Studies on modification of polyester fabrics I: Alkaline hydrolysis

Hydrolysis of polyester fabrics with sodium hydroxide has been studied with a view to imparting hydrophilicity and other comfort-related properties to polyester textiles. Effect of reaction parameters such as treatment time concentration of alkali, and temperature on the extent of hydrolysis is examined and the modified fabrics are evaluated for their important physical, mechanical, and physicochemical properties. The mechanism of hydrolytic degradation of polyester fabrics, as determined by the weight loss, has also been ascertained. Alkali progressively degrades polyester by saponification of its ester linkages and results in a loss in weight of the fabric. Weight loss increases linearly with treatment time and nonlinearly with alkali concentration and reaction temperature. A Linear correlation exists between strength loss of the fabric and its weight loss. By alkaline hydrolysis, surface hydrophilicity and feel of the fabric are considerably improved, whereas such properties as moisture regain, crease recovery angle, etc., remain practically unchanged. Attempts have been made to explain the results in terms of modifications in the surface characteristics of polyester fabrics.     

Highly Aligned Centrifugal Spun Polyacrylonitrile Nanofibers Collected and Processed with Automated Tracks

A parallel automated track collector is integrated with a rationally designed centrifugal spinning head to collect aligned polyacrylonitrile (PAN) nanofibers. Centrifugal spinning is an extremely promising nanofiber fabrication technology due to high production rates. However, continuous oriented fiber collection and processing presents challenges. Engineering solutions to these two challenges are explored in this study. A 3D-printed head design, optimized through a computational fluid dynamics simulation approach, is utilized to limit unwanted air currents that disturb deposited nanofibers. An automated track collecting device has pulled deposited nanofibers away from the collecting area. This results in a continuous supply of individual aligned nanofibers as opposed to the densely packed nanofiber mesh ring that is deposited on conventional static post collectors. The automated track collector allows for simple integration of the postdraw processing step that is critical to polymer fiber manufacturing for enhancing macromolecular orientation and mechanical properties. Postdrawing has enhanced the mechanical properties of centrifugal spun PAN nanofibers, which have different crystalline properties compared with conventional PAN microfiber. These technological developments address key limitations of centrifugal spinning that can facilitate high production rate commercial fabrication of highly aligned, high-performance polymer nanofibers.     

A convolutional neural network (CNN)-based direct method to detect stiction in control valves

Control valves are considered important capital assets in any process industry. A properly maintained control valve can have a significant impact on how well the process is controlled as well as the overall cost of the plant. However, control valves can suffer from poor control performance due to valve non-linearities. One of the main reasons for non-linearity is control valve stiction. Stiction not only causes oscillations in the process variables but also shortens the life of the control valve, resulting in an economic loss for the process. In a process plant, a control engineer generally analyzes the time series plot of process value (PV), set point (SP), and controller output (OP) data and identifies stiction based on the typical shape pattern of PV/SP/OP plot. In this study, the same shape pattern methodology is adapted to identify stiction using convolutional neural network (CNN) technique. A one-dimensional convolution neural network (Conv1D) algorithm is developed, which works directly on PV/SP/OP time series data for stiction detection. The proposed CNN algorithm is tested on both simulated and industrial control loop data. The suggested method provides promising results with a combined stiction prediction accuracy of 92% (92.2% in predicting non-sticky and 91.53% in predicting sticky loops) for the industrial loops data studied.     

LVT: a layered verification technique for distributed computing systems

This paper presents a layered verification technique, called LVT, for the verification of distributed computing systems with multiple component layers. Each lower layer in such a system provides services in support of functionality of the higher layer. By taking a very general view of programming languages as interfaces of systems, LVT treats each layer in a distributed computing system as a distributed programming language. Each relatively higher‐level language in the computing system is implemented in terms of a lower‐level language. The verification of each layer in a distributed computing system can then be viewed as the verification of implementation correctness for a distributed language. This paper also presents the application of LVT to the verification of a distributed computing system, which has three layers: a small high‐level distributed programming language; a multiple processor architecture consisting of an instruction set and system calls for inter‐process message passing; and a network interface. Programs in the high‐level language are implemented by a compiler mapping from the language layer to the multiprocessor layer. System calls are implemented by network services. LVT and its application demonstrate that the correct execution of a distributed program, most notably its inter‐process communication, is verifiable through layers. The verified layers guarantee the correctness of (1) the compiled code that makes reference to operating system calls, (2) the operating system calls in terms of network calls, and (3) the network calls in terms of network transmission steps. The specification and verification involved are carried out by using the Cambridge Higher Order Logic (HOL) theorem proving system. Copyright © 1999 John Wiley & Sons, Ltd.     

Fabrication procedures and process sensitivities for CdS/CdTe solar cells

This paper details the laboratory processes used to fabricate CdS/CdTe solar cells at the National Renewable Energy Laboratory. The basic fabrication technique includes low‐pressure chemical vapor deposited SnO₂ , chemical‐bath deposited CdS, close‐spaced sublimated CdTe, solution‐CdCl₂ treatment, and an acid‐contact etch, followed by application of a doped‐graphite paste. This paper also describes the results of a reproducibility study in which cells were produced by multiple operators with an average AM1·5 efficiency of 12·6%. And finally, this paper discusses process sensitivities and alternative cell fabrication procedures and reports the fabrication of a cell with an AM1·5 efficiency of 15·4%. Copyright © 1999 John Wiley & Sons, Ltd.     

Fine-Tuning Supramolecular Assemblies by Controlling Micellar Aggregates

Supramolecular assembly can be used to fabricate complex functional materials by organizing simple building blocks. However, it is difficult to control the hierarchical assembly across multiple length scales. The correlation of a supramolecular gel network and a pre-gelling aggregate will help to understand how a molecular-level assembly is translated into a higher order. Here, a functional dipeptide 2NapFF is used that can assemble in different micellar structures at high pH by varying the counterion. Replacing the counterions with a divalent calcium salt results in a cross-linked gel network, or an interesting analog “gel noodles.” The physical properties of the gel noodles can be varied by choosing specific micellar assemblies as the pre-gel. The mechanical rigidity of the gel networks is compared by nanoindentation and tensile testing, and the pattern to the structures of the micelles observed by small-angle X-ray scattering is correlated. The supramolecular assembly can be fine-tuned by using different micelles as the pre-gel without affecting the inherent gel-state properties.     

A comprehensive review on deploying robotics application in telecom network tower's field maintenance: Challenges with current practices and feasibility analysis for robotics implementation

This survey article highlights the difficulties in the field maintenance of telecommunication towers. It critically analyses the main features of the deployment of robots to maintain telecommunication towers. The growing demand for mobile connectivity poses the need for more towers, and the subsequent problem of network maintenance becomes more critical. Most tower maintenance is required work at height; therefore, height-related risks are more frequent. A rigorous review is conducted, and the growth of the telecommunications network and key on-site maintenance challenges are analyzed. Despite numerous challenges, these towers are maintained manually by riggers (certified climbers) worldwide. It raises the question, Is it possible to implement automation by robots for the maintenance of telecommunications towers? The feasibility analysis to deploy the robots is conducted systematically. To access the tower through a robot, detailed information on the type of towers, the climbing arrangements available on the existing towers, and the necessary operations to be carried out at the height is collected. A critical analysis of the climbing robots currently available in the literature, their grasping technology, and control algorithms is performed. The opinion of experts in the telecommunication industry is very helpful in identifying the requirements of robotic systems. The design attributes especially needed for the climbing robot, and the execution of the maintenance in height are highlighted. Due justification is given for deploying robots for field maintenance of telecom towers. The recommended methodology for designing an automation system helps research in the field of maintenance of telecom towers through robots, which could bring a remarkable solution to the telecom sector.     

High and low-energy proton radiation damage in p/n InP MOCVD solar cells

Indium phosphide p⁺/n/n⁺ solar cells, fabricated by metal organic chemical vapor deposition, were irradiated with 0.2-MeV and 10-MeV protons to a fluence of 10¹³ cm⁻². The power output degradation, 1-V behavior, carrier concentration and defect concentration were observed at intermediate points throughout the irradiations. The 0.2-MeV proton-irradiated solar cells suffered much greater and more rapid degradation in power output than those irradiated wit h 10 MeV protons. The efficiency losses were accompanied by larger increases in the recombination currents in the 0.2-MeV proton-irradiated solar cells. The low-energy proton irradiations also had a larger impact on the series resistance of the solar cell s. Despite the radiation-induced damage, the carrier concentration in the base of the solar cells showed no reduction after 10-MeV or 0.2-MeV proton irradiations and even increased during irradiation with 0.2-MeV protons. In a deep-level transient spectro scopy study of the irradiated samples, the minority carrier defects H4 and H5 at E_v + 0.33 and E_v + 0.52 eV and the majority carrier defects E7 and E10 at E_c − 0.39 and E_c − 0.74 eV were observed. Th e defect introduction rates for the 0.2-MeV proton irradiations were about 20 times higher than for the 10-MeV proton irradiations. The defect E10, observed here after irradiation, has been shown to act as a donor in irradiated n-type InP and may be responsible for obscuring carrier removal. The results of this study are consistent with the much greater damage produced by low-energy protons whose limited range causes them to stop in the active region of the solar cell. © This article is a US Government work and, as such, is in the public domain in the United States of America