Hydrocarbon impurities in SiF<Subscript>4</Subscript> and SiH<Subscript>4</Subscript> prepared from it

Using gas chromatography and high-resolution Fourier-transform IR spectroscopy, we have determined the concentrations of C₁–C₄ hydrocarbon impurities in isotopically unmodified silicon tetrafluoride before and after fine purification and in ²⁸Si-enriched SiF₄. The concentrations of C₁–C₄ hydrocarbon impurities in silicon tetrafluoride for SiH₄ synthesis have been shown to correlate with those in the synthesized silane.     

Methane conversion in a plasma created by a periodic-pulsed electron beam and non-self-sustained discharge

The process of methane conversion in a mixture modeling the natural gas under the action of a periodic nanosecond pulsed electron beam and an electron-beam-induced non-self-sustained discharge has been numerically simulated and studied in experiment. The possibility of methane conversion under the action of electric pulses without significant heating of the processed gas mixture is demonstrated for the first time. The main conversion products in experiment were hydrogen, ethylene, and acetylene.     

Left-handed transmission lines at millimetre and sub-millimetre wavelengths

Co-planar strip (CPS) transmission lines, aimed at operating up to sub-millimetre wavelengths, were periodically loaded by lumped capacitances and inductances in series and shunt configuration, respectively. Under this condition, propagation on the line is backward with group and phase velocities of opposite signs. The transmission lines were fabricated onto a quartz substrate by e-beam patterning and thin film deposition, silicon nitride and gold layers, on a deep sub-micron scale (~200 nm). A direct evidence of left-handedness between 160 and 380 GHz was achieved via the tracking of phase advance in a differential phase experiment using electro-optic sampling. The comparison between modelling results by electromagnetic full wave circuit analysis and experiment was performed in the time and frequency domains. It shows a good agreement in the dispersion characteristics and ultra-fast variations in the transmitted signals. At last, we took benefit of a lumped element fitting approach in order to discuss of the frequency capability of this non-resonant approach     

Air flow through a non-airconditioned bus with open windows

Open window buses without air-conditioning are a major mode of urban and inter-city transport in most countries. High occupancy combined with hot and humid conditions makes travel in these buses quite uncomfortable. In this study air flow through a bus has been studied that could be the basis for low cost and eco-friendly methods of increasing passenger comfort and possibly reduce drag. The aerodynamics of such a road vehicle has not been studied as previous investigations have been confined to vehicles with closed windows that present a smooth exterior to air flow. Using a 1:25 scaled Perspex model of an urban bus in Delhi, flow visualization was performed in a water channel. The Reynolds numbers were one-tenth of a real bus moving at 10 m/s. Smoke and tuft visualizations were also performed on an urban bus at 40 km/h. Numerical simulations were performed at the actual Reynolds number. Even though there were Reynolds number differences, the broad features were similar. Air enters the bus from the rear windows, moves to the front (relative to the bus) and exits from the front windows. Inside air velocity relative to the bus is about one-tenth of the free-stream velocity. The flow is highly three-dimensional and unsteady.     

Local Structure and Valence State of Mn in Ga1−x Mn x N Epilayers

Mn has been incorporated in epilayers of the large-gap semiconductor GaN grown by molecular beam epitaxy using a nitrogen plasma cell. Detailed extended X-ray absorption fine structure (EXAFS) studies of a Ga_0.98Mn_0.02N epilayer confirm that the Mn atoms substitute the Ga atoms, with an increase by 2.7% of the distance to the nearest nitrogen atoms. Near-edge spectroscopy results tend to indicate that the valence state of Mn is slightly higher than 3+, while EXAFS analysis suggests an electron transfer to the N neighbors.     

Mechanical improvement of hydroxyapatite by TiO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> nanoparticles deposition

Deposition of Ti was carried out by laser ablation onto hydroxyapatite porous discs in an Ar atmosphere. Ti nanoparticles were deposited onto HAp surface in order to modify its roughness and morphology as it is observed by scanning electron microscopy (SEM) and scanning probe microscopy (SPM). A homogeneous distribution of Ti over the disc surface was corroborated by elemental mapping. A comparison of the hydroxyapatite hardness before and after deposition was performed using SPM nanoindentation. Transmission Electron Microscopy (TEM) showed that the Ti nanoparticles obtained were covered by an oxygen shell. It is shown that surface modifications of the covered HAp by Ti result in better mechanical properties, reducing the possible damage to the HAp ceramic by friction or impacts as it often happens in meniscus, bone junctions and the inclusion of prosthesis for human treatments.     

A novel technique to prepare LiNbO3 at low temperature

Fresh niobium hydroxide was first precipitated from NbF₅ solution using an aqueous ammonium hydroxide under basic conditions. Then a simple procedure of mixing lithium and niobium hydroxides together and heating at a low temperature (400 °C) produced pure ultrafine single phase LiNbO₃ (LN). In the literature, this is the lowest temperature so far reported on the formation of LN. The phase content and lattice parameters are determined by X-ray diffraction (XRD). The average particle size and morphology were studied by transmission electron microscopy (TEM).