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151.
The hydroxyl radical (HO(?)) is a strong oxidant that reacts with electron-rich sites on organic compounds and initiates complex radical chain reactions in aqueous phase advanced oxidation processes (AOPs). Computer based kinetic modeling requires a reaction pathway generator and predictions of associated reaction rate constants. Previously, we reported a reaction pathway generator that can enumerate the most important elementary reactions for aliphatic compounds. For the reaction rate constant predictor, we develop linear free energy relationships (LFERs) between aqueous phase literature-reported HO(?) reaction rate constants and theoretically calculated free energies of activation for H-atom abstraction from a C-H bond and HO(?) addition to alkenes. The theoretical method uses ab initio quantum mechanical calculations, Gaussian 1-3, for gas phase reactions and a solvation method, COSMO-RS theory, to estimate the impact of water. Theoretically calculated free energies of activation are found to be within approximately ±3 kcal/mol of experimental values. Considering errors that arise from quantum mechanical calculations and experiments, this should be within the acceptable errors. The established LFERs are used to predict the HO(?) reaction rate constants within a factor of 5 from the experimental values. This approach may be applied to other reaction mechanisms to establish a library of rate constant predictions for kinetic modeling of AOPs. 相似文献
152.
We observed the photo-decomposition process of polystyrene latex (PSL) spheres on a rutile TiO?(110) single crystal surface by using atomic force microscopy. During the decomposition process, both the height and width of the PSL spheres linearly decreased with the irradiation time in a similar way from the beginning, suggesting that the PSL spheres are isotropically decomposed. This indicates that the interface between the PSL spheres and the TiO? surface is not a dominant reaction site, as expected from normal photocatalytic reactions. 相似文献
153.
Dynamic deformation measurement with a large deformation is effectively performed by using virtual speckle patterns. The virtual
speckle pattern has been generally produced by using the operation based on Fourier transform. However, it takes a long calculating
time to produce a virtual speckle pattern, because the method requires Fourier transform operation at each pixel of CCD. In
the proposed method, virtual speckle patterns are produced by Carré algorithm without any operation by Fourier transform.
The method is applied to the in-plane deformation measurement in this paper. As the results, it is confirmed that the calculating
cost of virtual speckle patterns is improved remarkably, and that the measurement accuracy of the new method is also equal
to the ordinary methods. It is also confirmed that the proposed method will expand the use of the speckle interferometry based
on virtual speckle pattern technology. 相似文献
154.
Kazuhiro Yamamoto Satoshi Inoue Hiroshi Yamashita Daisuke Shimokuri Satoru Ishizuka Yoshiaki Onuma 《亚洲传热研究》2006,35(7):501-512
We have investigated turbulent combustion by PIV (Particle Image Velocimetry) technique. Comparing with LDV data, the validity of PIV measurements has been confirmed. Particularly, the conditions of sampling number and spatial resolution have been shown to yield reliable data using PIV. Based on the velocity fields in cold flow and combustion, the interaction between flame and flow has been discussed. It was observed that the flow field is changed by combustion and the turbulence is reduced. In order to determine statistical quantities such as mean velocity and RMS of velocity fluctuation, a sampling number of 1000 is needed. Moreover, the velocity correlation coefficient was evaluated to obtain the integral length scale of the flow. For both cold flow and combustion, the PIV estimated scale is very close to that of LDV based on the assumption of Taylor's hypothesis. As a result, the spatial resolution in this study is about 6 times smaller than the integral length scale. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(7): 501–512, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20129 相似文献
155.
Preparation and properties of CuInS2 thin film prepared from electroplated precursor 总被引:1,自引:1,他引:1
Yoshio Onuma Kenji Takeuchi Sumihiro Ichikawa Yasunari Suzuki Ryo Fukasawa Daisuke Matono Kenji Nakamura Masao Nakazawa Koji Takei 《Solar Energy》2006,80(1):132-138
Thin CuInS2 films were prepared by sulfurization of Cu/In bi-layers. First, the precursor layer was electroplated onto the treated surface of Mo-coated glass. Observation of the cross-section prepared by focused ion beam (FIB) etching revealed that the void-free film was initially formed on the top surface of the precursor layer and continued to grow until the advancing front of the film reached the Mo layer. The nucleation of voids near the bottom of the CuInS2 film followed. To determine whether the condition of the Cu/In alloy influences the CuInS2 quality we investigated the Cu/In alloy state using FIB. We found that the annealed precursor of low Cu/In ratio (1.2) has several voids in the mid position in the layer compared with Cu-rich precursor (1.6). The cross-sectional view of the Cu-rich absorber layer is uniform compared with the low copper absorber layer. Thin film solar cells were fabricated using the CuInS2 film (Cu/In ratio: 1.2) as an optical absorber layer. It was found that the optimization of a sulfurization period is important in order to improve the cell efficiency. We have not yet obtained good results with high Cu-rich absorber because of a blister problem. This blister was found before sulfurization. So, we are going to solve this blister problem before sulfurization. 相似文献
156.
Satoru Yamamoto Daisuke Niiyama Byeong Rog Shin 《International Journal of Heat and Mass Transfer》2004,47(26):774-5792
Natural convection around a horizontal circular pipe coupled with heat conduction in the solid structure is numerically investigated using a preconditioning method for solving incompressible and compressible Navier–Stokes equations. In this method, fundamental equations are completely reduced to an equation of heat conduction when the flow field is static (zero velocity). Therefore, not only compressible flows but also very slow flows such as natural convection in a flow field and heat conduction in a static field can be simultaneously calculated using the same computational algorithm. In this study, we first calculated the compressible flow around a NACA0012 airfoil with conduction in the airfoil and then simulated natural convections around a horizontal circular pipe with a different heat conductivity. Finally, we numerically investigated the effect of heat conductivity of the pipe on natural convection. 相似文献
157.
Kameyama S Imaki M Hirano Y Ueno S Kawakami S Sakaizawa D Kimura T Nakajima M 《Applied optics》2011,50(14):2055-2068
A feasibility study is carried out on a 1.6 μm continuous-wave modulation laser absorption spectrometer system for measurement of global CO(2)concentration from a satellite. The studies are performed for wavelength selection and both systematic and random error analyses. The systematic error in the differential absorption optical depth (DAOD) is mainly caused by the temperature estimation error, surface pressure estimation error, altitude estimation error, and ON wavelength instability. The systematic errors caused by unwanted backscattering from background aerosols and dust aerosols can be reduced to less than 0.26% by using a modulation frequency of around 200 kHz, when backscatter coefficients of these unwanted backscattering have a simple profile on altitude. The influence of backscattering from cirrus clouds is much larger than that of dust aerosols. The transmission power required to reduce the random error in the DAOD to 0.26% is determined by the signal-to-noise ratio and the carrier-to-noise ratio calculations. For a satellite altitude of 400 km and receiving aperture diameter of 1 m, the required transmission power is approximately 18 W and 70 W when albedo is 0.31 and 0.08, respectively; the total measurement time in this case is 4 s, which corresponds to a horizontal resolution of 28 km. 相似文献
158.
Daisuke Watanabe Keishi Nishio Yoshio Sakka Masataka Ohgaki Ian J. Davies Tomohiro Umeda Seiichiro Koda Kiyoshi Itatani 《Journal of Materials Science》2011,46(6):1956-1962
High-density β-calcium orthophosphate (β-Ca3(PO4)2, also called β-tricalcium phosphate: β-TCP) ceramics with submicrometer-sized grains were fabricated using a pulse-current
pressure firing route. The maximum relative density of the β-TCP compacts was 98.7% at 1050 °C and this was accompanied by
a translucent appearance. The mean grain size of the β-TCP compacts increased slightly with temperature to reach 0.78 μm at 1000 °C. However, upon further increasing the firing
temperature to 1050 °C the mean grain size increased significantly to 1.6 μm. The extent of plastic deformation during tensile
testing was examined at temperatures between 900 and 1100 °C using a strain rate in the range 9.26 × 10−5 to 4.44 × 10−4 s−1. The maximum tensile strain achieved was 145% for a test temperature of 1000 °C and strain rate of 1.48 × 10−4 s−1 and this was attributed to the relatively high density and small grain size. 相似文献
159.
Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion
Tatsuya Miyazaki Daisuke Terada Yoji Miyajima Challapalli Suryanarayana Reiko Murao Yoshihiko Yokoyama Kazumasa Sugiyama Minoru Umemoto Yoshikazu Todaka Nobuhiro Tsuji 《Journal of Materials Science》2011,46(12):4296-4301
The structural changes in mechanically mixed metals of immiscible combinations of elements caused by bulk mechanical alloying
(MA) through the use of high pressure torsion (HPT) were investigated in Ag–Ni and Nb–Zr systems. There was no alloying between
Ag and Ni on atomic scale even after 100 rotations of HPT. On the other hand, the β-Zr phase started to appear after HPT 2
rotations in the Nb–Zr system, even though β-Zr is a high temperature phase. Further, Nb and Zr were completely mixed to form
a bcc structured single phase after HPT 100 rotations. The sequence of alloying in the Nb–Zr system during HPT was discussed.
These results clearly suggest that non-equilibrium phases can form in the Nb–Zr system by bulk MA by the use of HPT. 相似文献
160.
Dhinesh Babu Velusamy Richard Hahnkee Kim Kazuto Takaishi Tsuyoshi Muto Daisuke Hashizume Soyoon Lee Masanobu Uchiyama Tetsuya Aoyama Jean-Charles Ribierre Cheolmin Park 《Organic Electronics》2014,15(11):2719-2727
Polymer ferroelectric-gate field effect transistors (Fe-FETs) employing ferroelectric polymer thin films as gate insulators are highly attractive as a next-generation non-volatile memory. For minimizing gate leakage current of a device which arises from electrically defective ferroelectric polymer layer in particular at low operation voltage, the materials design of interlayers between the ferroelectric insulator and gate electrode is essential. Here, we introduce a new solution-processed interlayer of conductive reduced graphene oxides (rGOs) modified with a conjugated block copolymer, poly(styrene-block-paraphenylene) (PS-b-PPP). A FeFET with a solution-processed p-type oligomeric semiconducting channel and ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) insulator exhibited characteristic source–drain current hysteresis arising from ferroelectric polarization switching of a PVDF-TrFE insulator. Our PS-b-PPP modified rGOs (PMrGOs) with conductive moieties embedded in insulating polymer matrix not only significantly reduced the gate leakage current but also efficiently lowered operation voltage of the device. In consequence, the device showed large memory gate voltage window and high ON/OFF source–drain current ratio with excellent data retention and read/write cycle endurance. Furthermore, our PMrGOs interlayers were successfully employed to FeFETs fabricated on mechanically flexible substrates with promising non-volatile memory performance under repetitive bending deformation. 相似文献