Study on structure-property relationship of polyimide blends

Summary Three pairs of polyimide/polyimide blends (50/50 wt%) with different molecular structures were prepared by two ways, i.e. mixing of the polyamic acid precursors with subsequent imidization, and direct solution mixing of the polyimides. The blends were studied with DMA technique. The results obtained show that all the blends prepared with these two different ways are miscible, as there existed only one glass transition temperature (Tg) for all the blends. It is suggested that the miscibility of these polyimide/polyimide blends is a result of the strong inter-molecular charge-transfer interaction between the chains of their components.     

5—烃基—2,3—二甲基吡嗪的合成

2,3-二基-5,6-二氢吡嗪与醛或酮在氢氧化钠的乙醇溶液中反应制得16种5-烃基-2,3-二甲基吡嗪。产率66%～90%。其中6种为新合成的化合物。产率17%～87.9%。     

Augment low-field intra-operative MRI with preoperative MRI using a hybrid non-rigid registration method

Background

Preoperatively acquired diffusion tensor image (DTI) and blood oxygen level dependent (BOLD) have been proved to be effective in providing more anatomical and functional information; however, the brain deformation induced by brain shift and tumor resection severely impairs the correspondence between the image space and the patient space in image-guided neurosurgery.

Method

To address the brain deformation, we developed a hybrid non-rigid registration method to register high-field preoperative MRI with low-field intra-operative MRI in order to recover the deformation induced by brain shift and tumor resection. The registered DTI and BOLD are fused with low-field intra-operative MRI for image-guided neurosurgery.

Results

The proposed hybrid registration method was evaluated by comparing the landmarks predicted by the hybrid registration method with the landmarks identified in the low-field intra-operative MRI for 10 patients. The prediction error of the hybrid method is 1.92 ± 0.54 mm, and the compensation accuracy is 74.3 ± 5.0%. Compared to the landmarks far from the resection region, those near the resection region demonstrated a higher compensation accuracy (P-value = .003) although these landmarks had larger initial displacements.

Conclusions

The proposed hybrid registration method is able to bring preoperatively acquired BOLD and DTI into the operating room and compensate for the deformation to augment low-field intra-operative MRI with rich anatomical and functional information.     

基于海量搜索历史数据的用户兴趣模型

针对互联网搜索引擎环境中,基于海量搜索历史数据分析用户兴趣的问题,提出一种改进的用户兴趣模型。该模型根据用户搜索的历史数据,结合向量空间模型（ VSM ）和TF-IDF算法,递归地回溯出用户兴趣权重列表。为解决用户兴趣变化和时间性能的问题,该模型引入时间遗忘机制进行动态更新,并在Hadoop分布式系统架构下利用MapReduce分布式编程模型进行实现。实验结果表明,改进的用户兴趣模型的查准率和召回率都能达到50',具有较好的可行性和可用性。     

连续式双膜分离塔的数学模型

本文建立了适用于连续式双膜分离塔的数学模型。用实验数据验证了数学模型的可行性和合理性。将本模型与已发表的模型进行了比较,结果表明本模型具有形式简单、计算方便和适用范围更宽广等优点。     

Anisotropic geodesics for live‐wire mesh segmentation

We present an interactive method for mesh segmentation that is inspired by the classical live‐wire interaction for image segmentation. The core contribution of the work is the definition and computation of wires on surfaces that are likely to lie at segment boundaries. We define wires as geodesics in a new tensor‐based anisotropic metric, which improves upon previous metrics in stability and feature‐awareness. We further introduce a simple but effective mesh embedding approach that allows geodesic paths in an anisotropic path to be computed efficiently using existing algorithms designed for Euclidean geodesics. Our tool is particularly suited for delineating segmentation boundaries that are aligned with features or curvature directions, and we demonstrate its use in creating artist‐guided segmentations.     

Phase Assemblages of Pr α-sialon Derived from SHS-ed Powders and TEM Study on the Nucleation of Pr α-sialon

The Pr α-sialon powders prepared by self-propagating high-temperature synthesis (SHS), consisting of 55 wt% Pr α-sialon and 45 wt% of β-sialon (abbreviated as α' and β'), were hot-pressed at 1800°C for 1 h. The results showed that Pr α' phase would transfer to β' with the appearance of JEM phase (Pr(Si_{6− z} Al _z )(N_{10− z} O _z )) after sintering, thus resulting in the increase of β' phase to 86 wt%. The addition of Y₂O₃ into SHS-ed Pr α' powders as the starting materials restrains the transformation of α' to β' and prevents the formation of JEM phase as well. The nucleation mechanism of Pr α' grain during hot-pressing was investigated in terms of transmission electron microscope and energy-dispersive spectrometer analysis. Two nucleation modes of Pr α' grains were found, i.e., nucleating on the undissolved Pr α' grains and on the nuclei of (Pr, Y) α' grains precipitated from liquid phase.     

凝结水再循环管道振动原因及减振措施

对比了福建省内某电厂一期、二期工程600 MW发电机组凝结水再循环管道的设计和布置,经过分析,得出了一期管道振动的原因。在二期设计中做出了一些改进,基本解决了凝结水再循环管道的振动问题。     

计算机局域网硬件常见故障及维修处理方法

随着网络的逐步普及,局域网的建设走向信息化已成为必然选择,它不仅为现代化教学,综合化信息管理,办公自动化等一系列应用提供基本操作平台而且能提供多种服务。本人联系工作实践,阐述局域网常见故障和处理的方法,并针对计算机局域网常见硬件故障,提出相应处理对策。     

Oxidative dehydrogenation of ethane over Co–BaCO3 catalysts using CO2 as oxidant: effects of Co promoter

Co–BaCO₃ catalysts exhibited high catalytic performance for oxidative dehydrogenation of ethane (ODE) using CO₂ as oxidant. The maximal formation rate of C₂H₄ was 0.264 mmol · min⁻¹ · (g · cat.)⁻¹ (48.0% C₂H₆ conversion, 92.2% C₂H₄ selectivity, 44.3% C₂H₄ yield) on 7 wt% Co–BaCO₃ catalyst at 650 °C and 6000 ml. (g · cat.)⁻¹. h⁻¹. Co–BaCO₃ catalysts were comparatively characterized by XRF, N₂ isotherm adsorption-desorption, XRD, H₂-TPR and LRs. It was found that Co⁴⁺–O species were active sites on these catalysts in ODE with CO₂. The redox cycle of Co–O species played an important role on the catalytic performance of Co–BaCO₃ catalysts. On the other hand, the co-operation of BaCO₃ and BaCoO₃ was considered to be one of possible reasons for the high catalytic activity of these catalysts.