Sunflower oil coating on the nanoparticles of iron(III) oxides

High-temperature solution phase reaction of iron(III)-furoate in sunflower oil, in the presence of trichloroacetic acid and 1,2-hexadecylamine leads to iron(III) oxide (amorphous and γ-Fe2O3) nanoparticles with sizes about 1.3 nm in diameter (method “A”), and about 5.5 nm (amorphous Fe2O3) from the “sunflower oil/oxadiazol” system (method “B”).     

Lactones in the Synthesis of Prostaglandins and Prostaglandin Analogs

In the total stereo-controlled synthesis of natural prostaglandins (PGs) and their structural analogs, a vast class of compounds and drugs, known as the lactones, are encountered in a few key steps to build the final molecule, as: δ-lactones, γ-lactones, and 1,9-, 1,11-, and 1,15-macrolactones. After the synthesis of 1,9-PGF_2α and 1,15-PGF_2α lactones, many 1,15-lactones of E₂, E₃, F₂, F₃, A₂, and A₃ were found in the marine mollusc Tethys fimbria and the quest for understanding their biological role stimulated the research on their synthesis. Then 1,9-, 1,11-, and 1,15-PG lactones of the drugs were synthesized as an alternative to the corresponding esters, and the first part of the paper describes the methods used for their synthesis. The efficient Corey procedure for the synthesis of prostaglandins uses the key δ-lactone and γ-lactone intermediates with three or four stereocenters on the cyclopentane fragment to link the PG side chains. The paper describes the most used procedures for the synthesis of the milestone δ-Corey-lactones and γ-Corey-lactones, their improvements, and some new promising methods, such as interesting, new stereo-controlled and catalyzed enantioselective reactions, and methods based on the chemical/enzymatic resolution of the compounds in different steps of the sequences. The many uses of δ-lactones not only for the synthesis of γ-lactones, but also for obtaining 9β-halogen-PGs and halogen-substituted cyclopentane intermediates, as synthons for new 9β-PG analogs and future applications, are also discussed.     

罗马尼亚外国投资的现状

罗马尼亚商务立法制度对外国投资者非常有列，允许外国投资者拥有100％的所有权，允许将利润与资本转向国外，也允许减免税收。根据1990年31号公司法的规定，外国投资者可以在罗建立新公司或分公司，全部外资或合资，法人或自然人。凡在罗投资者，需向罗开发局提出申请，罗开发局收到申请后应在30天内予以答复，在此期间未收到答复，则视为批准。外国投资者在罗可享受各种优惠：外资既可投向各工业部门，也可投向农业、基础设施、交通运输、工民建、科技开发、贸易、旅游、银行、保险等；外国投资者所获合法利润可以自由转换成货币输出国外：按合同条款规定，还可向国外转让版权、技术和其他服务项目；外资在罗将不会国有化，不会征用，不会剥夺所有权；根据法律规定及合同条款，外国投资者有权参加投资管理；外国投资者可以免征海关进口税等。当然，外国投资者必须遵守罗马尼亚的有关法律，特别是不允许违反环境保护法，不允许影响罗马尼亚的国家安全与国防利益，不允许危害公共秩序、健康与道德规范。     

Abstractions of data types

The use of abstraction in the context of abstract data types, is investigated. Properties to be checked are formulas in a first order logic under Kleene's 3-valued interpretation. Abstractions are defined as pairs consisting of a congruence and a predicate interpretation. Three types of abstractions are considered,∀∀, ∀∃ and ∃^0,1∀, and for each of them corresponding property preservation results are established. An abstraction refinement property is also obtained. It shows how one can pass from an existing abstraction to a (less) finer one. Finally, equationally specified abstractions in the context of equationally specified abstract data types are discussed and exemplified.On leave from the Department of Computer Science, “Al. I. Cuza” University, Iaşi 740083, RomaniaThe research reported in this paper was partially supported by the program ECO-NET 08112WJ/2004-2005 and by the National University Research Council of Romania, grants CNCSIS 632(28)/2004 and CNCSIS 632(50)/2005.     

Breakdown voltage of diffused epitaxial junctions

The quantitative aspects of the breakdown-voltage calculations in reach-through-limited p⁺−n−n⁺ junctions are revisited, using numerical simulation. It is shown that the conventional abrupt-junction approximation may underestimate the breakdown voltage of diffused epitaxial junctions by as much as 60%, depending on junction depth. Oppositely, but less erroneously, a combined abrupt/linearly-graded approximation overestimates the breakdown voltage by at most 15%. A set of numerically calculated plots are provided for the design of low-voltage power devices.     

On the connection between the exponential stability of C0-semigroups and the admissibility of a certain Sobolev space

Let T be a strongly continuous semigroup on a Banach space X and A its infinitesimal generator. We will prove that T is exponentially stable, if and only if, there exist p[1,∞) such that the space is admissible to the system Σ(A,I,I), defined below (i.e for all f belonging to the Sobolev space the convolution T*f lies in .     

Lyapunov based predictive control of vehicle drivetrains over CAN

Vehicle drivetrains are characterized by fast dynamics, subject to physical and control constraints, which make controller design for driveline oscillations damping a challenging problem. Furthermore, in current implementations, the connections between the controller and the physical plant are realized using a controller area network (CAN) as the communication medium, which introduces time-varying delays. As such, the goal of this paper is to provide a control design methodology that can cope with all these challenges and limitations and still yield an effective solution. To this end, firstly, a continuous-time model of a vehicle drivetrain is derived. Then, a method for determining a worst case upper bound on the delays that can be introduced by a CAN is presented, which enables the usage of a polytopic approximation technique to obtain a discrete-time model of the closed-loop CAN system. Thirdly, a non-conservative Lyapunov based predictive controller is designed for the resulting model with time-varying delays, polytopic uncertainty and hard constraints. Several tests performed using an industry validated drivetrain model and the Matlab toolbox TrueTime indicate that the proposed design methodology can handle both the performance/physical constraints and the strict limitations on the computational complexity, while effectively coping with time-varying delays. Preliminary real-time results further validate the proposed methodology.     

C-Testable modified-Booth multipliers

In this paper the testability of modified-Booth array multipliers for standard cells based design environments is examined for first time. In such cases the structure of the cells may be unknown, thus Cell Fault Model (CFM) is adopted. Two C-testable designs are proposed. A design for an N _x × N_y bits modified-Booth multiplier, which uses ripple carry addition at the last stage of the multiplication, is first proposed. The design requires the addition of only one extra primary input and 38 test vectors with respect to CFM. A second C-testable design is given using carry lookahead addition at the last stage which is the case of practical implementations of modified-Booth multipliers. Such a C-testable design using carry lookahead addition is for first time proposed in the open literature. This second design requires the addition of 4 extra primary inputs. One-level and two-levels carry lookahead adders, are considered. The C-testable design requires 61 test vectors for the former and 73 test vectors for the latter, respectively. The hardware and delay overheads imposed by both C-testable designs are very small and decrease when the size of the multiplier increases.     

Plate tectonic reconstructions with continuously closing plates

We present a new algorithm for modeling a self-consistent set of global plate polygons. Each plate polygon is composed of a finite list of plate margins, all with different Euler poles. We introduce a "continuously closed plate" (CCP), such that, as each margin moves independently, the plate polygon remains closed geometrically as a function of time. This method solves emerging needs in computational geodynamics to combine kinematic with dynamic models. Because they have polygons that are too widely spaced in time and have inconsistent motions between margins and plates, traditional global plate tectonic reconstructions have become inadequate for geodynamics. The CCP algorithm has been incorporated into the GPlates open-source paleogeographic system. The algorithm is a set of procedures and data structures that operate on collections of reconstructed geometric data to form closed plate polygons; the main data structures used for each plate polygon are based on a nested hierarchy of topological elements. Reconstructions with CCPs can be created, edited, visualized, and exported with GPlates. The native storage of the dynamic reconstructions is the GPlates Markup Language, GPML, which uses an XML-based file format called GML. We demonstrate the utility of the CCP method by creating a global reconstruction with continuously closing plates from 140 Ma to the present using data from existing, traditional reconstructions.     

Novel thermosensitive flocculanting agent based on pullulan

New thermosensitive polysaccharide (P-g-pNIPAAm) was synthesized by graft-polymerization of p(N-isopropylacrylamide) (pNIPAAm) onto pullulan (P) using Ce(IV) ion as initiator. The grafted polysaccharide was characterized by FT-IR and ¹H NMR spectroscopy and elemental analysis. Its flocculation efficiency was studied in a clay suspension, in comparison with p(NIPAAm) homopolymer, as a function of the polymer dose, temperature and settling time. The thermosensitive polysaccharide could induce clay particle flocculation both below and above the lower critical solution temperature (LCST), but the process was more effective above the LCST. A lower value of the residual turbidity at the optimum polymer dose and a wider flocculation window were recorded at temperature above the LCST. The floc size distribution and surface morphology revealed bigger size flocs when the flocculation was performed above the LCST. The re-dispersion effect was negligible for the flocs obtained in the presence of P-g-pNIPAAm.