Biodesulfurization of dibenzothiophene sulfone by Arthrobacter sp. and studies with oxidized Illinois No. 6 coal

A bacterium identified as Arthrobacter sp. was grown on dibenzothiophene (DBT) sulfone as a sole source of sulfur, producing sulfite and sulfate. Sulfur in DBT sulfone (1.0 mM) was nearly quantitatively converted to sulfate by the organism. The organism could also use DBT sulfone as a sole source of carbon and energy. There was evidence for transient accumulation of benzoic acid in the culture medium after growth of the cells slowed. The DBT sulfoxide analogue 9-fluorenone was converted by resting cells to a product identified as 1,10-dihydroxy-1,10-dihydrofluoren-9-one, suggesting that DBT sulfone may be metabolized via an angular hydroxylation resulting in carbon- sulfur bond cleavage. This strain of Arthrobacter showed no ability to desulfurize oxidized Illinois No. 6 coal.     

A bi‐objective approach to reschedule new jobs in a one machine model

We consider a one machine scheduling model, minimizing a classical objective function—either the total completion time or the maximum tardiness—and with two sets of jobs: one with initial jobs already scheduled and one with new jobs that must be inserted in the schedule. As such rescheduling can create a modification of the schedule of the initial jobs, a disruption objective is considered in addition to the original objective. This additional objective can be formulated in four different ways. Such model has been introduced by Hall and Potts, minimizing either a linear aggregation of the two objectives or the initial objective under a constraint giving an upper limit of the disruption objective. In this paper, the aim is to obtain the set of efficient schedules in regard to the two objectives. Algorithms are provided for the eight possible bi‐objective problems and illustrated by some didactic examples.     

Silica to Silicon: Key Carbothermic Reactions and Kinetics

The primary carbothermic reactions for the reduction of silica to produce silicon were defined and the reaction kinetics were determined. Most possible reactions between silicon oxide and carbon or carbon compounds were studied by a series of thermogravimetric analyses at temperatures up to 2000°C. Four key sequential reactions occur with SiC and SiO as intermediate reactants; two reactions involve SiO₂ and two involve SiO. Reaction rate versus temperature, activation energy, and preexponential factors were determined for each of six reactions involving SiO₂ or SiO. These kinetic studies show that SiO, when combined with either carbon or Sic, reacts in the gaseous state, and the sublimation of SiO is not the rate-limiting reaction for forming silicon.     

Effect of plant sterols,fatty acids and lecithin on cholesterol absorption in vivo in the rat

The inhibitory effect of plant sterols, fatty acids and lecithin on cholesterol intestnal absorption was studied in the unanesthetized rat using a single pass perfusion technique. Bile was excluded from the perfused intestine. Cholesterol absorption did not change following the additions of cholestanol, cholestanone, lanosterol, stigmasterol and β-sitosterol. A 3-fold increase in the molarity of cholestanol and β-sitosterol or the separate additions of the saturated short and medium chain fatty acids, butyric and octanoic, also did not change cholesterol absorption. The unsaturated long chain fatty acids, oleic, linoleic, linolenic and arachidonic, inhibited cholesterol absorption. Lecithin additions at concentrations of 0.1–1.5 mM caused a progressive, dose-related inhibition of cholesterol absorption. The inhibitory effect of these agents on cholesterol absorption is likely to have been caused by changes in cholesterol solubility in the micelle and shifts in the partition coefficient of cholesterol away from the cell membrane to the micelle.     

Effect of vibration on eye,head and helmet movements while wearing a helmet‐mounted display

Previous research has demonstrated a loss of helmet‐mounted display (HMD) legibility for users exposed to whole body vibration. A pair of human factors studies was conducted to evaluate the effect of whole body vibration on eye, head, and helmet movements for seated users of a HMD while conducting simple fixation and smooth pursuit tracking tasks. These experiments confirmed that vertical eye motion can be demonstrated, that is consistent with the human visual systems' response to the vestibular–ocular reflex (VOR). Helmet slippage was also shown to occur, which could exacerbate loss of display legibility. The largest amplitudes in eye movements were observed during exposure to sinusoidal vibration in the 4–6 Hz range, which is consistent with the frequencies that past research has associated with whole‐body resonance and the largest decrease in display legibility. Further, the measured eye movements appeared to be correlated with both the angular acceleration of the user's head and the angular slippage of the user's helmet. This research demonstrates that the loss of legibility while wearing HMDs likely results from a combination of VOR‐triggered eye movements and movement of the display. Future compensation algorithms should consider adjusting the display in response to both VOR‐triggered eye and HMD motion.     

Mullite for Structural, Electronic, and Optical Applications

Mullite (3Al₂O₃·2SiO₂) is becoming increasingly important in electronic, optical, and high-temperature structural applications. This paper reviews the current state of mullite-related research at a fundamental level, within the framework of phase equilibria, crystal structure, synthesis, processing, and properties. Phase equilibria are discussed in terms of the problems associated with the nucleation kinetics of mullite and the large variations observed in the solid-solution range. The incongruent melting behavior of mullite is now widely accepted. Large variations in the solid solubility from 58 to 76 mol% alumina are related to the ordering/disordering of oxygen vacancies and are strongly coupled with the method of synthesis used to form mullite. Similarly, reaction sequences which lead to the formation of mullite upon heating depend on the spatial scale at which the components are mixed. Mixing at the atomic level is useful for low-temperature (<1000°C) synthesis of mullite but not for low-temperature sintering. In contrast, precursors that are segregated are better suited for low-temperature (1250° to 1500°C) densification through viscous deformation. Flexural strength and creep resistance at elevated temperatures are significantly affected by the presence of glassy boundary inclusions; in the absence of glassy inclusions, polycrystalline mullite retains >90% of its room-temperature strength to 1500°C and displays very high creep resistance. Because of its low dielectric constant, mullite has now emerged as a substrate material in high-performance packaging applications. Interest in optical applications mainly centers on its applicability as a window material within the mid-infrared range.     

Initial cholesterol uptake by everted sacs of rat small intestine: Kinetic and thermodynamic aspects

The kinetics of initial cholesterol uptake by everted rat proximal and distal small intestinal sacs were evaluated in vitro. The mucosal incubation solution consisted of 0.05 mM cholesterol solubilized in 4.8 mM sodium taurocholate micellar solution at pH 7.4. Experiments were performed at temperatures from 26 to 38 C. The rate of cholesterol uptake followed a linear relationship when plotted against time indicating an apparent zero-order kinetics mechanism for initial uptake. An Arrhenius plot of the results of uptake versus temperature remained linear over the entire range of temperatures studied. The large free energy of activation (20 kcal/mole) suggests that an energy barrier for cholesterol uptake exists at the enterocyte luminal cell membrane and may be an important limiting step in cholesterol uptake. It is proposed that a transient association between cholesterol and a component of the enterocyte luminal cell membrane is formed during initial uptake of cholesterol. The transient association may be an activated complex formed with proteins present at or within the luminal enterocyte cell membrane.     

Thermal stability of substituted phenol-formaldehyde resins

A variety of crosslinked phenol-, or derivatized phenol-formaldehyde polymers have been synthesized. The phenol derivatives included o- and p-cresol, p-nonylphenol, m-pentadecylphenol, and raw and distilled cashew nutshell liquid. The derivatives were copolymerized with phenol and formaldehyde using sulfuric acid as catalyst to yield novolak-type prepolymers, which were then cured with hexamethylenetetramine. Thermogravimetric analysis was used to evaluate the thermal stability of the cured resins. It was found that the thermal stability of the resins decreased with increasing amounts of cashew nutshell liquid, with distilled cashew resins being slightly more thermally stable than raw cashew resins. The thermal stability of resins containing substituted phenols with alkyl chains was observed to increase from n-pentadecylphenol to cresol to phenol. The trend in thermal stability of the resins may be explained on the basis of alkyl groups being less thermally stable than aromatic rings. The amount of hexamethylenetetramine used to cure the prepolymers also influences the thermal stability of the resins. It appears that a level of 10 to 15% hexamethylenetetramine maximizes the thermal stability of the resin.     

Nanobubble generation and its applications in froth flotation (part Ⅲ): specially designed laboratory scale column flotation of phosphate

Froth flotation is used widely for upgrading raw phosphate. The flotation recovery of coarse phosphate (-1.18+0.425 mm) is much lower than that achieved on the -0.425+0.15 mm size fraction. Enhanced recovery of coarse phosphate particles is of great economic and environmental importance for phosphate industry. In this investigation, four different phosphate samples were aquired, characterized and tested in a specially designed laboratory-scale flotation column. Significant recovery improvement of coarse phosphate flotation was achieved using cavitation-generated nanobubble though its effects differ among the four testing phosphate samples. The laboratory-scale flotation column test results indicate that nanobubble increased P2O5 recovery by up to 10%-30% for a given Acid Insoluble (A.I.) rejection, depending on the characteristic of phosphate samples. The improvement ef-fect of nanobubble on the hard-to-float particles was more significant than that on easy-to-float particles, especially at lower col-lector dosages. Nanobubbles reduced the collector dosage by 1/3 to 1/2. Nanobubbles almost doubled the coarse phosphate flotation rate constant and increased the flotation selectivity index by up to 25%.