全文获取类型
收费全文 | 167篇 |
免费 | 9篇 |
专业分类
化学工业 | 67篇 |
金属工艺 | 3篇 |
机械仪表 | 5篇 |
建筑科学 | 1篇 |
能源动力 | 4篇 |
轻工业 | 29篇 |
无线电 | 5篇 |
一般工业技术 | 28篇 |
冶金工业 | 22篇 |
原子能技术 | 3篇 |
自动化技术 | 9篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 8篇 |
2017年 | 7篇 |
2016年 | 3篇 |
2015年 | 3篇 |
2014年 | 5篇 |
2013年 | 8篇 |
2012年 | 7篇 |
2011年 | 10篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 13篇 |
2007年 | 10篇 |
2006年 | 3篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 2篇 |
2002年 | 3篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1993年 | 3篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 1篇 |
排序方式: 共有176条查询结果,搜索用时 15 毫秒
21.
The present investigation analyses the thermodynamic behaviour of the surfaces and adsorption as a function of temperature and composition in the Fe-S-O melts based on the Butler's equations. The calculated values of the surface tensions exhibit an elevation or depression depending on the type of the added solute at a concentration which coincides with that already present in the system. Generally, the desorption of the solutes as a function of temperature results in an initial increase followed by a decrease in the values of the surface tension. The observations are analyzed based on the surface interaction parameters which are derived in the present research. 相似文献
22.
Inverse gas chromatography technique has been used to study the thermodynamic compatibility of the industrially important elastomers polybutadiene (BR) and polybutadiene copolymerised with acrylonitrile (NBR). The NBR used in this study had nitrile contents of 18 and 34%. The ratio of BR/NBR in blends varied between 1 and 0.25 in both cases and retention volume of twelve probes was measured at 80°C. The Flory-Huggins interaction parameter X′23, computed using a standard procedure, and also the interaction parameter B23 showed that BR and NBR are incompatible in all compositions and that incompatibility increases with nitrile content. © 1995 John Wiley & Sons, Inc. 相似文献
23.
Integral excess free energy of a quaternary system has been expressed in terms of the MacLaurin infinite series. The series is subjected to appropriate boundary conditions and each of the derivatives correlated to the corresponding interaction coefficients. The derivation of the partial functions involves extensive summation of various infinite series pertaining to the first order and quaternary parameters to remove any truncational error. The thermodynamic consistency of the derived partials has been established based on the Gibbs-Duhem relations. The equations are used to interpret the thermodynamic properties of the Fe-Cr-Ni-N system. 相似文献
24.
Expressions for various second-order derivatives of surface tension with respect to composition at infinite dilution in terms of the interaction parameters of the surface and those of the bulk phases of dilute ternary melts have been presented. A method of deducing the parameters, which consists of repeated differentiation of Butler’s equations with subsequent application of the appropriate boundary conditions, has been developed. The present investigation calculates the surface tension and adsorption functions of the Fe-S-O melts at 1873 and 1923 K using the modified form of Butler’s equations and the derived values for the surface interaction parameters of the system. The calculated values are found to be in good agreement with those of the experimental data of the system. The present analysis indicates that the energetics of the surface phase are considerably different from those of the bulk phase. The present research investigates a critical compositional range beyond which the surface tension increases with temperature. The observed increase in adsorption of sulfur with consequent desorption of oxygen as a function of temperature above the critical compositional range has been ascribed to the increase of activity ratios of oxygen to sulfur in the surface relative to those in the bulk phase of the system. 相似文献
25.
V. K. Raizada V. S. Tripathi Darshan Lal G. S. Singh C. D. Dwivedi A. K. Sen 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1993,56(3):265-270
Butyraldehyde is an important chemical for many industrial applications, especially in the production of polyvinylbutyral. A systematic study of its synthesis by catalytic dehydrogenation of butanol, using zinc oxide as catalyst has been carried out. The effect of the method of preparation of zinc oxide on its catalytic activity for the title reaction has also been studied. The optimum conditions for maximum yield have been worked out and on the basis of secondary electron micrograms the reasons for higher activity/selectivity in the case of zinc oxide calcined from zinc hydroxide is attributed to the presence of hexagonal morphology. A kinetic study for the best zinc oxide catalyst has been carried out and the rate equation has been determined. 相似文献
26.
A proper node architecture design capable to support different network protocol enhances the data transport capability of a wavelength division multiplexed system. In the present paper a simple node architecture model has been developed to simulate the node throughput based on media access control protocols for bursty data traffic of variable time slot duration and data rate. An appropriate mathematical model has been derived to evaluate different types of traffic reservation protocols used in WDM networks. It has been observed that the network performance is well controlled through implemented protocols and network design parameters. 相似文献
27.
Polyvinylidene fluoride (PVDF) has several crystal forms of which the α-form is nonpolar, while the β-form is polar and has the highest piezoelectric constant. α PVDF, when stretched, transforms into the β form, which has wide applications in sensors and actuators. Steered molecular dynamics simulations are used to study the transformation of a single chain of PVDF from a trans–gauche conformation to an all trans one. The Helmholtz free energy change (∆F) is estimated using Jarzynski's equality. The transformation starts at the chain ends followed by the transformation of the remaining chain. The free energy change for the transformation is found to be always positive, indicating that the TGTG' form has higher thermodynamic stability than the all trans form throughout the studied temperature range. With increasing temperature, free energy change for the transformation increases monotonically. 相似文献
28.
Swetank Kumar Saha Darshan Godabanahal Malleshappa Avinash Palamanda Viral Vijay Vira Anuj Garg Dimitrios Koutsonikolas 《Wireless Networks》2018,24(7):2427-2450
This paper presents a feasibility study of 60 GHz indoor WLANs. We evaluate 60 GHz performance in a typical academic office building under the primary assumption that 60 GHz WLAN APs and clients will be equipped with relatively wide-beam antennas to cope with client mobility. In contrast to previous works which measured performance at a single layer using custom, non-standard compliant hardware, we investigate performance across multiple layers using primarily 802.11ad-compliant wide-beam COTS devices. Our study shows that the large number of reflective surfaces in typical indoor WLAN environments combined with wider beams makes performance highly unpredictable and invalidates several assumptions that hold true in static, narrow-beam, Line-Of-Sight scenarios. Additionally, we present the first measurements, to our best knowledge, of power consumption of an 802.11ad NIC and examine the impact of a number of factors on power consumption. 相似文献
29.
F. Femila Komahal H. Nagabhushana R.B. Basavaraj G.P. Darshan B. Daruka Prasad S.C. Sharma D. Kavyashree 《Advanced Powder Technology》2018,29(9):1991-2002
Core–shell SiO2@ZnAl2O4:Eu3+ (5?mol%) nanophosphor (NP) with coatings up to the level IV has been prepared by a facile solvothermal route, followed by heat treatment. Scanning electron microscopy studies of fabricated core–shell particles displays good spherical shape and non-agglomeration with a narrow size distribution. The thickness of the shell increased with increase in coating cycles. Photoluminescence (PL) studies exhibited strong red emission peaks at 612?nm corresponding to the 5Do?→?7F2 transition of the Eu3+ ions. PL intensity increased with calcination temperature and coating cycles. The color coordinates of the coated NP were turned towards intense pure red emission with color purity ~95%. Powder dusting method was used to visualize latent fingerprints (LFPs) by staining uncoated and coated NP on various porous and non-porous surfaces under UV light. It was clear that core–shell NP display high sensitivity, reproducibility, selectivity, reliability, and can obtain the complete three levels of fingerprint ridge details. Judd–Ofelt (J-O) intensity parameters and radiative properties, namely transition probabilities, radiative lifetimes, branching ratios, and quantum efficiency were evaluated. The aforementioned results established that the SiO2@ZnAl2O4:Eu3+ (5?mol%) NP can be used as an ideal candidate for multifunctional applications such as WLEDs, LFPs, anticounterfeiting etc. 相似文献
30.
Durairaj Rekha Subramanyan Neelakrishnan Duraiswami Divakar 《Clean Technologies and Environmental Policy》2023,25(4):1361-1384
Clean Technologies and Environmental Policy - The utilization of catalytic converters is one of the well-known strategies to clean the exhaust. The catalytic converters oxidize the destructive... 相似文献