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M. Clara O. Gans S. Weiss D. Sanz-Escribano S. Scharf C. Scheffknecht 《Water research》2009,43(18):4760-4768
Perfluorinated alkylated substances (PFAS) are of global interest due to their occurrence and persistency in the environment. This study includes surface waters and sediments for the analysis of eleven PFAS. The PFAS studied can be grouped in perfluoroalkyl carboxylates (PFCAs), perfluoroalkyl sulfonates (PFS) and perfluoroalkyl sulfonamides (PFSA). The two most important compounds are perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS). These two substances showed the most significant values for surface water samples with maximum concentrations of 21 ng l−1 for PFOA and 37 ng l−1 for PFOS. Sediment samples from seven Austrian lakes and the river Danube were studied. Whereas PFSA and PFS were not detected in any sediment sample PFCAs were detected in most of the lake samples in concentrations up to 1.7 μg kg−1 dry wt. PFOA, perfluorohexanoic acid (PFHxA) and perfluoroheptanoic acid (PFHpA) were detected in all Danube river sediment samples in concentrations varying from 0.1 up to 5.1 μg kg−1 dry wt. For the various sampling points the proportional mass flows deriving from wastewater discharges were calculated. Whereas only up to 10% of the average flow is discharged wastewater up to more than 50% of the PFAS mass flows in the rivers can be attributed to wastewater discharges. Besides wastewater different other pathways as emissions from point sources, further degradation of precursor products, runoff from contaminated sites or surface runoff as well as dry and wet deposition have to be considered as relevant sources for PFAS contamination in surface waters. 相似文献
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Alegre Clara Iris Aymará Zalazar María Fernanda Bulhões Cazula Bárbara Alves Helton José Peruchena Nélida María 《Topics in Catalysis》2019,62(12-16):941-955
Topics in Catalysis - In this work, a theoretical study in conjunction with a spectroscopic analysis by FTIR were carried out in order to obtain molecular insights on the role of... 相似文献
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de Souza Junior Jonas Pereira Frazão Joaquim José de Morais Thais Chagas Barros Espoti Clara Degli dos Santos Sarah Marcilene Machado de Mello Prado Renato 《SILICON》2021,13(4):1269-1275
Silicon - Silicon (Si) combined with foliar spraying of salicylic acid (SA) can affect the absorption of this beneficial element. A study with Si non-accumulators plants (soybean and bean) observed... 相似文献
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Clara Sangrós Giménez Laura Helmers Carsten Schilde Alexander Diener Arno Kwade 《化学工程与技术》2020,43(5):819-829
All-solid-state batteries constitute a very promising energy storage device. Two very important properties of these battery cells are the ionic and the electrical conductivity, which describe the ion and the electron transport through the electrodes, respectively. In this work, a numerical method is presented to model the electrical conductivity, considering the outcome of discrete-element method simulations and the intrinsic conductivities of both the active material particles and the conductive additive particles. The results are calibrated and validated with the help of experimental data of real manufactured electrodes. The tortuosity, which strongly influences the ionic conductivity, is also presented for the analyzed electrodes, taking their microstructure into account. 相似文献
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