Aggregation-Induced Circularly Polarized Luminescence: Chiral Organic Materials for Emerging Optical Technologies

Chirality is becoming increasingly important in the design of organic materials with functional properties, when bulk anisotropy is needed. In the past decades, a plethora of chiral organic materials have been studied and developed. Nanostructures have brought substantial advancement to the realization of organic-molecule-based devices, and the possibilities for solid-state light emission are very promising in view of potential applications. Scientific approaches to the realization of chiral emissive materials are indeed growing exponentially. The chiral nanostructures discussed are related both to the way in which luminescence is generated and the way in which it is detected. As to the former, the focus will be on organic chromophores with aggregation-induced emission properties, so that emission is present, or at least largely amplified, when the molecules are in the aggregated state. As to the latter, the focus will be on the ability and a quantitative comparison of organic nanostructures capable of circularly polarized emission.     

Additive manufacturing of copper alloys: influence of process parameters and alloying elements

Owing to the physical properties of copper and its alloys it is challenging to achieve good surface quality and low porosity by the widely used laser-based additive manufacturing processes. This paper deals with the role of alloy composition, powder size and process parameters in additive manufacturing with laser beam melting machine (with power up to 100 W). Test parts were produced in pure copper and CuNiSi(Cr) alloys. The porosity was investigated as a function of different process parameters and powder size ranges. The effects of the alloy physical properties (reflectivity, thermal conductivity, melting range and surface tension) are discussed. Moreover, the effect of thermal treatment on the properties of CuNiSi parts was assessed in conventional two-step heat treatments.     

Identification of hybrid and linear parameter‐varying models via piecewise affine regression using mixed integer programming

This article presents a two‐stage algorithm for piecewise affine (PWA) regression. In the first stage, a moving horizon strategy is employed to simultaneously estimate the model parameters and to classify the training data by solving a small‐size mixed‐integer quadratic programming problem. In the second stage, linear multicategory separation methods are used to partition the regressor space. The framework of PWA regression is adapted to the identification of PWA AutoRegressive with eXogenous input (PWARX) models as well as linear parameter‐varying (LPV) models. The performance of the proposed algorithm is demonstrated on an academic example and on two benchmark experimental case studies. The first experimental example concerns modeling the placement process in a pick‐and‐place machine, while the second one consists in the identification of an LPV model describing the input‐output relationship of an electronic bandpass filter with time‐varying resonant frequency.     

The multi-modal interface of Robot-Era multi-robot services tailored for the elderly

Socially assistive robotic platforms are now a realistic option for the long-term care of ageing populations. Elderly users may benefit from many services provided by robots operating in different environments, such as providing assistance inside apartments, serving in shared facilities of buildings or guiding people outdoors. In this paper, we present the experience gained within the EU FP7 ROBOT-ERA project towards the objective of implementing easy-to-use and acceptable service robotic system for the elderly. In particular, we detail the user-centred design and the experimental evaluation in realistic environments of a web-based multi-modal user interface tailored for elderly users of near future multi-robot services. Experimental results demonstrate positive evaluation of usability and willingness to use by elderly users, especially those less experienced with technological devices who could benefit more from the adoption of robotic services. Further analyses showed how multi-modal modes of interaction support more flexible and natural elderly–robot interaction, make clear the benefits for the users and, therefore, increase its acceptability. Finally, we provide insights and lessons learned from the extensive experimentation, which, to the best of our knowledge, is one of the largest experimentation of a multi-robot multi-service system so far.     

天气雷达低噪声放大器的仿真设计

The intersection of Quantum Technologies and Robotics Autonomy is explored in the present paper. The two areas are brought together in establishing an interdisciplinary interface that contributes to advancing the field of system autonomy, and pushes the engineering boundaries beyond the existing techniques. The present research adopts the experimental aspects of quantum entanglement and quantum cryptography, and integrates these established quantum capabilities into distributed robotic platforms, to explore the possibility of achieving increased autonomy for the control of multi-agent robotic systems engaged in cooperative tasks. Experimental quantum capabilities are realized by producing single photons (using spontaneous parametric down-conversion process), polarization of photons, detecting vertical and horizontal polarizations, and single photon detecting/counting. Specifically, such quantum aspects are implemented on network of classical agents, i.e., classical aerial and ground robots/unmanned systems. With respect to classical systems for robotic applications, leveraging quantum technology is expected to lead to guaranteed security, very fast control and communication, and unparalleled quantum capabilities such as entanglement and quantum superposition that will enable novel applications.     

Natural and NH<Subscript>4</Subscript><Superscript>+</Superscript>-enriched zeolitite amendment effects on nitrate leaching from a reclaimed agricultural soil (Ferrara Province,Italy)

In this paper we report an overview of the main outcomes of a 3-years experimental cultivation carried out in an Italian reclaimed agricultural field amended with different types of zeolitites (rock containing > 50% of zeolites), under cereals cultivation (Sorghum vulgare Pers, Zea mays and Triticum durum). The aim of the experiment was to exploit the properties of zeolite-rich volcanic rocks (zeolitites) for reducing the excessively high NO₃^? content in the soil and in waters flowing out the sub-surface drainage system of the field and flushing into the surface water system, reducing concomitantly also chemical fertilization application rates (up to 50%). Zeolitites were tested both in their natural state and in a NH₄⁺-enriched form, obtained through an enrichment process with NH₄⁺-rich zoo-technical effluents (pig slurry). NO₃^? content in soils and in waters discharged through SSDS were periodically monitored during the experimentation and crop yield quantified. Results showed that, for three consecutive cultivation cycles, the overall NO₃^? concentrations in water extracts was reduced by 45% in the zeolitite treated soils, while in SSDS waters the reduction reached the 64%. Notwithstanding the lower N input from chemical fertilizers, crop yield was not negatively affected in the zeolitite amended soils with respect to the control. Zeolitite addition increased thus soil NH₄⁺ retention and probably influenced several pathways of N losses, allowing a better fertilizer use efficiency by plants and a reduction of the overall NO₃^? concentrations in the surface waters.     

The FAST module: an add-on unit for driving commercial scanning probe microscopes at video rate and beyond

We present the design and the performance of the FAST (Fast Acquisition of SPM Timeseries) module, an add-on instrument that can drive commercial scanning probe microscopes (SPM) at and beyond video rate image frequencies. In the design of this module, we adopted and integrated several technical solutions previously proposed by different groups in order to overcome the problems encountered when driving SPMs at high scanning frequencies. The fast probe motion control and signal acquisition are implemented in a way that is totally transparent to the existing control electronics, allowing the user to switch immediately and seamlessly to the fast scanning mode when imaging in the conventional slow mode. The unit provides a completely non-invasive, fast scanning upgrade to common SPM instruments that are not specifically designed for high speed scanning. To test its performance, we used this module to drive a commercial scanning tunneling microscope (STM) system in a quasi-constant height mode to frame rates of 100 Hz and above, demonstrating extremely stable and high resolution imaging capabilities. The module is extremely versatile and its application is not limited to STM setups but can, in principle, be generalized to any scanning probe instrument.     

The Future of Structural Chemistry Nucleates in the Present

A personal view of nearly four decades of structural chemistry is presented. The rise of molecular crystal engineering as an independent cross-disciplinary field of research at the intersection of crystallography with supramolecular chemistry and solid-state reactivity is discussed in light of the development of theoretical and instrumental tools and the need for novel molecular materials. The exchange of ideas and experience within the structural chemistry community has played a fundamental role in reaching the present high level of understanding of the factors that control crystal formation and stability. Crystal-oriented synthetic strategies, including solvent-free mechanochemical methods, have been developed, as well as screening methods and computational approaches. Some drawbacks and limitations are also discussed. The wealth of multiple crystal forms, from single-molecule crystals to solvates, co-crystals, salts and ionic co-crystals, and their polymorphs, is both an open challenge to the crystal engineering paradigm and a source of discovery and innovation.