Microstructure and mechanical properties of Ti 45Al 5Nb + (0–0.5C) sheets

The possible application of gamma titanium aluminides in aerospace industry requires a detailed understanding of the microstructure–property relationship of sheets made from this material. This paper reports the mechanical properties of sheets up to 1000 °C, based on alloy concepts with high Nb concentrations and small additions of C. Sheets were manufactured by rolling powder metallurgical compacts with compositions Ti 45Al 5Nb and Ti 45Al 5Nb 0.5C. The microstructures of both sheets are “near gamma” and consist of γ-TiAl and ₂-Ti₃Al phases. The texture of both phases is very weak. The strengths levels are very high and that of the C-containing sheet exceeds that of the C-free material at RT by 200 MPa. The mechanical properties of Ti 45Al 5Nb are independent of the direction in the sheet, in the whole temperature range from RT to 1000 °C. However, for the C-containing sheet this is true only in the upper temperature range.     

Primary energy and comfort performance of ventilation assisted thermo-active building systems in continental climates

This article presents a simulation study comparing the primary energy and comfort performance of ventilation assisted thermo-active building systems (TABS) relative to a conventional all-air (VAV) system in a compact office building featuring good thermal envelope performance, heat recovery, and solar gain control for the continental climate of Omaha, Nebraska with pronounced heating and cooling periods. TABS heating is accomplished using a geothermal heat pump and TABS cooling using a geothermal heat exchanger without an additional vapor compression cycle required. It was found that the coordination of the TABS and VAV systems is crucial, i.e., supply air temperature and active layer temperature setpoints and reset schedules greatly affect the performance of the overall system. The small contribution of TABS in the heating case shows the need for the adaptation of the ventilation system configuration to the TABS system. Annual cooling energy demand for the ventilation assisted TABS is higher than for the pure VAV system, which is due to lower occupied period room operative temperatures and thus a higher comfort provided. While a 4% useful energy penalty for the combined TABS/VAV was recorded, the VAV case requires 20% more delivered energy than the TABS case because of the displacement of compressor driven coil loads with low-exergy cooling through the ground heat exchanger in the TABS case. A primary energy intensity of 189 kWh/m² a was recorded for the TABS case; in contrast, the conventional all-air (VAV) equipped building incurs a primary energy intensity of 229 kWh/m²a, which represents a penalty of 20%. Clear advantages of the TABS approach can be observed with respect to thermal comfort: during summer cooling periods, the mean radiant temperature of the TABS case is on average 2 K below that of the VAV case. Moreover, the VAV system is associated with a fairly constant predicted mean vote (PMV) value of 0.75, which is quite warm, while the TABS equipped system reveals an average of 0.56, which results in only 12% instead of 17% of people dissatisfied. Based on these results, ventilation assisted thermo-active cooling systems appear to be a very promising alternative to conventional all-air systems offering both significant primary energy as well as thermal comfort advantages provided the TABS is mated with low-exergy heating and cooling sources.     

Evaluation of uncertainties in sewer condition assessment

Closed Circuit Television Inspection is used since decades as industry standard for sewer system inspection and structural performance evaluation. In current practice, inspection data are helpful to support asset management decisions. However, the quality and uncertainty of sewer condition assessment is rarely questioned. This article presents a methodology to determine the probability to underestimate, overestimate or accurately estimate the real condition of a pipe using visual inspection. The approach is based on the analysis of double inspections of the same sewer pipes and has been tested using the extensive data-set of the city of Braunschweig in Germany. Results indicate that the probability to inspect correctly a pipe in poor condition is close to 80%. The probability to overestimate the condition of a pipe in bad condition (false negative) is 20% whereas the probability to underestimate the condition of a pipe in good condition (false positive) is 15%. Finally, sewer condition evaluation can be used to assess the general condition of the network with an excellent accuracy probably because the respective effects of false positive and false negative are buffered.     

Detailed Structure–Function Correlations of Bacillus subtilis Acetolactate Synthase

Isobutanol is deemed to be a next‐generation biofuel and a renewable platform chemical. 1 Non‐natural biosynthetic pathways for isobutanol production have been implemented in cell‐based and in vitro systems with Bacillus subtilis acetolactate synthase (AlsS) as key biocatalyst. 2 – 6 AlsS catalyzes the condensation of two pyruvate molecules to acetolactate with thiamine diphosphate and Mg²⁺ as cofactors. AlsS also catalyzes the conversion of 2‐ketoisovalerate into isobutyraldehyde, the immediate precursor of isobutanol. Our phylogenetic analysis suggests that the ALS enzyme family forms a distinct subgroup of ThDP‐dependent enzymes. To unravel catalytically relevant structure‐function relationships, we solved the AlsS crystal structure at 2.3 Å in the presence of ThDP, Mg²⁺ and in a transition state with a 2‐lactyl moiety bound to ThDP. We supplemented our structural data by point mutations in the active site to identify catalytically important residues.     

Einfluss von Aluminium auf die Karbidbildung im Schnellarbeitsstahl

Aluminum as an alloying element in high-speed steel was investigated for the first time during the Second World War at the Montanuniversität Leoben. At this time there was an enormous consumption or rather a shortage of molybdenum and especially of tungsten worldwide. Tungsten was not only used for the high-speed steel production but was also very much needed for the war industry. Attempts were made in order to replace these alloying elements in high-speed steels with cheaper elements. It was found that a certain percentage of tungsten and molybdenum in high-speed steel can be replaced or substituted by an aluminium content of 0.3 up to 1.4 mass-% without any loss of cutting performance. However, no detailed metallurgical investigations were carried out to explain and clarify this behaviour of aluminium. The influence of aluminium in high-speed steels is highly controversial, due to the fact that aluminium compared to tungsten and molybdenum is not a carbide-forming element, but the special properties of high-speed steels are mainly gained by the presence of carbides. Despite several works in this field, there is no clear understanding of how aluminium can affect the properties of high-speed steel. In the present work, standard and modern examination methods, such as scanning electron microscope, energy dispersive X-ray spectroscopy, and atom probe tomography, were used to investigate the effect of aluminium on the primary and secondary hardening carbides in high-speed steels. The investigations were conducted on three high-speed steel grades with varying the aluminium content only.     

Computer-Assisted Determination of Reaction Parameters for the Simulation of Micropollutant Abatement in Wastewater Ozonation

For the purpose of the simulation of the kinetics of the reaction of ozone with wastewater in a bubble column, the kinetics can be adequately described by two components and their respective rate constants. Ozone uptake and ozone steady states along a bubble column have been determined. A modeling procedure has been developed that allows us to describe this behavior and to simulate the degradation of micropollutants. For fast (diclofenac) and moderately fast (bezafibrate) reacting micropollutants this model describes their measured elimination well.     

Element contents in leaves of four plant species (birch, mountain ash, fern and spruce) along anthropogenic and geogenic concentration gradients

Forty samples each of leaves of birch (Betula pubescens Ehrh.), European mountain ash (Sorbus aucuparia (L.)) and bracken fern (Pteridium aquilinum (L.) Kuhn) as well as spruce needles (Picea abies (L.) Karsten) were collected along a 120 km south-north transect running through Norway's largest city, Oslo. Concentrations of 25 chemical elements (Ag, Au, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, La, Mg, Mn, Mo, Na, Ni, P, Pb, S, Sb, Sr, Ti, and Zn) as well as loss on ignition for the 4 sample materials are reported. The decline of input of sea spray with distance from the coast, geology, pH and anthropogenic contamination all played a role for the observed element concentrations in the leaves. Although growing under exactly the same natural conditions each plant species displayed quite unique uptake characteristics. Plant-species dependency and individual differences in the reaction of the plant leaves to different element sources make the investigated species of very limited value as bioindicators of anthropogenic activities. Anthropogenic contamination influences plant-leaf element content within a limited distance ( approximately 20 km) from the source.     

Processing and electromechanical properties of lanthanum-doped Pb(Zr,Ti)O<Subscript>3</Subscript> extruded piezoelectric fibres

This article describes the processing and characterisation of lanthanum-doped lead zirconate titanate (PLZT)-based ferroelectric fibres for composite transducer applications. X-ray diffraction of the extruded and sintered fibres indicated some lead loss during sintering; however, the fibres exhibited low porosity (1.54%), high maximum piezoelectric strain (4041 ppm) and relatively low coercive field (0.77 kV/mm). The low coercive field of the lanthanum-doped fibres may be advantageous in terms of facilitating polarization of the fibres in composite architectures.     

Suppression of inward-rectifying K+ channels KAT1 and AKT2 by dominant negative point mutations in the KAT1 alpha-subunit

Na(+)-glucose transport and transepithelial permeability were investigated during symptomatic acute cryptosporidiosis in newborn rats. The infection resulted in a significant (P < 0.01) decrease in the ileal short-circuit current and a nonsignificant fall in the transepithelial potential difference and conductance. In glucose-stimulated conditions, the rise in ileal short-circuit current and transepithelial permeability were significantly lower in Cryptosporidium parvum-infected rats than in controls (delta Isc = 3.24 +/- 1.21 microA.cm-2 vs delta Isc = 5.09 +/- 2.23 microA.cm-2 in infected and control animals, respectively; P < 0.001; delta PD = -0.35 +/- 0.13 mV vs delta PD = -0.44 +/- 0.14 mV for infected and control animals, respectively; P < 0.01). Electrical parameters were not affected by addition of the cyclooxygenase inhibitor indomethacin in either Cryptosporidium-infected newborn rats or controls. Horseradish peroxidase and mannitol flux studies demonstrated a significant decrease (P < 0.05) in transepithelial molecular permeability in infected enterocyte rats, HRP flux = 380, range 68-5570 ng.cm-2, and mannitol flux = 1.06, range, 0.34-1.44%.cm-2.min-1, compared with controls rats, HRP flux = 4446 range, 1121-124,363 ng.cm-2, and mannitol flux = 1.99, range, 0.57-5.09%.cm-2.min-1; P < 0.05. These effects could originate from C. parvum-induced alteration of intracellular trafficking of pinocytosis vesicles and therefore account for the decrease in permeability to solute and macromolecules, together with impaired transcellular nutrient transport, in suckling rats.