Multi-Fidelity High-Throughput Optimization of Electrical Conductivity in P3HT-CNT Composites

Combining high-throughput experiments with machine learning accelerates materials and process optimization toward user-specified target properties. In this study, a rapid machine learning-driven automated flow mixing setup with a high-throughput drop-casting system is introduced for thin film preparation, followed by fast characterization of proxy optical and target electrical properties that completes one cycle of learning with 160 unique samples in a single day, a > 10 ×  improvement relative to quantified, manual-controlled baseline. Regio-regular poly-3-hexylthiophene is combined with various types of carbon nanotubes, to identify the optimum composition and synthesis conditions to realize electrical conductivities as high as state-of-the-art 1000 S cm⁻¹. The results are subsequently verified and explained using offline high-fidelity experiments. Graph-based model selection strategies with classical regression that optimize among multi-fidelity noisy input-output measurements are introduced. These strategies present a robust machine-learning driven high-throughput experimental scheme that can be effectively applied to understand, optimize, and design new materials and composites.     

一种空管S波段30 kW固态发射机的设计

介绍了一种S波段30 kW空管雷达固态发射机的性能指标,阐述了发射机射频链路、监控保护、电源和冷却各部分的设计特点和实现方法;其次,针对空管雷达发射机的特殊需求,描述了在线更换技术和数字化检测技术;最后给出了发射机性能测试结果.本发射机的成功研制,可为今后其他固态发射机设计提供参考.     

Ad hoc网络中一种基于身份的组密钥协商协议

移动Ad hoc网络是一种资源有限的移动多跳无线网络。在网络中构建组密钥协商协议时应尽可能地减少资源开销。文中在基于身份的网络安全环境下,设计了一种基于环状结构的组密钥协商协议。该协议采用椭圆曲线上的双线性配对,仅通过单轮通信完成组密钥协商。经过分析,该协议具有等献性,已知密钥安全,无密钥控制等安全属性,适用于Ad hoc网络。     

数字射频存储器在脉冲多普勒雷达噪声干扰中的应用

采用数字射频存储器(DRFM)技术的噪声干扰机,具有瞄频精度高、噪声带宽窄、干扰功率利用率高的特点,可对脉冲多普勒(PD)雷达实施有效干扰。介绍了DRFM干扰机的组成和工作原理。并分析了瞄频误差和寄生信号的产生以及它们对干扰噪声的影响。     

线性调频信号2-D到达角估计的虚拟阵元法

通过原始数据的共轭重排构造了虚拟阵列，利用实际阵列与虚拟阵列的互Wigner-Ville分布建立了新的空间时频分布，并给出了基于子空间投影和L-阵列的线性调频信号2-D到达角估计算法。理论分析和仿真实验证明了算法的有效性。     

Virtual RF system platform dedicated to heterogeneous complex SoC design

In this paper, we propose to develop a hierarchical library associated with various simulators that can be used in a single platform, called TrustMe-ViP, which enables a unique simulation framework and full model interoperability. Such platform is dedicated to complex SoC design, such as trusted personal devices where cost and time-to-market are very important constraints. To validate this methodology, we present the estimation of BER and power consumption for a Bluetooth transceiver.     

钝感三基发射药的燃烧性能

针对含水溶性组份硝基胍(NGu)的三基发射药,采用水相搅拌工艺制备出钝感发射药样品,进行了高分子钝感技术研究。通过扫描电镜研究了加入饱和剂和未加入饱和剂的两种钝感发射药样品的表面状态。结果表明,与未加入饱和剂的钝感工艺相比较,采用添加饱和剂的钝感工艺制得的发射药表面结构致密。采用可控点火参量模拟装置进行点火试验;在药室容积100cm3,装填密度0.2g.cm-3,点火压力10MPa的条件下进行了密闭爆发器试验;选用14.5mm弹道枪进行了内弹道试验。结果表明,钝感处理后的发射药样品点火延迟时间(6.86,5.72ms)延长,燃烧渐增性能增强,内弹道性能提高,且添加饱和剂的发射药性能比未添加饱和剂的优良。     

实验设备运行状况监测系统的设计与实现

针对高校设备利用率低的现象,提出了一种基于电流监测的实验设备运行状况监测系统实现方法。系统以STC12C5A60S2为电流监测模块控制器。结合Zigbee和485总线通信方式,将实验设备运行状况的信息进行集中管理,以较小的代价,大大简化了监督实验设备使用情况的工作流程,给管理人员提供了极大的便利。经过测试表明,该系统可以运行正常、稳定,可以适应断电等情况,完全满足设计需求,具有较高的推广应用价值。     

The Effect of Ageing on Exciton Dynamics,Charge Separation,and Recombination in P3HT/PCBM Photovoltaic Blends

A study of how light‐induced degradation influences the fundamental photophysical processes in the active layer of poly(3‐hexylthiophene)/[6,6]‐phenyl C₆₁‐butyric acid methyl ester (P3HT/PCBM) solar cells is presented. Non‐encapsulated samples are systematically aged by exposure to AM 1.5 illumination in the presence of dry air for different periods of time. The extent of degradation is quantified by the relative loss in the absorption maximum of the P3HT, which is varied in the range 0% to 20%. For degraded samples an increasing loss in the number of excitons within the P3HT domains is observed with longer ageing periods. This loss occurs rapidly, within the first 15 ps after photoexcitation. A more pronounced decrease in the population of polarons than excitons is observed, which also occurs on a timescale of a few picoseconds. These observations, complemented by a quantitative analysis of the polaron and exciton population dynamics, unravel two primary loss mechanisms for the performances of aged P3HT/PCBM solar cells. One is an initial ultrafast decrease in the polaron generation, apparently not related to the exciton diffusion to the polymer/fullerene interface; the second, less significant, is a loss in the exciton population within the photoexcited P3HT domains. The steady‐state photoinduced absorption spectra of degraded samples exhibits the appearance of a signal ascribed to triplet excitons, which is absent for non‐degraded samples. This latter observation is interpreted considering the formation of degraded sites where intersystem crossing and triplet exciton formation is more effective. The photovoltaic characteristics of same blends are also studied and discussed by comparing the decrease in the overall power conversion efficiency of solar cells.     

Conjugated Polymer Based Nanoparticles as Dual‐Modal Probes for Targeted In Vivo Fluorescence and Magnetic Resonance Imaging

A facile strategy is developed to synthesize dual‐modal fluorescent‐magnetic nanoparticles (NPs) with surface folic acid by co‐encapsulation of a far‐red/near‐infrared (FR/NIR)‐emissive conjugated polymer (PFVBT) and lipid‐coated iron oxides (IOs) into a mixture of poly(lactic‐co‐glycolic‐acid)‐poly(ethylene glycol)‐folate (PLGA‐PEG‐FOL) and PLGA. The obtained NPs exhibit superparamagnetic properties and high fluorescence, which indicates that the lipid coated on IOs is effective at separating the conjugated polymer from IOs to minimize fluorescence quenching. These NPs are spherical in shape with an average diameter of ≈180 nm in water, as determined by laser light scattering. In vitro studies reveal that these dual‐modal NPs can serve as an effective fluorescent probe to achieve targeted imaging of MCF‐7 breast cancer cells without obvious cytotoxicity. In vivo fluorescence and magnetic resonance imaging results suggest that the NPs are able to preferentially accumulate in tumor tissues to allow dual‐modal detection of tumors in a living body. This demonstrates the potential of conjugated polymer based dual‐modal nanoprobes for versatile in vitro and in vivo applications in future.