Biosorption of cadmium (II) and lead (II) from aqueous solutions using mushrooms: A comparative study

Sorption capacity of oyster mushroom (Pleurotus platypus), button mushroom (Agaricus bisporus) and milky mushroom (Calocybe indica) were evaluated on biosorption of heavy metals, viz. cadmium (II) and lead (II) from aqueous solutions. The optimum sorption conditions were studied for each metal separately. The desired pH of the aqueous solution was found to be 6.0 for the removal of cadmium (II) and 5.0 for removal of lead (II) for all the mushrooms. The percent removal of both the metals was found to increase with the increase in biosorbent dosage and contact time. The fitness of the biosorption data for Langmuir and Freundlich adsorption models was investigated. It was found that biosorption of cadmium (II) and lead (II) ions onto the biomass of the three mushrooms were better suitable to Langmuir than Freundlich adsorption model. P. platypus showed the highest metal uptake potential for cadmium (q_max 34.96 mg/g) whereas A. bisporus exhibited maximum potential for lead (q_max 33.78 mg/g). Milky mushroom showed the lowest metal uptake capacity for both the metals. The present data confirms that mushrooms may be used as efficient biosorbent for the removal of cadmium (II) and lead (II) ions from aqueous solution.     

The flexible PEI composites

The present study investigates the compatibilizing effect of polyphosphazene on the blends of poly(ether imide) (PEI) and thermotropic liquid crystalline polymer (Vectra‐B). FTIR study showed that there was a partial interaction or chemical reaction between the PEI and LCP in the presence of compatibilizer. Polyphosphazene is compatibilized with both PEI and LCP, which was evident from DMA results. From the X‐ray diffraction study, it has been observed that the crystalline structure of PEI–LCP blends was increased with the addition of compatibilizer. The thermal study of the composites has been studied by DTA/thermo gravimetric analyses (TGA). TGA thermograms showed an increase in decomposition temperature of PEI–LCP blends in the presence of compatibilizer. Measurement of the tensile properties showed an increase in the elongation as well as enhanced modulus and strength. From SEM micrographs of tensile fractured surfaces, the addition of compatibilizer to PEI–LCP blends was found to increase the adhesion between the matrix and the dispersed phase. POLYM. COMPOS., 27:533–538, 2006. © 2006 Society of Plastics Engineers     

Arsenic groundwater contamination and its health effects in the state of Uttar Pradesh (UP) in upper and middle Ganga plain, India: a severe danger

This communication presents results of our 2-year survey on groundwater arsenic contamination in three districts Ballia, Varanasi and Gazipur of Uttar Pradesh (UP) in the upper and middle Ganga plain, India. Analyses of 4,780 tubewell water samples revealed that arsenic concentrations in 46.5% exceeded 10 microg/L, in 26.7%, 50 microg/L and in 10% 300 microg/L limits. Arsenic concentrations up to 3,192 microg//L were observed. The age of tubewells (n=1,881) ranged from less than a year to 32 years, with an average of 6.5 years. Our study shows that older tubewells had a greater chance of contamination. Depth of tubewells (n=3,810) varied from 6 to 60.5 m with a mean of 25.75 m. A detailed study in three administrative units within Ballia district, i.e. block, Gram Panchayet, and village was carried out to assess the magnitude of the contamination. Before our survey the affected villagers were not aware that they were suffering from arsenical toxicity through contaminated drinking water. A preliminary clinical examination in 11 affected villages (10 from Ballia and 1 from Gazipur district) revealed typical arsenical skin lesions ranging from melanosis, keratosis to Bowens (suspected). Out of 989 villagers (691 adults, and 298 children) screened, 137 (19.8%) of the adults and 17 (5.7%) of the children were diagnosed to have typical arsenical skin lesions. Arsenical neuropathy and adverse obstetric outcome were also observed, indicating severity of exposure. The range of arsenic concentrations in hair, nail and urine was 137-10,900, 764-19,700 microg/kg, and 23-4,030 microg/L, respectively. The urine, hair and nail concentrations of arsenic correlated significantly (r=0.76, 0.61, and 0.55, respectively) with drinking water arsenic concentrations. The similarity to previous studies on arsenic contamination in West Bengal, Bihar and Bangladesh indicates that people from a significant part of the surveyed areas in UP are suffering and this will spread unless drives to raise awareness of arsenic toxicity are undertaken and an arsenic safe water supply is immediately introduced.     

Effect of MQL and nanofluid on the machinability aspects of hardened alloy steel

Abstract

The current research comprises of various machinability aspects of 4340 hardened alloy steel which are scrutinized with in context of improvements in main cutting force, tool flank wear, crater wear, surface roughness, micro-hardness, machined surface morphology, chip morphology, chip reduction coefficient and apparent coefficient of friction under three different cutting fluid applications i.e. compressed air, water soluble coolant and nanofluid (using eco-friendly radiator coolant as the base fluid and Al₂O₃ as the nanoparticle) using uncoated cermet cutting inserts and a comparative assessment was performed to select which fluid performed better in terms of various machining attributes among three cutting fluids. The minimum quantity lubrication technique (MQL) was used in which a smaller volume of coolant sprinkled at high pressure. This method is found as the most effective alternative to minimize health risks and machining costs, which is quite high in other setups. The test specimen was machined at three different cutting speeds i.e. 100, 120 and 140?m/min along with two machining parameters i.e. feed and depth of cut were kept constant respectively at 0.2?mm/rev and 0.4?mm. Outcomes made a conclusion that Al₂O₃ enriched ecofriendly nanocoolant outperformed both compressed air and water soluble coolant in terms of every machinability aspects.     

Noncoherent MMSE multiuser receivers and their blind adaptiveimplementations

Three noncoherent minimum mean-squared error (NMSE)-based multiuser receivers are proposed for multipulse modulation. These receivers have a common MMSE prefilter and are followed by one of three phase-independent decision rules. The simplest decision rule selects the maximum magnitude of the MMSE filter outputs, and the other two account for the second-order statistics of the residual multiple-access interference that remains after MMSE filtering. Blind adaptive algorithms are then proposed for the three noncoherent MMSE receivers. The common adaptive algorithm for the MMSE prefilter, which is based on the stochastic approximation method, is shown to converge in the mean-squared error sense to the nonblind NMSE prefilter. Our convergence analysis yields new insight into the tradeoff between the rate of convergence and the residual mean-squared error. The noncoherent blind receivers obtained here do not require the knowledge of the received signals of any of the interfering users, and are hence well-suited for distributed implementation in cellular wireless networks or in communication systems that must operate in noncooperative environments     

Simulation‐based performance evaluation of routing protocols for mobile ad hoc networks

In this paper we evaluate several routing protocols for mobile, wireless, ad hoc networks via packetlevel simulations. The ad hoc networks are multihop wireless networks with dynamically changing network connectivity owing to mobility. The protocol suite includes several routing protocols specifically designed for ad hoc routing, as well as more traditional protocols, such as link state and distance vector, used for dynamic networks. Performance is evaluated with respect to fraction of packets delivered, endtoend delay, and routing load for a given traffic and mobility model. Both small (30 nodes) and medium sized (60 nodes) networks are used. It is observed that the new generation of ondemand routing protocols use much lower routing load, especially with small number of peertopeer conversations. However, the traditional link state and distance vector protocols provide, in general, better packet delivery and endtoend delay performance.     

Multi-Objective Approach for Reconfiguration of Distribution Systems with Distributed Generations

This paper presents a fuzzy multi-objective based heuristic algorithm for network reconfiguration of distribution systems considering distributed generations (DGs). The objectives of reduction of real power loss, branch current carrying capacity limit, maximum and minimum voltage constraints, and feeder load balancing are considered for performance enhancement of the distribution system. Since these objectives are non-commensurable and difficult to solve simultaneously using conventional approaches, they are converted into fuzzy domain and a fuzzy multi-objective function is formulated. A sensitivity analysis based on voltage profile improvement and real power loss reduction is used for obtaining optimal locations of DGs and genetic algorithm is used for optimal sizing of DGs. The proposed reconfiguration algorithm is implemented in two stages, initially in the first stage without incorporating DGs and in the second stage incorporating DGs for obtaining an optimal distribution system network reconfiguration. The advantage of the proposed method is demonstrated through a seventy node four feeders and a sixteen node three feeders distribution systems.     

Influence of temperature, voltage and hydrogen on the reversible transition of electrical conductivity in sol–gel grown nanocrystalline TiO2 thin film

Undoped nanocrystalline p-type TiO₂ thin film was deposited by sol–gel method on a thermally oxidized p-Si (2–5 Ω cm resistivity and $ \left\langle {100} \right\rangle $ orientation) substrate. The thin film was characterized by two-dimensional X-ray Diffraction (2D-XRD) and Field Emission Scanning Electron Microscopy (FESEM) to confirm the formation of stable nano crystalline anatase titania and to determine the grain size (~10 nm). Optical absorption spectroscopy was carried out to ascertain the band gap of the material. Two lateral Pd contacts were used as the metal electrodes to TiO₂ thin film to study the electrical conductivity. A clear p- to n-type transition was observed at 240 °C and a bias voltage of 0.83 V and the effect was enhanced on exposure to H₂ gas. The thin film showed fully n-type conductivity at 275 °C and 0.1 V. However, the reversal of the type of conductivity from n- to p-type was observed below 240 °C during lowering the temperature. The creation of oxygen vacancy and the diffusion of lattice oxygen to the surface of TiO₂ thin film might be the most possible mechanism of such transitions. Presence of hydrogen enhanced the process.     

Improvement of lubrication and cooling in grinding

The presence of air boundary layer around a grinding wheel impedes the proper entry of cutting fluid into grinding zone and thereby lubrication and cooling are hampered. It leads to the thermal damage to the workpiece and rapid wheel wear. This experimental work is aimed at increasing the lubrication and cooling effects in grinding by a novel method of using scraper board. The experiments are conducted, using the scraper board, to find the critical region where the air pressure is zero. The coolant jet has then impinged into the grinding zone which is maintained within the critical region. The requirement of specific energy, surface texture, and mechanical properties of the ground surface are analyzed and compared with the traditional grinding and the grinding at various positions of scraper board. Results show that the grinding ratio improved by 35.6and 119%, surface roughness decreased by 36 and 54.2%, while the requirement of specific energy is reduced by 50.8 and 57.3% when scraper board is positioned at the critical distance in comparison to the 57.5° position and no scraper board, respectively. The results indicate that the introduction of fluid in the present method can improve the process efficiency and the product quality effectively.