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81.
    
In diethyl ether extracts from celeriac (Apium graveolens L. var.rapaceum) all four stereoisomers of (3a–7a)-cis-3-butylhexahydrophthalide were found to be present. The analyses were carried out by means of GC, enantioselective GC and GC-MS. The assignment of the relative configuration of the diastereomers3 and4 was accomplished by NOE difference spectroscopy.
  相似文献   
82.
The authors present an original analysis of an aperture-coupled microstrip antenna. The theory is based on the segmentation method, which considers the patch as a multiport network whose impedance matrix is deduced from a hybrid matrix, and the use of analytical expressions of the cavity admittance at the slot centre. The theory is presented for the first time, and the theoretical results are in good agreement with previous published measurements  相似文献   
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84.
The beta subunit of human chorionic gonadotropin is potentially encoded by six genes, which can be categorized into two types based on a sequence change at codon 117: GCC for the type I and GAC for the type II genes. We previously showed that, whereas type I genes were exclusively expressed in normal breast tissues, expression of type II genes was associated with malignant transformation (Bellet, D., et al. Cancer Res., 57: 516-523, 1997). We designed a simple and robust test (the CG117 assay) that measures the percentage of type II over both types of chorionic gonadotropin beta mRNAs. Normal breast tissues consistently had a negative CG117 index, whereas cancer breast tissues showed indexes ranging from 0 to 100%. The prognostic significance of the CG117 index was investigated in a series of 99 unilateral invasive primary breast cancer patients with known long-term outcome (median follow-up, 9 years). The CG117 index was positive in 48 (48.5%) of the 99 tumor mRNA samples. The index was not significantly associated with standard prognostic parameters, including clinical and macroscopic tumor size, histopathological grade, and lymph node status or steroid receptor status. Patients with a positive CG117 index in primary tumor mRNA had significantly shorter metastasis-free survival (P = 0.014) and overall survival (P = 0.038) after surgery, compared to patients with a negative index. The prognostic significance of the CG117 index persisted in Cox multivariate regression analysis, both for metastasis-free survival (P = 0.008) and overall survival (P = 0.016), together with lymph node status (P = 0.027 and P = 0.009, respectively). These findings indicate that the CG117 index may contribute to the identification of high-risk breast cancer patients.  相似文献   
85.
86.
Of the several sources of acoustic information for distance perception, those arising from motion of the listener or sound source have received little attention. This motion-related information (recently called acoustic tau) is described, and experiments evaluating its utilization are presented. Accuracy and consistency at walking to the locations of briefly presented sounds were better when people listened while walking than while standing still. Manipulations of the sound to simulate shorter or longer target distances produced appropriate undershooting but not overshooting. The results indicate that people use motion-related acoustic information about distance to guide their locomotor actions, although they do not take full advantage of this information. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
87.
88.
Three- and 4-yr-old children were tested for comprehension of knowledge formation. In Exp 1, 34 Ss watched as a surprise was hidden under 1 of 4 obscured cups. The experimenter then pointed to the cup. All children searched under the correct cup, but no 3-yr-olds (in contrast to most 4-yr-olds) could explain how they knew where to look. Ss then discriminated between simultaneous pointing by 2 adults, one who had hidden a surprise and one who had left the room before the surprise was hidden. Most 4-yr-olds (but no 3-yr-olds) showed clear discrimination between the adults. In Exp 2, 16 Ss were tested with procedures designed to make the source of their own knowledge more obvious, but this had no effect on performance. It is concluded that studies using very similar procedures with chimpanzees and rhesus macaques were measuring an ability (or inability) to understand how knowledge states form. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
89.
The atmospheric oxidation of the unsaturated aldehyde 2-ethyl acrolein, CH2=C(C2H5)CHO, has been studied in laboratory experiments involving the reaction of ozone with 2-ethyl acrolein in the dark (with cyclohexane added to scavenge the hydroxyl radical), and the sunlight irradiation of 2-ethyl acrolein with NO in air. The major carbonyl products of the 2-ethyl acrolein reaction with ozone are formaldehyde, acetaldehyde, and the dicarbonyl ethylglyoxal, CH3CH2COCHO. Sunlight irradiation of 2-ethyl acrolein and NO led to the formation of three carbonyls (formaldehyde, acetaldehyde, and ethylglyoxal) and three peroxyacyl nitrates, (RC(O)OONO2), including PAN (R = CH3), PPN (R = C2H5), and the unsaturated compound EPAN (R = CH2=C(C2H5)). Mechanisms are outlined for the reactions of ozone and of the hydroxyl radical with 2-ethyl acrolein. These mechanisms are consistent with the observed carbonyl and peroxyacyl nitrate products. Thermal decomposition, a major atmospheric removal process for peroxyacyl nitrates, has been studied for EPAN. The decomposition rate of EPAN relative to that of PAN is 0.59–0.73 at 292–294 K and 1 atm of air. Atmospheric implications of these results are discussed.  相似文献   
90.
Studied memory for visuospatial arrays in 28 male and 34 female healthy dextral adults (aged 20–90 yrs). 10 abstract figures were presented in each hemispace over a series of learning trials, and then delayed free recall of figure placement was obtained. Figures were misplaced significantly downward and leftward in both hemispaces. Both vertical and horizontal absolute error increased significanty with age, but no age effects on directional errors were observed. The increase in absolute error over age is consistent with decreased anterograde memory and visuospatial skills in the elderly. The directional errors are believed to result from an attentional shift toward proximal peripersonal space, in combination with attentional shifts from differential left vs right cerebral activation. Gender effects were also observed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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