全文获取类型
收费全文 | 1705篇 |
免费 | 79篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 89篇 |
综合类 | 3篇 |
化学工业 | 394篇 |
金属工艺 | 49篇 |
机械仪表 | 31篇 |
建筑科学 | 45篇 |
能源动力 | 89篇 |
轻工业 | 158篇 |
水利工程 | 10篇 |
石油天然气 | 3篇 |
无线电 | 146篇 |
一般工业技术 | 350篇 |
冶金工业 | 206篇 |
原子能技术 | 43篇 |
自动化技术 | 174篇 |
出版年
2023年 | 6篇 |
2022年 | 32篇 |
2021年 | 53篇 |
2020年 | 22篇 |
2019年 | 44篇 |
2018年 | 38篇 |
2017年 | 36篇 |
2016年 | 48篇 |
2015年 | 48篇 |
2014年 | 60篇 |
2013年 | 106篇 |
2012年 | 99篇 |
2011年 | 137篇 |
2010年 | 88篇 |
2009年 | 95篇 |
2008年 | 106篇 |
2007年 | 78篇 |
2006年 | 59篇 |
2005年 | 64篇 |
2004年 | 49篇 |
2003年 | 49篇 |
2002年 | 32篇 |
2001年 | 26篇 |
2000年 | 21篇 |
1999年 | 18篇 |
1998年 | 82篇 |
1997年 | 51篇 |
1996年 | 40篇 |
1995年 | 23篇 |
1994年 | 26篇 |
1993年 | 19篇 |
1992年 | 17篇 |
1991年 | 5篇 |
1990年 | 10篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1987年 | 9篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 9篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 3篇 |
排序方式: 共有1790条查询结果,搜索用时 31 毫秒
61.
62.
Hyun Soon Park Yasukazu Murakami Keiichi Yanagisawa Tsuyoshi Matsuda Ryosuke Kainuma Daisuke Shindo Akira Tonomura 《Advanced functional materials》2012,22(16):3434-3437
Peculiar magnetic domain walls produced in Heusler alloys, which have attracted renewed interest due to their potential application to actuators and spintronic devices, are studied here using electron holography. The observations reveal unexpectedly narrow magnetic domain walls, the width of which showed perfect agreement with that of the antiphase boundaries (APB, e.g., only 3 nm). While the results can be explained by the significant depression of ferromagnetism due to the local chemical disorder, the electron phase shift indicates that ferromagnetic correlation still remains in the APB region. 相似文献
63.
Daisuke Kawashima Yutaka Asako 《International Journal of Heat and Mass Transfer》2012,55(9-10):2244-2248
This paper focuses on temperature rise due to the viscous dissipation in liquids flowing through micro-channels. In the past, equations for the prediction of the temperature rise have been obtained as a function of the friction factor, Reynolds number and Eckert number or a similar form, starting from Navier–Stokes equation and energy equation under the assumption of fully developed laminar flow by researchers. The temperature rises calculated from the equations have been compared with experimental data and the equations have been validated. However, in this paper, a new equation for the prediction of the temperature rise is simply obtained from the first law of thermodynamics without restriction of fully developed laminar flow. 相似文献
64.
Daisuke Yamamoto Takeshi Ozaki Carlos A. R. Sá de Melo Ippei Danshita 《Journal of Low Temperature Physics》2014,175(1-2):258-264
We study a first-order phase transition between superfluid and Mott insulator phases in binary Bose mixtures loaded into a hypercubic optical lattice. The system is described by a two-component Bose-Hubbard model. Considering the difference between the two kinds of bosons in the intra-component interaction strength, we discuss the metastability of the system and the hysteresis associated with the first-order superfluid-Mott insulator transition. It is found that the sweeping of hopping amplitude induces a conventional hysteresis-loop behavior. We also find an anomalous hysteresis behavior when the chemical potential is varied. In the anomalous hysteresis, the phase transition occurs in a unidirectional way and a hysteresis loop does not form. 相似文献
65.
66.
Discovery of a Novel Scaffold as an Indoleamine 2,3‐Dioxygenase 1 (IDO1) Inhibitor Based on the Pyrrolopiperazinone Alkaloid,Longamide B
下载免费PDF全文
![点击此处可从《ChemMedChem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Zenyu Shiokawa Emi Kashiwabara Daisuke Yoshidome Prof. Dr. Koichi Fukase Dr. Shinsuke Inuki Prof. Dr. Yukari Fujimoto 《ChemMedChem》2016,11(24):2682-2689
Indoleamine 2,3‐dioxygenase 1 (IDO1) has emerged as a key target for cancer therapy, as IDO1 plays a critical role in the capacity of tumor cells to evade the immune system. The pyrrolopiperazinone alkaloid longamide B and its derivatives were identified as novel IDO1 inhibitors based on docking studies and small library synthesis. The thioamide derivative showed higher IDO1 inhibitory activity than longamide B, and displayed an activity similar to that of a representative IDO1 inhibitor, 1‐methyl‐tryptophan. These results suggest that the pyrrolopiperazinone scaffold of longamide B could be used in the development of IDO1 inhibitors. 相似文献
67.
Tsukaho Yahagi Daisuke Kawai Takuma Takahashi Motoyuki Iijima Junichi Tatami 《Journal of the American Ceramic Society》2022,105(3):2046-2057
Si3N4 ceramics with excellent mechanical properties are used for heat dissipation substrates and so on. In order to improve their reliability and expand their application fields, it is desirable to understand and control the electrical properties of Si3N4 ceramics. In this study, the electrical resistivity of Si3N4 ceramics with Yb2O3 additive was investigated by applying various voltages at temperatures ranging from 25°C to 300°C. When Yb2O3 was added as a sintering aid to Si3N4 ceramics, a crystalline J-phase (Yb4Si2O7N2) was formed and their electrical resistivity was significantly lower than that of Y2O3 additive. The electrical resistivity of the Yb2O3-added ceramics decreased with an increase in temperature and applied voltage. Yb existed in multiple valence states, Yb2+ and Yb3+, in the Si3N4 ceramics and the decrease in the electrical resistivity can be attributed hopping conduction through the J-phase. The J-phase in the Si3N4 ceramics was observed to be continuous, and percolation analysis suggested that the J-phase formed an infinite cluster. Therefore, the decrease in the electrical resistivity of the Yb2O3-added Si3N4 ceramics was found mainly to result from the formation of an infinite cluster of J-phase, which exhibits hopping conduction. 相似文献
68.
Highly monodisperse polystyrene nanoparticles with mean diameters of less than 100 nm are synthesized via aqueous emulsion polymerization using an amphoteric initiator (VA-057) in the presence of sub-millimolar concentrations of anionic surfactant. Since the net charge on the initiator is almost zero at neutral pH, the resultant latex particle size is mainly determined by surfactant adsorption. Polymerizations were performed in the presence of a range of anionic surfactants with differing critical micelle concentrations (CMC) by varying the concentrations of surfactant, initiator and monomer, and also the ionic strength. Sodium dodecyl benzene sulfonate (SDBS), sodium hexadecyl sulfate (SHS), and sodium octadecyl sulfate (SOS) have relatively low CMCs and so enable formation of highly monodisperse nanoparticles at relatively low (sub-millimolar) surfactant concentrations, CS (i.e. below the CMC in each case). Empirically, it was found that the particle number, Np, and coefficient of variation of the particle size, CV, were strongly dependent on the CS/CMC ratio: Np increased almost in proportion with the square of this ratio, while the CV exhibited a minimum at approximately CS/CMC = 0.20. Higher ionic strength reduced the particle size, which is consistent with the above relationship because the addition of salt lowers the CMCs of ionic surfactants. Polymer latex particles produced using such formulations form highly regular, close-packed colloidal arrays. 相似文献
69.
A series of hyper-branched polyimide (HBPI)/mesoporous SiO2 nanocomposite films were prepared from a fluorinated anhydride (6FDA), a fluorinated triamine (TFAPOB), and mesoporous SiO2 nanoparticles (NPs). The anhydride-terminated precursor of HBPI was functionalized using a coupling agent prior to mixing with SiO2 NPs. The morphologies and thermal-optical properties of the nanocomposite films were investigated, with particular focus on their optical transparency, refractive indices (n), and thermo-optical (TO) coefficients. The absolute values of TO coefficients (|dn/dT|) of HBPI film (50.8 ppm/K) were significantly reduced to 13.4 ppm/K by homogeneous dispersion of 15 wt% of SiO2 NPs. The HBPI/SiO2 composite films exhibited high thermal stability without significant weight loss of up to 400 °C in air. The films also exhibited small coefficients of linear thermal expansion (CTEs) within the range 30–40 ppm/K. In addition, enhanced interfacial interactions between SiO2 and HBPI significantly improve the optical transparency with cutoff wavelengths shorter than 450 nm. The refractive indices of HBPI/SiO2 composite films were found to range from 1.477 to 1.502, which agrees well with the calculated values. This study shows that the incorporation of SiO2 NPs in multi-functional HBPI matrix is a promising approach to prepare high performance thermally stable films for thermo-optic applications. 相似文献
70.
Hisatoyo Morinaga Yoshihide Kiyokawa Ryosuke Fujikawa Daisuke Nagai Hiroshi Morikawa 《Polymer Bulletin》2014,71(9):2421-2435
Partially biobased polyamphiphile-bearing reactive epoxy groups in the side chains were obtained in 62–78 % yields by a radical copolymerization of limonene oxide (LO) and PEG methylacrylate (PEGA) with different feed ratios. Degree of LO incorporation into the copolymer was determined as 12–23 % by 1H NMR spectroscopic analysis. The copolymer having LO unit:PEGA unit = 19:81 formed polymer associates in water, particle diameter of which was ranged mainly from 4 to 66 nm and hydrodynamic mean diameter was 12.3 nm. Its critical micelle concentration was determined as 0.53 g/L by fluorescence spectroscopic analysis. A cross-linking reaction of the epoxy groups in the side chains was conducted with 3.97 mol% (to the epoxy group) of branched poly(ethylene imine) as a cross-linker to give the corresponding hydrogel in 56 % yield. The hydrogel can absorb water as much as 13 times its own mass. 相似文献