Synthesis, Characterization, and Cytotoxicity Analysis of a Biodegradable Polyurethane

A polyester urethane was synthesized for use in a biodegradable scaffold. The polyurethane was synthesized in a two-step process: first, ester diol was synthesized from lactic acid and polyethylene glycol 400 (PEG 400), then it was polymerized with toluene diisocyanate using dibutyl tin dilaurate (DBTDL) as a catalyst to form a polyester urethane. Polyester urethane has tensile strength of 51-59 MPa and elongation at fracture of 369-439%. FTIR and XRD were used to confirm the formation and structure of the polymer. Hydrolytic degradation was studied in different alkali solutions and in saline water. In order to assess the cellular response of this material, cytotoxicity analysis was carried out against the cell line.     

Precipitation hardening in nickel-copper base alloy monel K 500

The occurrence of a significant amount of age hardening, due to the precipitation of the γ′ phase, has been demonstrated in the nickel-copper base alloy MONEL K 500. The microstructure of the precipitation-hardened and deformed alloy has been examined in peak-aged underaged and overaged conditions. An attempt has been made to compare the observed increments in strength in these three aged conditions to those predicted on the basis of relevant theoretical models.     

Favorable influence of ssDNA-functionalized SWCNT on the navigation pattern of C. elegans

Microsystem Technologies - Single-Walled Carbon Nanotubes (SWCNTs) are widely used as potential carriers in drug delivery systems. The objective of this work was to observe the effects of pristine,...     

Thin-film ferroelectrics of PZT of sol-gel processing

The ferroelectric effect has been demonstrated for sol-gel derived lead zirconate titanate (PZT) (53/47) thin films. The respective values of coercive field and remanent polarization were 4x10(6) V/m and 0.36 C/m(2). The thin-film fabrication process is simple and compatible with Si planar technology, and offers a wide variety of potential uses for counting, memory, and integrated optical circuit applications.     

Influence of Nano Silica on Mechanical and Durability Characteristic of Mortar made by Partial Replacement of Natural Fine Aggregate with Recycled Fine Aggregate

Silicon - To implement sustainability concepts in the construction industry, the possibility of utilizing the recycled fine aggregate obtained from the crushing of coarse aggregate debris of...     

Knowledge-based systems using neural networks for electron beam welding process of reactive material (Zircaloy-4)

Bead-on-plate welding of zircaloy-4 (a reactive material) plates was conducted using electron beam according to central composite design of experiments. Its predictive models were developed in the form of knowledge-based systems in both forward and reverse directions using neural networks. Input parameters considered for this welding of reactive metals were accelerating voltage, beam current and weld speed. The responses of the welding process were measured in terms of bead width, depth of penetration and micro-hardness. Forward mapping of the welding process was conducted using regression analysis, back-propagation neural network (BPNN), genetic algorithm-tuned neural network (GANN) and particle swarm optimization algorithm-tuned neural network (PSONN). Reverse mapping of this process was also carried out using the BPNN, GANN and PSONN-based approaches. Neural network-based approaches could model this welding process of reactive material in both forward and reverse directions efficiently, which is required for the automation of the same. The performance of the neural network models was found to be data-dependent. The BPNN could outperform the other two approaches for most of the cases but not all in both the forward and reverse mappings.     

Effect of organic modifiers on dynamic and static nanomechanical properties and crystallinity of intercalated clay–polycaprolactam nanocomposites

Polymer clay nanocomposites (PCN) of Polyamide6 and sodium montmorillonite are prepared using different organic modifiers (12‐aminolauric acid, n‐dodecylamine, and 1,12‐diaminododecane) to study effect of organic modifiers on structure and nanomechanical properties of PCN. Using X‐ray diffraction and differential scanning calorimetry, crystalline nature of PCNs are evaluated. Nanoscale viscoelastic properties of PCNs are evaluated using nanodynamic mechanical analyzer (NanoDMA). Nanoscale elastic modulus and hardness of PCNs are evaluated using nanoindenter. PCNs show enhancement in elastic modulus, storage modulus, loss modulus, and loss factor by maximum amount of 62.88%, 56.38%, 145.74%, and 71.43%, respectively, and decrease in percentage crystallinity by 16.52% compared to pure polymer. This result indicates that organic modifiers have effect on crystallinity and nanomechanical properties of PCN. To evaluate effect of clay loading on nanomechanical properties of PCN, PCN containing 12‐aminolauric acid is synthesized with different weight percent (3, 6, and 9% of weight of polymer) of organically modified montmorillonite (OMMT), which shows that nanomechanical properties of PCN improves with increase in clay loading. Our study reveals that change in crystallinity of polymer in PCN may have role in the enhancement of nanomechanical properties of PCNs in comparison to pristine polymer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Structure of Polymeric PbTiO3 Gels

The structural features of PbTiO₃ gels were found to be highly dependent on hydrolysis conditions. Gels formed from acid-catalyzed solutions were clear and rubbery, whereas base-catalyzed gels were translucent or cloudy with phase separation. Direct TEM observations determined that acid-catalyzed gels were fibrous in character and physically homogeneous, whereas base-catalyzed gels had a coarse texture. Analyses by EDX and SAD indicated that acidic gels were chemically homogeneous and microcrystalline, whereas basic gels were heterogeneous and amorphous.     

Genetic algorithm-based initial contour optimization for skin lesion border detection

Multimedia Tools and Applications - Automated segmentation has an essential role in detecting several diseases, such as skin lesions. In segmentation, the active contour (AC) is an efficient method...