Electrochemical Synthesis of Cu (II) Coordination Polymer Coatings Based on 2,2′-Thiodiacetic Acid and 1,2,4,5-Benzenetetracarboxylate

Electrochemical synthesis of coordination polymers of Cu(II), [Cu(TDA)]_n and [Cu₂(BTC)(H₂O)₆?6H₂O]_n in which H₂TDA is 2,2′-thiodiacetic acid and BTC stands for 1,2,4,5-benzenetetracarboxylate was carried out by the electrochemical oxidation of Cu anode in the presence of H₂TDA (a flexible ligand), and 1,2,4,5-benzentetracarboxylic acid (H₄BTC) (a rigid ligand) in aqueous solutions. The structure of coordination polymers were characterized by scanning electron microscopy, X-ray powder diffraction, elemental analysis, thermal gravimetric and differential thermal analyses. The crystal structure of the compounds consists of one-dimensional cubical crystal polymeric units of [Cu(TDA)]_n and [Cu₂(BTC)(H₂O)₆?6H₂O]_n. Furthermore, the coordination number of Cu (II) ions in synthesized coordination polymers to be found five. The main advantages of electrosynthesis are the minor synthesis time, the milder conditions and the facile synthesis of coordination polymer coatings.     

Nonlinear analysis of size-dependent frequencies in porous FG curved nanotubes based on nonlocal strain gradient theory

A nonlocal strain gradient model is developed in this research to analyse the nonlinear frequencies of functionally graded porous curved nanotubes. It is assumed that the curved nanotube is in contact with a two-parameter nonlinear elastic foundation and is also subjected to the uniform temperature rise. The non-classical theory presented for curved nanotubes contains a nonlocal parameter and a material length scale parameter which can capture the size effect. A power law distribution function is used to describe the graded properties through the thickness direction of curved nanotubes. The even dispersion pattern is used to model the porosities distribution. The high-order shear deformation theory and the von Kármán type of geometric non-linearity are utilized to obtain the nonlinear governing equations of the structure. The size-dependent equations of motion for the large amplitude vibrations of curved nanotubes are obtained by employing Hamilton’s principle. The analytical solutions are extracted for the curved nanotube with immovable hinged-hinged boundary conditions. Size-dependent frequencies of the curved nanotube exposed to thermal field are obtained using the two-step perturbation technique and Galerkin procedure. The effects of important parameters such as nonlocal and length scale parameters, temperature field, elastic foundation, porosity, power law index and geometrical parameters are studied in detail.

     

An improved volleyball premier league algorithm based on sine cosine algorithm for global optimization problem

Volleyball premier league (VPL) simulating some phenomena of volleyball game has been presented recently. This powerful algorithm uses such racing and interplays between teams within a season. Furthermore, the algorithm imitates the coaching procedure within a game. Therefore, some volleyball metaphors, including substitution, coaching, and learning, are used to find a better solution prepared by the VPL algorithm. However, the learning phase has the largest effect on the performance of the VPL algorithm, in which this phase can lead to making the VPL stuck in optimal local solution. Therefore, this paper proposed a modified VPL using sine cosine algorithm (SCA). In which the SCA operators have been applied in the learning phase to obtain a more accurate solution. So, we have used SCA operators in VPL to grasp their advantages resulting in a more efficient approach for finding the optimal solution of the optimization problem and avoid the limitations of the traditional VPL algorithm. The propounded VPLSCA algorithm is tested on the 25 functions. The results captured by the VPLSCA have been compared with other metaheuristic algorithms such as cuckoo search, social-spider optimization algorithm, ant lion optimizer, grey wolf optimizer, salp swarm algorithm, whale optimization algorithm, moth flame optimization, artificial bee colony, SCA, and VPL. Furthermore, the three typical optimization problems in the field of designing engineering have been solved using the VPLSCA. According to the obtained results, the proposed algorithm shows very reasonable and promising results compared to others.

     

Approximating of conic sections by DP curves with endpoint interpolation

Conic sections have many applications in industrial design, however, they cannot be exactly represented in polynomial form. Hence approximating conic sections with polynomials is a challenging problem. In this paper, we use the monomial form of Delgado and Peña (DP) curves and present a matrix representation for them. Using the matrix form and the least squares method, we propose a simple and efficient algorithm for approximating conic sections by DP curves of arbitrary degree with endpoint interpolation. Finally, we test and compare the proposed algorithm on some numerical examples which validates and confirms efficiency of it.     

Automated optimal design of double-layer latticed domes using particle swarm optimization

Most of the conventional design methods of large-scale domes need deep engineering insight; furthermore, they hardly give the most economical solutions. Therefore, in this paper, a new practical design algorithm is presented to automate optimal geometry and sizing design of the latticed space domes through the idea of using parametric mathematical functions. Moreover, a simple approach is developed for the optimal sizing design of trusses with outsized number of elements. The robust technique of particle swarm optimization is employed to find the solution of the propounded optimization problem. Some numerical examples on the minimum weight design of several famous domes are provided to demonstrate the efficiency of the proposed design algorithm.     

Evolution of quantum correlations in the open quantum systems consisting of two coupled oscillators

The open quantum systems consisting of coupled and uncoupled asymmetric oscillators are considered with an initial quantum-dot trapped-ion coherent state. The quantum correlations between spatial modes of this trapped ion are examined to find their dependence on the temperature, asymmetric parameter, dissipation coefficient and the magnetic field. It is observed that the discord of the initial state is an increasing function of the asymmetric parameter and the magnetic field. Moreover, in the case of two uncoupled modes, entanglement and discord are decreasing functions of temperature and the dissipation coefficient. However, as the temperature and dissipation coefficient increase, the discord fades out faster. In the case of two coupled modes, as the temperature and dissipation coefficient increase, the sudden death of the entanglement and fade out of the discord happen sooner; moreover, as the magnetic field increases, the entanglement sudden death and the discord fade out time occur sooner. Also, with the increase in the asymmetric parameter, the entanglement sudden death is postponed. In addition, in the asymmetric system, appreciable discord can be created in the temperature range 0–10 K, while appreciable entanglement can be created in the temperature range 0–5 mK. Finally, it is observed that non-monotonic evolution of quantum correlations is due to coupling of modes.     

A solution method for frictional contact problems of a crack in FGMs under mechanical and thermal loads

This article provides a numerical treatment of a finite crack in an interfacial layer with spatially varying elastic properties under in-plane mechanical and thermal loading conditions. The variation of stress intensity factors and energy release rates with the functions which are governing the material properties of the interfacial layer is studied. Transient and steady-state response of a central crack in FGMs subjected to the mechanical and thermal loads are investigated. Unlike earlier studies which consider the cracks encountered as open, the current investigation studies cracks in an essentially compressive environment in which the crack faces are in contact and frictional effects play an important role. To solve this contact problem, a simple and efficient, iterative finite element method developed by authors is used. Numerical examples are provided to verify the technique and the results are compared with those of the published papers. This revised version was published online in July 2006 with corrections to the Cover Date.     

Combining continuous catalytic regenerative naphtha reformer with thermally coupled concept for improving the process yield

Advancements in the catalytic naphtha reforming process, as one of the main processes in petrochemical industry, contributed to development of continuous catalytic regenerative naphtha reformer units. Increasing the yield of aromatic and hydrogen as well as saving the energy in this process through the application of thermal coupling technique is a potentially interesting idea. This novel idea has been assessed in this paper. In the proposed configuration, continuous catalyst regeneration naphtha reforming process is coupled with hydrogenation of nitrobenzene in a two co-axial reactor separated by a solid wall, where the generated heat in nitrobenzene hydrogenation reaction transfers to naphtha reforming reaction medium through the surface of the tube. A steady-state, homogeneous, two-dimensional model is used to describe the performance of this configuration and a kinetic model including 32 pseudo-components with 84 reactions is considered for naphtha reforming reaction. After validating the model with the commercial data of a domestic plant, the obtained results of coupled reactor are compared by the conventional one. The obtained results show the superiority of CCR coupled reactor against the conventional one.