchymal stromal cells

Resin composite‐based dental materials can leach certain components into the oral environment, causing potentially harmful gingival biological effect. Gingival tissue is a rich source of mesenchymal stem cells (MSCs) that is easily accessible, and can be used as a complementary approach for the investigation of dental material biocompatibility. Using gingival MSCs (gMSCs), the present study aimed to investigate the cytotoxicity of two classes of restorative dental materials (ormocers and resin composites) used to restore class II cavities close to the gingival margin, in addition to analyzing the leached compounds from these resin composite‐based materials. Functionality assays (Colony‐forming unit, migratory potential, and proliferation assays) and a viability assay (MTT) were employed. Cells' aspect was observed by scanning electron microscopy (SEM). Leached monomers were also quantitated using high‐performance liquid chromatography (HPLC). The cytotoxicity of the biomaterials was highlighted by impaired functionality and diminished viability of gMSCs. Despite being variants of the same commercial material, the two ormocers behaved differently one material having a more negative impact on cell functionality than the other. Cells appeared to attach well to all materials. Main monomer molecules were mostly released by the tested materials. For all samples, an increased elution of monomers was recorded in artificial saliva as compared with culture medium. One composite material has released nearly eight times more urethane dimetacrylate in artificial saliva than in culture medium. Significantly lower gMSC viability scores were recorded for all the investigated samples in comparison with the control.     

3D reconstruction of existing concrete bridges using optical methods

Routine bridge inspections usually consist of visual observations. These inspections are time-consuming and subjective. There is a need to identify new inspection techniques for infrastructure that reduce traffic disturbance, and improve the efficiency and reliability of the acquired data. This study compared the performance of three different imaging technologies for the three-dimensional (3D) geometric modeling of existing structures: terrestrial laser scanning, close-range photogrammetry, and infrared scanning. Each technology was used to assess six existing concrete railway bridges. The technologies were compared in terms of geometric deviations, visualization capabilities, the level of the inspector’s experience, and degree of automation. The results suggest that all methods investigated can be used to create 3D models, however, with different level of completeness. Measurements such as span length, deck widths, etc. can be extracted with good accuracy. Although promising, a full off-site inspection is currently not feasible as some areas of the bridges were difficult to capture mainly due to restricted access and narrow spaces. Measurements based on terrestrial laser scanning were closer to the reality compared to photogrammetry and infrared scanning. The study indicates the no special training is needed for photogrammetry and infrared scanning to generate a 3D geometric model.     

The Influence of the thermal insulation of the window frameworks on the energy performance of the window

The paper presents the energetic performances of a window in diverse constructive realization solutions and the thermal protection of its frame. The study made has at its basis the numeric analysis of the temperature field upon the effect made by the joining of the thermal insulation from the walls on the embrasures of the window hole. The heat transfer through the window‐wall‐insulation ensemble was determined with the help of the “WINDOW‐WALL” calculus program derived from the calculus program CIMPSPAT, made by the authors in the variant 2008 (first variant in 1980) written in the programming language Delphi under Windows environment. The analysis of the interior microclimate conditions existing in the dwelling houses from our country, leads to the necessity of a better knowing of the heat transfer phenomena closer to the real phenomenon that takes place in the case of the windows placed in different situations of exploitation. The practical finding of different behavior of windows, the condense phenomenon met on the interior surface of the window framework and the contour in which the window is placed, calls for the necessity of the calculus presented in the paper.