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排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
In this study, 0.95?Sr0.7Ba0.3Nb2O6-0.05CaTiO3-x wt% Er2O3 ceramics (SBNCTEx; x?=?0–5) were synthesized using traditional solid-state method, and we investigated the microstructure, energy storage properties as well as the relationship between dielectric breakdown strength and interfacial polarization. As compared with pure 0.95?Sr0.7Ba0.3Nb2O6-0.05CaTiO3 ceramics, the Er2O3 dopants suppressed the grain growth of SBNCTEx, and the doped ones showed the dense microstructure. The secondary phase was found for x?≥?1 according to the EDS results, and the influence of the secondary phase on relative dielectric breakdown strength has also been studied. The dielectric breakdown strength increased from 18.1?kV/mm to 34.4?kV/mm, which is good for energy storage. The energy storage density of 0.28?J/cm3 and the energy storage efficiency of 91.4% were obtained in the SBNCTE5 ceramics. The results indicate that SBNCTE ceramics can be used as energy storage capacitors. 相似文献
32.
Lei He Yan Xuan Feng Zhang Xue Wang Huaqing Pan Junfeng Ren Meina Chen 《International Journal of Hydrogen Energy》2021,46(1):1096-1105
Bulk and surface properties of proton stability and transportation in Y and Nd co-doped BaCeO3 (BCYN), especially the effect of Nd segregation, were investigated by first-principles calculations. Since the structure of doped BaCeO3 at the operating temperature of proton-conducting has been unclear for a long time, we have summarized the latest experimental results and calculated the structure of the asymmetric BCYN for the first time. The results show that compared with Y, Nd doping promotes oxygen vacancy formation, however reduces proton stability. Our calculation can also provide a possible explanation for the formation of space charge layer at the grain boundary of doped BaCeO3 in experiment. Unlike the stable Y in BCYN, Nd is calculated to be easily segregated, which can facilitate both proton hydration and proton transportation near the surface. Moreover, Nd segregation at the grain boundary is predicted to be beneficial for proton transportation between grains. 相似文献
33.
以从自然腐败的樱桃上分离的链格孢霉(Alternaria sp.)LD3.0086为指示菌,研究苯乳酸对链格孢霉的主要抑制作用靶位。应用分光光度法测定苯乳酸对链格孢霉的最小抑菌浓度,通过卡尔科弗卢尔荧光增白剂染液(calcofluor white,CFW)染色观察苯乳酸对菌丝顶端生长的破坏作用,利用扫描电子显微镜和透射电子显微镜观察链格孢霉的超微结构变化,通过测定苯乳酸作用前后链格孢霉上清液中N-乙酰葡萄糖胺质量浓度变化研究苯乳酸对菌丝细胞壁的破坏作用,应用荧光双染色法观察苯乳酸对链格孢霉菌丝细胞膜的损伤作用。结果表明,12.5 mmol/L的苯乳酸能有效抑制链格孢霉的生长;与对照组(无菌水处理)相比,苯乳酸处理后链格孢霉顶端生长细胞无明显形变,经12.5 mmol/L苯乳酸处理的链格孢霉上清液中N-乙酰葡萄糖胺质量浓度基本不变;苯乳酸处理24 h,链格孢霉菌丝细胞壁表面无明显损伤,细胞内结构发生明显变化;苯乳酸短时间(4 h)处理链格孢霉,菌丝细胞膜仍较为完整,加入苯乳酸较长时间(8 h)后细胞膜发生破裂。综合分析可知,苯乳酸对链格孢霉的主要作用靶位应不是菌丝体的细胞壁和细胞膜,而是在菌丝体内部,通过破坏菌丝内部细胞器结构或引起细胞内的生化反应,从而抑制链格孢霉的生长和繁殖,发挥抑菌活性。 相似文献
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针对领域自适应问题中源域和目标域的联合分布差异最小化问题,提出两阶段领域自适应学习方法.在第一阶段考虑样本标签和数据结构的判别信息,通过学习一个共享投影变换,使投影后的共享空间中边缘分布的差异最小.第二阶段利用源域标记数据和目标域非标记数据学习一个带结构风险的自适应分类器,不仅能最小化源域和目标域条件分布差异,还能进一步保持源域和目标域边缘分布的流形一致性.在3个基准数据集上的实验表明,文中方法在平均分类准确率和Kappa系数两项评价指标上均表现较优. 相似文献
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37.
Huimin Zhao Wensi Wang Yunmei Du Yu Yang Minghui Wang Shaoxiang Li Ruixin Chen Yanru Liu Lei Wang 《International Journal of Hydrogen Energy》2021,46(18):10763-10772
In this work, we synthesized Se doped MoS2@Ni3S2 with nanosheets coated nanorods structure supported on Ni foam (MoNiSeS). Firstly, MoS2@Ni3S2 (MoNiS) nanorods was synthesized by hydrothermal method. After selenization treatment, MoSe2 successfully formed on the edge of MoS2 nanosheets and particle Ni3S2 transformed into NiSe, in which MoSe2 and NiSe acted as new phase in MoNiSeS. The obtained MoNiSeS only needs a low overpotential of 68 mV to reach the current density of 10 mA cm?2, and has a low Tafel plots of 72.77 mV dec?1 and good electrochemical durability, whose electrochemical activity is much better than that of MoNiS and NiSeS, implying the introduction of Mo and Se is beneficial to improve the electrocatalytic performance of NiS for HER. In addition, the proper amount of Mo source, which has an effect on the morphology of product, has also been investigated. For MoNiSeS, the typical nanosheets coated nanarods expose more active sites and the synergic effects is good to the improvement of the catalytic activity. Meanwhile, WNiSeS has also been prepared using the same method and the corresponding results show that the electrochemical activity of WNiSeS is much better than that of NiSeS, proving the universality of this strategy. 相似文献
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40.
以2,6-二甲基苯胺为原料,通过重氮化反应制备2,6-二甲基苯腈,经水蒸汽蒸馏法提纯后,采用75%硫酸酸化,再经酸碱法对产物进行脱色和纯化得产物2,6-二甲基苯甲酸,总收率68.4%。工艺简单、操作安全、适合工业化生产。 相似文献