$$\hbox {SiO}_{2}\hbox {/TiO}_{2}$$ multi-layered thin films with self-cleaning and enhanced optical properties

Self-cleaning, high transmittance glazing was obtained by cold spray deposition for glazings. The thin films contain \(\hbox {TiO}_{2}\), \(\hbox {SiO}_{2}\) and Au nanoparticles in different structures which allow for tailoring the optical, hydrophilic and photocatalytic properties. The crystallinity, morphology and surface energy were correlated with the optical transmittance and reflectance; the transmittance increased from 89.45 (for the glass substrate) to 91.76% when Au nanoparticles were used in the tandem layered structures. The samples containing alternating multi-layered \(\hbox {SiO}_{2}\) and \(\hbox {TiO}_{2}\) thin films without gold nanoparticles show hydrophilic surface; for these layers, the photocatalytic efficiency reaches 40% under simulated solar radiation. A conditioning effect based on adsorption was observed to increase the photocatalytic efficiency. These highly transparent coatings are well suited for glazings and fenestration, showing the self-cleaning effect based on combined superhydrophilicity and photocatalysis.     

Computation and analysis of the workspace of a reconfigurable parallel robotic system

A reconfigurable robotic system permits multiple configurations having different characteristics, using mostly modularized building blocks. The goal of this paper is to investigate how the shape, dimensions and the distribution of singularities in the workspace for different configurations, with different degrees of freedom, of a reconfigurable robotic system, are changed. The computation of the workspace is based on the modularity property of the system. The presented results are also experimentally validated.     

Polyamine Functionalized Magnetite Nanoparticles as Novel Adsorbents for Cu(II) Removal from Aqueous Solutions

Three novel magnetic adsorbents were synthesized through the immobilization of di-, tri-, and tetraamine onto the surface of silica coated magnetite nanoparticles. The adsorbents were characterized by XRD patterns, FTIR spectroscopy, elemental and thermogravimetric analysis, magnetic measurements, SEM/TEM, EDX spectroscopy, and N₂ adsorption/desorption isotherms. Their capacity to remove copper ions from aqueous solutions was investigated and discussed comparatively. The equilibrium data were analyzed using Langmuir and Freundlich isotherms. The kinetics was evaluated using the pseudo-first-order, pseudo-second-order, and intra-particle diffusion models. The best interpretation for the equilibrium data was given by the Langmuir isotherm for the tri- and tetraamine functionalized adsorbents, while for the diamine functionalized adsorbent the Freundlich model seemed to be better. The kinetic data were well fitted to the pseudo-second-order model. The overall rate of adsorption was significantly influenced by external mass transfer and intraparticle diffusion. It was observed that the adsorption capacity at room temperature decreased as the length of polyamine chain immobilized on the adsorbent surface increased, the maximum adsorption capacities being 52.3 mg g^?1 for 1,3-diaminopropan functionalized adsorbent, 44.2 mg g^?1 for diethylenetriamine functionalized adsorbent, and 39.2 mg g^?1 for triethylenetetramine functionalized adsorbent. The sorption process proved to be highly dependent of pH. The results of the present work recommend these materials as potential candidates for copper removal from aqueous solutions.     

Photocatalytic degradation of methyl orange: influence of H2O2 in the TiO2-based system

The purpose of this study was to investigate the photocatalytic oxidation of a reactive azo dye. The photocatalytic activity of the TiO2 was studied using a reactor equipped with UV-A sources, with maximum emission at 365 nm. The photocatalytic activity of the TiO2 powder (99.9% anatase) and thin films has been measured through the decomposition of methyl orange solutions. The thin film was prepared by doctor blade and spray pyrolysis deposition (SPD). The TiO2 suspensions were prepared at 1 g/L concentration, and the initial methyl orange concentration was fixed at 7.8125 mg/L. The influence of the TiO2 (powder or thin films) and/or O2 and H2O2 on the photobleaching rate, was tested under different experiments, at pH = 5. Thin films (doctor blade) of TiO2 formed of mezo-sized aggregates formed of nanosized anatase crystallites show better photobleaching efficiency than thin film (SPD) due to their large internal surface. The rate is even higher in H2O2 compared to oxygen environment.     

Glow discharge techniques in the chemical analysis of photovoltaic materials

The presented study gives an integrated overview on the prospects of glow discharge (GD) methods in the chemical analysis of photovoltaic materials. With a focus on recent research and important photovoltaic (PV) materials, the GD coupled analytical methods, high resolution mass spectrometry (MS), time‐of‐flight‐mass spectrometry (TOF‐MS) and optical emission spectrometry (OES) are discussed. Each exemplary study carried out will point out the most suitable GD technique for the problem at hand, at the same time showing ways to increase analytical accuracy and to overcome typical instrumental restrictions. Challenging GD‐MS analyses of thin and ultra thin films (down to 20 nm) as well as GD‐MS and GD‐OES studies of ready‐to‐use modules were carried out, showing the reader the application potential of GD methods in a PV development or production process. For the first time, novel cell concepts based on crystalline silicon on glass and silicon nanowires are analyzed by GD‐OES, revealing precise chemical information on the devices. Copyright © 2012 John Wiley & Sons, Ltd.     

Design and implementation of tuned viscoelastic dampers for vibration control in milling

Passive means of vibration attenuation have been employed successfully and efficiently in machining systems such as turning and milling. Traditional approach to controlling vibration in a milling system is to develop control mechanisms for cutting tools or machine spindles. However, due to the nature of milling operations where the cutting tools rotate at high speed, the passive vibration control methods find very limited application with the traditional approach. In order to utilise the potential of the passive vibration control methodology in milling applications, the milling operation should be viewed as a system comprising an elastic structure and operation parameters. Dynamics of this closed-loop system should improve with improvement in dynamics of any of the system components, especially within the elastic structure that comprises the cutting tool, the machine tool, the workholding system and the workpiece. Although the level of improvement will vary depending on which component of the elastic chain is targeted for this purpose. This paper presents the development and testing of tuned viscoelastic dampers (TVDs) for vibration control through their application on a workpiece in milling operations. This work targets workpiece held on a palletised workholding system for the control of unwanted vibration and thus deviates from the traditional approach where cutting tool and/or machine spindles are targeted for vibration control strategies. Palletised workholding systems, due to their compact design, offer an opportunity to design passive damping mechanisms that are easier to implement in the case of a milling system. The TVD developed through this research is based on a commercially available viscoelastic damping polymer. Advantage of such materials is their high damping performance over a wide range of excitation frequencies. The TVD design process has used a unique combination of analytical modelling with experimental FRF data. Modal impact testing showed that the application of the TVD reduced the amplitude of vibration acceleration by 20 dB for the target mode. Since the target mode corresponded to torsional vibration, the TVD was effective in two planar coordinates, i.e. X and Y. In addition, the TVD also significantly reduced the amplitude of a vibration mode far from the mode it was designed for. The system has been tested experimentally to demonstrate significant reduction in vibration amplitudes during a milling process. The milling tests with different combinations of cutting parameters show that multi-TVD approach is always valid regardless of the parameters being used. The only requirement for TVDs to function effectively is that the natural frequency of the system, for which the TVDs are designed, is excited during the milling process.     

Erweiterung des Stadions Innsbruck “Tivoli Neu” für die Fußballeuropameisterschaft 2008

Stadium Innsbruck “Tivoli Neu” extended for the European Football Championship 2008. Austria and Switzerland are the hosts of the European Football Championship EURO 2008. Each of both countries needs four stadiums with at least 30000 spectator seats. Innsbruck had a facility with a capacity of nearly 15000 seats. This existing stadium “Tivoli Neu” has therefore to be extended. The community of Innsbruck requests, that after the Championship the stadium has to be reconstructed into the original state.     

The teratogenicity of N(omega)-nitro-L-ariginine methyl ester (L-NAME), a nitric oxide synthase inhibitor, in rats

Exposure of gravid rats to the nitric oxide synthase inhibitor N(omega)-nitro-L-arginine methyl ester (L-NAME) in drinking water or by implanted osmotic minipumps significantly elevates maternal blood pressure, reducing uteroplacental perfusion. Administration by either route causes fetal growth retardation, but oral exposure also causes hind limb reduction malformations. The present study employed both oral and intraperitoneal routes to determine the period of sensitivity to developmental toxicity, dose-response, and possible fetotoxic mechanisms. Hind limb hemorrhage occurred only in litters from dams exposed to oral doses of 1 to 2 mg/mL from gestational days 15 through 17. In contrast to oral exposure, single intraperitoneal injections caused both fore and hind limb reductions at doses of 25 mg/kg and above administered on gestational day 16 and later. Many other exposures that reduce uteroplacental perfusion have been associated with vascular disruptive dysmorphogenesis. These exposures include phenytoin, calcium channel inhibitors, cocaine, and uterine vascular clamping. Limb hemorrhage induced by these exposures is usually limited to distal structures, typically phalanges, and the incidence of affected fetuses rarely exceeds 50%. By contrast, hemorrhage caused by L-NAME frequently involves entire limbs, extending into adjacent flank in severe instances, and 100% of fetuses from treated dams may be affected. The basis of this difference and the differing defect patterns associated with the various routes of exposure are unclear, but the generation of reactive oxygen species during resumption of normal perfusion may play a role in this vascular disruption.     

Accumulation and desorption of free radicals in emulsion copolymerization

The emulsion copolymerization of styrene with acrylonitrile, seeded on a polybutadiene support and initiated either potassium persulfate or γ-rays has been studied. The original technique of support activation consists of two steps: the start of the copolymerization in the presence of a small fraction of monomers, followed by the addition of the rest of monomers, which leads to a great increase in the reaction rate. The experimental data provide evidence for a new mechanism that takes into account the desorption–reentry of the free oligoradicals into another particle, their transfer to the polybutadiene support, which results in the accumulation of trapped free radicals. As a consequence of free radicals' accumulation, the overall copolymerization rate increases. The accumulation as well as the desorption processes place this type of copolymerization far from Smith–Ewart theory case II.