加氢裂化复合催化剂使用技术的研究

使用1246与3762复合催化剂加氢裂化处理含焦化蜡油(50%以上)混合原料油时,催化剂不仅具有高脱氮能力、高转化率,同时,还具有好的加氢活性稳定性,为焦化蜡油的合理加工找到一条新路,并有显著的经济效益 。     

Generation of Graphs for the Identification of Various Types of Scientific Collaboration in an Academic Institution

Programming and Computer Software - Scientific collaborations have made important contributions to the scientific community. Various institutions have considered publications made by various...     

气体硬化水溶性砂芯的性能研究

以电熔刚玉为骨料、氢氧化钡为粘结剂、铝粉为添加剂的型芯混合料在吹入CO_2气体后即可实现硬化。本文研究了这种型芯的硬化工艺和常温特性,并采用X射线衍射分析、失重—示差热分析等方法,结合粘结膜的扫描电镜照片,对型芯的受热物理化学变化、高温强度、水溶性等行为进行了实验研究。     

显微组织对Ni-Cr合金热腐蚀行为的影响

采用机械合金化法和真空熔炼法制备了不同显微组织的Ni-20Cr（质量分数，％，下同）合金，并研究其在950℃，75％Na2SO4＋25％K2SO4（质量分数，下同）盐膜下的热腐蚀行为。结果表明：细晶的机械合金化Ni-20Cr合金热腐蚀后表面形成了单一连续的Cr2O3外氧化膜，有效地阻止了硫的向内扩散，延长了热腐蚀过程的孕育期，呈现出较普通晶粒尺寸的熔炼Ni-20Cr合金更好的抗热腐蚀性能。     

SBTV铁电材料的制备和微观组织结构

采用固相反应法合成了SrBi2Ta2O9(简称SBT)和V掺杂SrBi2Ta2O9(简称SBTV)陶瓷,通过TG-DTA、XRD、SEM、TEM等技术手段研究了材料的烧结工艺、相组成和微观组织结构.研究表明V2O5是一种很好的助烧剂,掺杂后材料的烧结温度可降低200℃烧结后纯SBT均为单一的钙钛矿相SBT;掺杂后2种成型工艺所制备的SBTV除了生成少量Bi4(V2O11)外,仍主要由钙钛矿相组成;同时所有的材料都发生了一定程度的择优取向.掺杂后材料的晶粒形态发生变化棒状转化为片状.同时V掺杂后引起了晶格畸变,产生应变,SBTV材料在透射中观察到具有α-边界特征的90°畴.     

Catalytic partial oxidation of methane to synthesis gas in a ceramic membrane reactor

Methane has been selectively converted to synthesis gas using a two-zone fixed bed of a Ni/Al₂O₃ catalyst inside a modified ceramic membrane. The first zone of the reactor was surrounded by an impervious wall, and therefore behaved as a conventional fixed bed reactor. In the second zone, some of the reaction products could preferentially diffuse out of the reactor, which yielded higher than equilibrium methane conversions. The influence of the different operating conditions has been studied, and the performance of the membrane reactor has been compared to that of a fixed bed reactor. The membrane reactor has also been used at pressures above atmospheric (2 bar), with good conversions and selectivities.     

Mn2+、Nb5+共掺BaTiO3陶瓷的制备及压电性能的研究

本文采用改进的固相反应法,制备了施主杂质Nb5 和受主杂质Mn2 共掺的BaTiO3陶瓷。按不同Nb5 、Mn2 的掺杂量,分别在1180℃、1210℃、1250℃、1280℃温度下煅烧。实验结果表明:当烧结温度为1250℃、掺杂量为0.05mol%时,制得的试样性能较好。     

基于高密度电阻率法的露天铁矿采空区探测的研究

露天铁矿开采区地下浅部大量采空区的存在,给矿山的人员及生产安全带来极大的威胁。为保证生产活动的顺利进行,必须对采空区进行精确探测。由于高密度电阻率法较常规电法具有信息丰富、精度高的特点,运用该法对露天铁矿采空区进行探测,结合数据反演断面图,在地下50m的范围内,共划定采空区四处,并精确划定采空区顶底板深度、水平范围和展布方向,为矿山的治理工作提供了可靠依据。并且在分析采集数据的基础上,总结出视电阻率识别模型及其主要特点,为地下采空区的划定提供了理论基础。     

Understanding of the tensile deformation in HDPE/LDPE blends based on their crystal structure and phase morphology

The mechanisms of tensile deformation in high density polyethylene/low density polyethylene (HDPE/LDPE) blends were studied by a video-controlled tensile set-up, combined with dynamic mechanical analysis and small angle X-ray scattering. When quenching from the melt to room temperature, HDPE forms well-organized spherulits with high crystallinity and rigid amorphous layers between lamellae, and LDPE forms irregular aggregates with low crystallinity and mobile amorphous layers between lamellae. A separate lamellar stack-like structure is formed in HDPE/LDPE blends during the quenching. The deformation is affected by both the crystal structure and the phase morphology. Because the semi-crystalline polymers are made up of two interpenetrating networks, one is built up by the entangled fluid part and the other by the crystallites, at low deformations the coupling and coarse slips of the crystalline blocks dominate the mechanical properties, which allows the system to maintain a homogeneous strain distribution in the sample. The assumption of a homogeneous strain distribution can now be further proved by the tensile deformation in HDPE/LDPE blends, which shows two-step processes, with HDPE crystallites being broken down first at imposed strain of 0.4 and then LDPE crystallites being broken later, at an imposed strain of 0.6.