低价硫化铝法从氧化铝直接炭还原制铝的动力学研究

低价硫化铝法从氧化铝直接炭还原制铝的动力学过程极为复杂,过程的前期受界面化学反应控制,过程后期受扩散过程控制,并求得不同时期的活化能,反应前期:E1=63.81 kJ/mol(6.67 Pa)、E2=50.82 kJ/mol(66.7 Pa)、E3=54.72 kJ/mol(666.7 Pa)、E4=39.61 kJ/mol(1333 Pa);反应后期:E*1=112.90 kJ/mol(6.67 Pa)、E*2=89.92 kJ/mol(66.7 Pa)、E*3=97.32 kJ/mol(666.7 Pa)、E*4=51.83 kJ/mol(1333 Pa).从动力学的角度提出了反应的较佳条件.温度、真空度的提高一方面可增大反应速率,但另一方面却加大了硫化铝的挥发,仅从增大速率而言,温度应大于1100 ℃,真空度应优于1333 Pa为宜.     

用分解法编制轴类零件图程序

采用分解法编写轴类零件程序，即将具有典型结构的轴分解成若干部分，把每一部分编成通用子程序，连同尺寸标注子程序、表面粗糙度子程序、剖面线子程序、尺寸公差及形位公差子程序等一并存贮在程序库中，需要时一一调用。     

Surface tailoring of an ethylene propylene diene elastomeric terpolymer via plasma‐polymerized coating of tetramethyldisiloxane

In the research presented here, we explore the use of a low‐energy plasma to deposit thin silicone polymer films using tetramethyldisiloxane (TMDSO) (H(CH₃)₂? Si? O? Si? (CH₃)₂H) on the surface of an ethylene propylene diene elastomeric terpolymer (EPDM) in order to enhance the surface hydrophobicity, lower the surface energy and improve the degradation/wear characteristics. The processing conditions were varied over a wide range of treatment times and discharge powers to control the physical characteristics, thickness, morphology and chemical structure of the plasma polymer films. Scanning electron microscopy (SEM) shows that pore‐free homogeneous plasma polymer thin films of granular microstructure composed of small grains are formed and that the morphology of the granular structure depends on the plasma processing conditions, such as plasma power and time of deposition. The thicknesses of the coatings were determined using SEM, which confirmed that the thicknesses of the deposited plasma‐polymer films could be precisely controlled by the plasma parameters. The kinetics of plasma‐polymer film deposition were also evaluated. Contact angle measurements of different solvent droplets on the coatings were used to calculate the surface energies of the coatings. These coatings appeared to be hydrophobic and had low surface energies. X‐ray photoelectron spectroscopy (XPS) and photoacoustic Fourier‐transform infrared (PA‐FT‐IR) spectroscopy were used to investigate the detailed chemical structures of the deposited films. The optimum plasma processing conditions to achieve the desired thin plasma polymer coatings are discussed in the light of the chemistry that takes place at the interfaces. Copyright © 2004 Society of Chemical Industry     

Protocol design for scalable and reliable group rekeying

We present the design and specification of a protocol for scalable and reliable group rekeying together with performance evaluation results. The protocol is based upon the use of key trees for secure groups and periodic batch rekeying. At the beginning of each rekey interval, the key server sends a rekey message to all users consisting of encrypted new keys (encryptions, in short) carried in a sequence of packets. We present a scheme for identifying keys, encryptions, and users, and a key assignment algorithm that ensures that the encryptions needed by a user are in the same packet. Our protocol provides reliable delivery of new keys to all users eventually. It also attempts to deliver new keys to all users with a high probability by the end of the rekey interval. For each rekey message, the protocol runs in two steps: a multicast step followed by a unicast step. Proactive forward error correction (FEC) multicast is used to reduce delivery latency. Our experiments show that a small FEC block size can be used to reduce encoding time at the server without increasing server bandwidth overhead. Early transition to unicast, after at most two multicast rounds, further reduces the worst-case delivery latency as well as user bandwidth requirement. The key server adaptively adjusts the proactivity factor based upon past feedback information; our experiments show that the number of NACKs after a multicast round can be effectively controlled around a target number. Throughout the protocol design, we strive to minimize processing and bandwidth requirements for both the key server and users.     

Mesoscale simulation of block copolymers in aqueous solution: parameterisation, micelle growth kinetics and the effect of temperature and concentration morphology

In this work, we utilise ‘MesoDyn’ [J Chem Phys 99 (1993) 9202; 106 (1997) 4260] density functional simulations to study the effect of temperature and concentration on the micellar morphology of polymeric surfactants. Parameterisation strategies based upon atomistic models and experimental data are discussed. Taking the temperature dependence of interaction energy into account, the change in morphology of Pluronic (PEO-PPO-PEO) block copolymer structure with temperature is well reproduced. As a function of concentration, the diameter of spherical micelles is found to increase in line with previous cryo-TEM observations [Phys Chem Chem Phys 1 (1999) 3331]. Simulations of high concentration PEO-PBO diblock systems show ordering similar to the face-centered cubic structures found experimentally [J Polym Sci B 33 (1995) 1085; Macromolecules 30 (1997) 5721; Polymer 39 (1998) 4891; Phys Chem Chem Phys 1 (1999) 2773].     

(BETS)2[RuX5NO] (X = Cl, Br): An Explanation of Different Conductive Properties Through Structural and Spectroscopic Studies

For the development of new crystal and electronic structures in molecular conductors, dimeric tetrathiafulvalene (TTF) and tetraselenafulvalenes (TSFs)1–3 linked by single or double methyl antimony bridge(s) have been prepared and their neutral crystal structures have been investigated. The donor2 (cis-2) forms a metallic cation radical salt with tetracyanoquinodimethane (TCNQ) containing one-dimensional array interactions.     

高精细数字会聚校正系统

数字会聚校正使1%的会聚精度提高到0.1%以上。本文叙述了数字会聚校正系统的设计要求,工作原理以及设计计算,给出了在投影电视上的试验结果,最后,指出了今后发展的方向。     

Comments on “Multiphase systolic algorithms for spectraldecomposition” [and reply]

Comments that the paper by Liu and Yao (see ibid., vol.40, no.1, p.190, 1992) presented an efficient algorithm for spectral decomposition, but the parallel algorithm and architecture for the Hessenberg reduction has a problem. The matrix obtained from the unitary similarity transformation is not necessarily a Hessenberg matrix. The authors reply that the Hessenberg reduction described is not in the Hessenberg form. Only the first column is in its proper form. There are many ways to overcome such a problem. One simple way is to use the multiphase rectangular systolic array