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排序方式: 共有432条查询结果,搜索用时 15 毫秒
351.
Marko Malićanin Vladislav Rac Vesna Antić Mališa Antić Laurentiu Mihai Palade Panagiotis Kefalas Vesna Rakić 《Journal of the American Oil Chemists' Society》2014,91(6):989-999
The goal of this work was to investigate the relationship between antioxidants’ content and the oxidative stabilities of grape seed oils obtained from the Cabernet Sauvignon variety. The samples of grape seed oils were obtained by ultrasound assisted extraction. The time of extraction was varied, while the other relevant parameters: extraction temperature, solvent to solid ratio and sonication power were kept constant. For the sake of comparison, the extraction was also done using the conventional Soxhlet method. For all the oil samples obtained, the contents of total phenolic compounds (TPC), α-tocopherol and fatty acids were determined using relevant analytic methods. Importantly, in the present study, the modern analytical techniques for estimation of antioxidant capacity (measuring the chemiluminescence intensity of a luminol-hemin solution) and oxidative stability [differential scanning calorimetry (DSC), coupled with thermogravimetry (TG)] were proposed. The obtained results prove that ultrasonic irradiation enables effective extraction of grape seed oil. It was shown that the extractive yields and the amounts of total phenolic compounds and α-tocopherol increase with time of extraction; the optimum time was determined. Results obtained in this work show that, for both oxidative stability and antioxidant capacity, TPC have a more important role then α-tocopherol. 相似文献
352.
This work reports on the physical definition and extraction of threshold voltage in Tunnel FETs (field effect transistors) based on numerical simulation data. It is shown that the Tunnel FET has the outstanding property of having two threshold voltages: one in terms of gate voltage, VTG, and one in terms of drain voltage, VTD. These threshold voltages can be physically defined based on the transition between a quasi-exponential dependence, and a linear dependence of the drain current on VGS or VDS, and by extension, on the saturation of the tunneling energy barrier width narrowing. The extractions of VTG and VTD are performed based on the transconductance change method in the double gate Tunnel FET with a high-k dielectric, and a systematic comparison with the constant current method is reported. The effect of gate length scaling on these Tunnel FETs’ threshold voltages, as well as the dependence of VTG on applied drain voltage and VTD on applied gate voltage, are investigated. 相似文献
353.
We show that anodization of Ti sheets in an ethylene glycol and HF containing electrolyte at temperatures under 0 °C results in the formation of a self-arranged ordered porous structure at the top surface of the sample. This perforated surface structure initiates the growth of an ordered array of titania nanotubes. The inner diameter of nanotubes can be modified in a controlled fashion in the range from 10 nm to more than 250 nm through the change of the electrolyte temperature from −20 °C to + 50 °C. The spectral distribution of cathodoluminescence from a cluster of nanotubes clearly demonstrates the formation of resonator modes which are separated from each other by around 200 meV. 相似文献
354.
This paper presents a new numerical procedure for the determination of the viscoelastic compliance properties of a matrix phase from a simple three-point bending test on a composite beam. The composite is modeled as elastic inclusions randomly dispersed throughout a viscoelastic matrix. It is also assumed that the spatial distribution of the inclusions in the composite is known or can be determined. Zevin’s method of iterative functions is proposed for the determination of the matrix properties. Following a detailed explanation of the proposed scheme, a numerical verification is performed using three-dimensional finite-element (FE) analysis simulations. The proposed scheme was applied to the experimentally obtained creep compliance of the asphalt concrete beam. The obtained viscoelastic properties of the asphalt binder matrix phase were used as input into the FE model to simulate the behavior of the composite beam. An excellent comparison between the experimental data and the predicted beam deflections was observed. This shows that the proposed method is robust and it can be implemented to solve identification problems for viscoelastic composite materials. 相似文献
355.
Ioana Madalina Zota Cristina Andreea Adam Drago Traian Marius Marcu Cristian Sttescu Radu Sascu Larisa Anghel Daniela Boiteanu Mihai Roca Corina Lucia Dima Cozma Alexandra Mataleru Maria Magdalena Leon Constantin Elena Andreea Moale Florin Mitu 《International journal of molecular sciences》2022,23(20)
Obstructive sleep apnea (OSA) is characterized by repetitive upper airway collapse, chronic hypoxia and a proinflammatory phenotype. The purpose of our study was to evaluate readily available inflammatory biomarkers (C-reactive protein (CRP), erythrocyte sedimentation rate (ESR), white blood cell count (WBC), red cell distribution width (RDW), neutrophil-to-lymphocyte ratio (NLR), platelet-to-lymphocyte ratio (PLR), mean platelet volume (MPV), WBC-to-MPV ratio (WMR) and lymphocyte-to-C-reactive protein ratio (LCR)) before and after CPAP in patients with moderate–severe OSA. We performed a prospective study that included patients with newly-diagnosed moderate–severe OSA. The control groups (patients without OSA and with mild OSA) were selected from the hospital polygraphy database. All subjects underwent routine blood panel, which was repeated in moderate–severe OSA patients after 8 weeks of CPAP. Our final study group included 31 controls, 33 patients with mild, 22 patients with moderate and 37 patients with severe OSA. CRP, ESR, NLR and WMR were correlated with OSA severity. After 8-week CPAP therapy, we documented a decrease in weight status, which remained statistically significant in both CPAP-adherent and non-adherent subgroups. Readily available, inexpensive inflammatory parameters can predict the presence of moderate–severe OSA, but are not influenced by short-term CPAP. 相似文献
356.
Ariana Hudi Valentina Grumezescu Oana Gherasim Alexandru Mihai Grumezescu Gabriela Dorcioman Irina Negut Ovidiu-Cristian Oprea Bogdan tefan Vasile Bianca Gleanu Carmen Curuiu Alina Maria Holban 《International journal of molecular sciences》2022,23(23)
Despite their great benefits for debilitated patients, indwelling devices are prone to become easily colonized by resident and opportunistic microorganisms, which have the ability to attach to their surfaces and form highly specialized communities called biofilms. These are extremely resistant to host defense mechanisms and antibiotics, leading to treatment failure and device replacement, but also to life-threatening complications. In this study, we aimed to optimize a silica (SiO2)-coated magnetite (Fe3O4)-based nanosystem containing the natural antimicrobial agent, eugenol (E), suitable for MAPLE (matrix-assisted pulsed laser evaporation) deposition as a bioactive coating for biomedical applications. X-ray diffraction, thermogravimetric analysis, Fourier-transform infrared spectroscopy, and transmission electron microscopy investigations were employed to characterize the obtained nanosystems. The in vitro tests evidenced the superior biocompatibility of such nanostructured coatings, as revealed by their non-cytotoxic activity and ability to promote cellular proliferation and sustain normal cellular development of dermal fibroblasts. Moreover, the obtained nanocoatings did not induce proinflammatory events in human blood samples. Our studies demonstrated that Fe3O4 NPs can improve the antimicrobial activity of E, while the use of a SiO2 matrix may increase its efficiency over prolonged periods of time. The Fe3O4@SiO2 nanosystems showed excellent biocompatibility, sustaining human dermal fibroblasts’ viability, proliferation, and typical architecture. More, the novel coatings lack proinflammatory potential as revealed by the absence of proinflammatory cytokine expression in response to human blood sample interactions. 相似文献
357.
Nicusor Fifere Anton Airinei Mihai Asandulesa Aurelian Rotaru Elena Laura Ursu Florica Doroftei 《International journal of molecular sciences》2022,23(22)
Dielectric, magnetic and Raman measurements of cerium oxide nanoparticles obtained by the precipitation method are discussed. Morphological study was performed by scanning electron microscopy, confirming the formation of nanoparticles of 5–27 nm. The Raman spectra exhibited a strong band around 465 cm−1, corresponding to the symmetrical stretching mode of the Ce-O8 vibrational unit. The nature of the room temperature ferromagnetism of cerium oxide nanoparticles was analyzed, taking into account the oxygen defects at the surface or interface of the nanoparticles. The evolution of dielectric constant, ε′, and dielectric loss, ε″ was studied as a function of frequency at different temperatures. Additionally, the variation of the electric conductivity versus temperature was investigated. Finally, complex impedance study of the cerium oxide nanoparticles was performed. 相似文献
358.
Marin-Aurel Trofin Stefania Racovita Silvia Vasiliu Ana-Lavinia Vasiliu Marcela Mihai 《International journal of molecular sciences》2022,23(23)
Crosslinked porous microparticles have received great attention as drug delivery systems lately due to their unique set of properties: the capability to form various polymer–drug combinations, low immunogenicity, patient compliance and ability to release drugs in a delayed or controlled manner. Moreover, polymers with betaine groups have shown some unique features such as antifouling, antimicrobial activity, biocompatibility and strong hydration properties. Herein, novel porous zwitterionic microparticles were prepared in two stages. The first step involves the synthesis of porous microparticles based on glycidyl methacrylate, N-vinylimidazole and triethyleneglycol dimethacrylate using the suspension polymerization technique, the second step being the synthesis of zwitterionic porous microparticles by polymer–analogous reaction in presence of sodium monochloroacetate as betainization agent. Both types of microparticles were characterized structurally and morphologically by FT-IR spectroscopy, energy dispersive X-ray analysis, scanning electron microscopy, dynamic vapors sorption and mercury porosimetry. The tetracycline loading into crosslinked and zwitterionic microparticles was also performed, the maximum tetracycline loading capacities being 87 mg/g and 135 mg/g, respectively. The drug release mechanism, elucidated by various mathematical models, is controlled by both diffusion and swelling processes as a function of the zwitterionic and/or porous microparticle structure. Both types of microparticles presented antibacterial activity against the two reference strains used in this study: Escherichia coli and Staphylococcus aureus. 相似文献
359.
Adelina-Gabriela Niculescu Cristina Chircov Alexandra Ctlina Bîrc Alexandru Mihai Grumezescu 《International journal of molecular sciences》2021,22(4)
Microfluidics is a relatively newly emerged field based on the combined principles of physics, chemistry, biology, fluid dynamics, microelectronics, and material science. Various materials can be processed into miniaturized chips containing channels and chambers in the microscale range. A diverse repertoire of methods can be chosen to manufacture such platforms of desired size, shape, and geometry. Whether they are used alone or in combination with other devices, microfluidic chips can be employed in nanoparticle preparation, drug encapsulation, delivery, and targeting, cell analysis, diagnosis, and cell culture. This paper presents microfluidic technology in terms of the available platform materials and fabrication techniques, also focusing on the biomedical applications of these remarkable devices. 相似文献
360.
Raluca Marinica Albu Iuliana Stoica Andreea Irina Barzic Mihai Postolache Mihai-Daniel Angheluta Dana Ortansa Dorohoi 《Polymer Engineering and Science》2021,61(10):2453-2465
Various azoderivative dyes were incorporated in uncolored poly(vinyl alcohol) (PVOH). One type of film was obtained by drying the layer of solution cast on glass plate. The other type was obtained by rubbing the PVOH layer before complete drying. Linear birefringence and dichroism of dyed polymer films were investigated as a function of stretching degree. An increase in the linear birefringence was found with increasing stretching degree for both uncolored and colored films. Dichroism of the PVOH films depends on the dye chemical structure and also on the stretching degree of both non-rubbed and rubbed and dyed PVOH samples. Molecular modeling was used to examine interactions occurring between PVOH and the embedded dye molecule. These stretching degree dependencies were approximated mathematically, which was used to describe the behavior of some components of interference filters. 相似文献