The Anomalous Optical Conductivity of Metallic La2?xSrxCuO4

The in-plane optical conductivity of three metallic La_2–x Sr _x CuO₄ single crystals with 0.10 x 0.15 has been studied between 30 and 295 K. Strong peaks in the far-infrared are observed, which cannot be explained by Drude-like models. Their similarity with peaks reported in Cu–O ladders with one-dimensional charge-ordering, their extremely low frequency, and their behavior with temperature allows us to conclude that those anomalous features are excitations of charge stripes in the Cu–O planes.     

TEM Observations of the Initial Oxidation Stages of Nb-Ion-Implanted TiAl

Coupon specimens of TiAl were implanted with Nb ions at an acceleration voltage of 50 kV with a dose of 10²¹ ions m.^–2 They were then slightly oxidized during heating to 900 or 1200 K, or at 1200 K for 3.6 ksec (1 hr) in a flow of purified oxygen under atmospheric pressure. The implanted specimens and oxidized specimens were characterized and observed by AES, X-ray diffractometry, SEM, TEM, EDS, and EPMA. Implantation improves the oxidation resistance significantly by forming virtually -Al₂O₃ scales. The implanted layer is about 75 nm thick; the outer part of 30-nm thickness is -Ti phase and the rest of 45-nm thickness is amorphous. Heating to 900 K in O₂ results in partial crystallization of the amorphous layer to Ti₅Al₃O₂ (Z-phase) and to 1200 K results in oxide scales of 270 to 400 nm thickness consisting mainly of Al₂O₃. The fraction of Al₂O₃ in the scale increases toward the substrate. Oxidation at 1200 K for 3.6 ksec results in Al₂O₃-rich scales of about 400-nm thickness. The oxide grain size is very fine, about 80 nm in size, and becomes smaller toward the outer scale surface. This implies that implantation enhanced the nucleation of Al₂O₃ grains relative to the growth of TiO₂ grains. This finding and the formation of -Ti phase are thought to be responsible for the excellent oxidation resistance obtained.     

Effect of temperature on friction observed between a Si3N4 tip and a dodecanethiol self-assembled monolayer on Au(1 1 1)

Recent computational studies (Phys. Rev. Lett. 70 (1993) 1960; Phys. Rev. B 62 (2000) 17055) predicted that friction of ordered organic monolayer had characteristic dependence on temperature, where the maximum friction was observed around rotator transition point of the monolayer. This remained to be confirmed experimentally. Using a friction force microscope (FFM) combined with a temperature regulation module, we attempted to investigate such dependence on temperature (130 K-room temperature) on a self-assembled monolayer of dodecanethiol prepared on Au(1 1 1). The observed friction showed strong dependence on temperature and good agreement with the computational prediction.     

Training of a leaning agent for navigation--inspired by brain-machine interface.

The design clue for the remote control of a mobile robot is inspired by the Talwar's brain-machine interface technology for remotely training and controlling rats. Our biologically inspired autonomous robot control consciousness-based architecture (CBA) is used for the remote control of a robot as a substitute for a rat. CBA is a developmental hierarchy model of the relationship between consciousness and behavior, including a training algorithm. This training algorithm computes a shortcut path to a goal using a cognitive map created based on behavior obstructions during a single successful trial. However, failures in reaching the goal due to errors of the vision and dead reckoning sensors require human intervention to improve autonomous navigation. A human operator remotely intervenes in autonomous behaviors in two ways: low-level intervention in reflexive actions and high-level ones in the cognitive map. Experiments are conducted to test CBA functions for intervention with a joystick for a Khepera robot navigating from the center of a square obstacle with an open side toward a goal. Their statistical results show that both human interventions, especially high-level ones, are effective in drastically improving the success rate of autonomous detours.     

Development of a novel emitting vinyl polymer and its application in organic electroluminescent devices

Abstract— A novel emitting vinyl polymer, poly[4‐(7‐{4‐[N,N‐bis(9,9‐dimethylfluoren‐2‐yl)amino]phenyl}‐2,1,3‐benzothiadiazol‐4‐yl)phenylethylene] (PVFABT), was designed and synthesized. The new vinyl polymer was found to form smooth amorphous films with a high glass‐transition temperature of 199°C. The polymer possesses bipolar character with both electron‐donating and accepting properties. It undergoes reversible anodic oxidation and cathodic reduction to give stable cation and anion radicals. It exhibits intense orange fluorescence in solution and as film. A multilayer organic electroluminescent device using PVFABT as an emitting material emitted orange light, exhibiting high performance.     

Behavior of Buried Flexible Pipe under High Fills and Design Implications

The existing design guidelines for buried flexible pipes are limited to depth up to 10?m. The increasing use of difficult terrains for infrastructure, landfills, and residential and industrial developments has prompted installation of drainage pipelines under 20–30?m high fills. This paper presents the behavior of an instrumented flexible pipe buried under a 47.1?m deep fill. For filling above 20?m, the measured vertical stress above the pipe exhibited a concave distribution, corresponding to 90 and 110% of the average vertical pressure at the center and edges of the pipe, respectively. The measured results suggest that a triangular lateral pressure distribution can lead to overly conservative and uneconomical results for high fills while Spangler’s analysis is unconservative. Based on the measured results, a revised vertical and lateral earth pressure diagram was proposed for the design of flexible pipe under high fills >20?m. This paper proposes closed-form analyses for estimating the moments and displacements of the pipe subjected to high fill earth pressures. These closed-form solutions agree well with the measured pipe displacements and strains.     

The road to RoboCup 2050

The ultimate goal of the RoboCup initiative is stated as follows: by mid-21st century, a team of fully autonomous humanoid robot soccer players shall win the soccer game, comply with the official rule of the FIFA, against the winner of the most recent World Cup. The authors consider this goal from the perspective of how close we are to it and what has to be done to reach it     

Impurity scattering effect on the anisotropic resistivity for La2−x Sr x CuO4−δ with a wide range of x

We have investigated the effect of the impurity scattering due to a small amount of oxygen defect, ( < 0.01) on the anisotropic resistivity of La _2–x Sr _x CuO _4– in a wide x range up to x = 0.26. In the superconducting region with 0.06 x 0.22, we found that impurity scattering by the oxygen defect remarkably decreases the c-axis resistivity c over the whole temperature range. The finding is interpreted in terms of the nonmetallic conduction along the c axis which is enhanced by scattering the confined carriers in the CuO ₂ plane. On the other hand, the enhancement of the c-axis conduction diminishes in the nonsuperconducting region. This is consistent with the two-dimensional nature of the electronic state which stabilizes the superconducting ground state in the cuprates.     

Electronic Structures of Two-Phase Microstructures in Pb-doped Bi2Sr2CaCu2O y

We have performed scanning tunneling microscopy/spectroscopy (STM/STS) on single crystals of heavily Pb-doped Bi ₂ Sr ₂ CaCu ₂ O _y (Pb-Bi2212). The obtained STM images clearly demonstrated phase separation into the and phases with lamella-type and new zigzag-like microstructures. From the site-specified tunneling measurements, it was directly confirmed that the phase possesses higher T _c . This suggests that the phase boundaries act as strong pinning sites especially at higher temperatures.