Glass and glass-ceramic coatings, versatile materials for industrial and engineering applications

Among various coating systems for industrial and engineering applications, glass and glass-ceramic coatings have advantages of chemical inertness, high temperature stability and superior mechanical properties such as abrasion, impact etc as compared to other coating materials applied by thermal spraying in its different forms viz. PVD, CVD, plasma, etc. Besides imparting required functional properties such as heat, abrasion and corrosion resistance to suit particular end use requirements, the glass and glass-ceramic coatings in general also provide good adherence, defect free surface and refractoriness. Systematic studies covering the basic science of glass and glass-ceramic coatings, the functional properties required for a particular end-use along with the various fields of application have been reviewed in this paper.     

Effect of noble metals in the decomposition of nitrous oxide over Fe-ferrierites

The decomposition of nitrous oxide was studied over Fe-ferrierite, Me-ferrierites and Fe/Me-ferrierites (Me: Pt, Rh and Ru). Flow as well as batch experiments were carried out and showed a synergy between Fe and Me ions. Ions of noble metals in Fe-ferrierite increased the catalytic activity in the sequence Pt < Rh ≅ Ru. Addition of NO substantially decreased the decomposition of N₂O over Rh/ferrierite and Ru/ferrierite, but not over bimetallic ferrierites. NO _x species created during the decomposition of nitrous oxide alone as well as with addition of NO, and employment of nitrous oxide labeled with ¹⁸O allowed us to assume a changing decomposition mechanism in the presence of Me ions in Fe-ferrierites.     

Assessing disharmony and disaffection in intimate relationships: Revision of the Marital Satisfaction Inventory factor scales.

Previous research has identified 2 broad components of distress in intimate relationships: overt conflict, or disharmony, and emotional distance, or disaffection. Using confirmatory factor analysis, the authors derived 2 broadband scales of disharmony and disaffection from the Marital Satisfaction Inventory-Revised (D. K. Snyder, 1997), building upon previous measures of these constructs (D. K. Snyder & Regts, 1982) derived from the original instrument. The new scales demonstrated high internal consistency and test-retest reliability, as well as discriminative validity and convergent validity with independent criteria of relationship functioning. Distinct distributions of these scales in community and clinical samples suggested their complementary role in research on intimate relationships and assessment of couples in treatment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Community response to environmental noise and the impact on cardiovascular risk score

Objective

The objective of our study was to investigate and evaluate the relationship between road traffic noise and cardiovascular risk.

Methods

The study sample (n = 659; 36.9% male, 63.1% female university students, mean age 22.83 ± 1.58 years) included a group exposed to road traffic noise (n = 280, L_eq,24 h = 67 ± 2 dB(A)) and a control group (n = 379, L_eq,24 h = 58.7 ± 6 dB(A)). Subjective response was determined by a validated noise annoyance questionnaire. The ten year risk of developing a coronary heart disease event was quantified as an evaluation of cardiovascular risk (SCORE60, Framingham 10-year risk estimation and projection to the age of 60, relative risk SCORE chart).

Results

Cardiovascular risk scores were significantly higher in the exposed group based on the Framingham scores projected to the age of 60, SCORE60 (AOR = 2.72 (95% CI = 1.21-6.15)) and the relative risk SCORE chart (AOR = 2.81 (1.46-5.41)).

Conclusions

These findings highlight the association between road traffic noise and cardiovascular risk.     

High-Rate Uncorrelated Bit Extraction for Shared Secret Key Generation from Channel Measurements

Secret keys can be generated and shared between two wireless nodes by measuring and encoding radio channel characteristics without ever revealing the secret key to an eavesdropper at a third location. This paper addresses bit extraction, i.e., the extraction of secret key bits from noisy radio channel measurements at two nodes such that the two secret keys reliably agree. Problems include 1) nonsimultaneous directional measurements, 2) correlated bit streams, and 3) low bit rate of secret key generation. This paper introduces high-rate uncorrelated bit extraction (HRUBE), a framework for interpolating, transforming for decorrelation, and encoding channel measurements using a multibit adaptive quantization scheme which allows multiple bits per component. We present an analysis of the probability of bit disagreement in generated secret keys, and we use experimental data to demonstrate the HRUBE scheme and to quantify its experimental performance. As two examples, the implemented HRUBE system can achieve 22 bits per second at a bit disagreement rate of 2.2 percent, or 10 bits per second at a bit disagreement rate of 0.54 percent.     

Combined exposure to cyanobacterial biomass, lead and the Newcastle virus enhances avian toxicity

Under environmental conditions, wild birds can be exposed to multiple stressors including natural toxins, anthropogenic pollutants and infectious agents at the same time.This experimental study was successful in testing the hypothesis that adverse effects of cyanotoxins, heavy metals and a non-pathogenic immunological challenge combine to enhance avian toxicity. Mortality occurred in combined exposures to naturally occurring cyanobacterial biomass and lead shots, lead shots and Newcastle vaccination as well as in single lead shot exposure. Mostly acute effects around day 10 were observed. On day 30 of exposure, there were no differences in the liver accumulation of lead in single and combined exposure groups. Interestingly, liver microcystin levels were elevated in birds co-exposed to cyanobacterial biomass together with lead or lead and the Newcastle virus. Significant differences in body weights between all Pb-exposed and Pb-non-exposed birds were found on days 10 and 20. Single exposure to cyanobacterial biomass resulted in hepatic vacuolar dystrophy, whereas co-exposure with lead led to more severe granular dystrophy. Haematological changes were associated with lead exposure, in particular. Biochemical analysis revealed a decrease in glucose and an increase in lactate dehydrogenase in single and combined cyanobacterial and lead exposures, which also showed a decreased antibody response to vaccination.The combined exposure of experimental birds to sub-lethal doses of individual stressors is ecologically realistic. It brings together new pieces of knowledge on avian health. In light of this study, investigators of wild bird die-offs should be circumspect when evaluating findings of low concentrations of contaminants that would not result in mortality on a separate basis. As such it has implications for wildlife biologists, veterinarians and conservationists of avian biodiversity.