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Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder. 相似文献
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Jinpeng Zhang Hongfeng Gao Nini Yuan Qiang Wang Yuhua Wu Yanli Sun Hongcun Bai 《中国化学工程学报》1982,28(11):2771-2777
Understanding and modulating the interaction between various reactive molecules and oxygen carriers are the key issue to achieve process intensification of chemical looping technology. C1 chemical molecules play an important role in many reactions involved with chemical looping processes. However, up to now, there is still a lack of systematic and in-depth understanding of the adsorption mechanism of C1 molecules on the surface of oxygen carriers (OCs). In this work, the intrinsic interaction between a series of C1 molecules composed of CH4, CO, CO2, CH3OH, HCHO and HCOOH and surface of NiO OCs in the chemical looping process have been studied using density functional theory calculations. Various adsorption configurations of C1 molecules and also different adsorption sites of NiO have been considered. The structural features of stable configuration of C1 molecules on the surface of NiO OCs have been obtained. Further, the interacted sites, types and strengths of C1 molecules on the surface of NiO have been directly pictured by the independent gradient model methods. Also, the nature of the interaction between C1 molecule and NiO surface has been investigated with the aid of energy decomposition analysis from a quantitative view. 相似文献
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TiB2的SHS合成过程理论分析 总被引:10,自引:4,他引:10
在TiB2陶瓷材料的自蔓延高温合成(简称SHS)过程中,通过改变原料的起始温度,稀释剂的含量和原始颗粒的尺寸等都可以调节合成过程的绝热温度,产物中熔融相的含量,以及燃烧波蔓延的速度,人而最终影响合成产物的结构和性质。本文对上述各种关系进行了理论计算和分析,其结果对实际合成与制备过程将有着重要的指导作用。 相似文献
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Chunnuan Ji Rongjun Qu Cheng Bo Cao Huo Chen Qiang Xu Changmei Sun Chunhua Wang Huafang Yuan Jun Zhou 《应用聚合物科学杂志》2006,102(6):6054-6059
A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg2+, Ag+, Cu2+, Zn2+, and Pb2+ at various pH values were determined. The maximum adsorption capacities for Hg2+ and Ag+ were 1.56 and 0.75 mmol g?1 respectively. The resin had high selectivity for Hg2+ and Ag+ over the pH range 1.0–7.0. The adsorption capacities for Hg2+ and Ag+ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg2+ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006 相似文献
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Yu-Hang Yuan Xing-Gui Zhou Wei Wu Yi-Ran Zhang Wei-Kang Yuan Lingai Luo 《Catalysis Today》2005,105(3-4):544-2
Gas phase propylene epoxidation on gold catalysts has attracted wide attention from industry and academia due to its high selectivity. However, it suffers from low propylene conversion and rapid catalyst deactivation. Experiments showed that propylene conversion could be increased by raising H2, O2, or C3H6 concentration in the feed, but the feed compositions were within the explosion limit. It was also shown that the activity of the used catalyst could be fully recovered, but the regeneration temperature was 280 °C, much higher than that for reaction. Therefore a microchannel reactor was devised to suppress explosion and was constructed with Fecralloy, to raise the temperature rapidly for catalyst regeneration by electric heating. In two minutes the temperature of the reactor could be raised from 50 to 300 °C. Catalysts were coated on the alloy belt by dip coating, and the performance of the reactor was evaluated under different operating conditions. Results showed that in the microreactor the overall reaction rate was controlled mainly by the intrinsic reaction rate, and also influenced by film diffusion to a certain extent. The deactivated catalyst was regenerated in the microchannel reactor and the activity was fully recovered. 相似文献