纳米陶瓷及其纳米复相陶瓷的研究现状

综述了纳米陶瓷和纳米复相陶瓷的的研究现状．探讨了纳米陶瓷的力学性能及其热喷涂纳米陶瓷涂层存在的问题．分析了纳米复相陶瓷的增韧机理，为纳米陶瓷的研究和应用提供了理论依据。     

Preparation and characterization of porous carbon beads and their application in dispersing small metal crystallites

Porous carbon beads were prepared by the pyrolysis of poly(vinylidene chloride) beads that were synthesized by suspension polymerization. After prolysis treatment at 180–300 °C under argon stream, the polymeric beads were further carbonized at 1000 °C for 3 h under argon stream to acquire porous carbon beads, of which the specific surface area was about 1000 m²/g, and pore size was mainly in the width range of 0.8–1.2 nm. The carbon structure and surface chemical composition characterized by X-ray diffraction and X-ray photoelectron spectroscopy, depended on the preparation temperature and the relations between them were examined. The characterization of the carbon beads by scanning electron microscopy, atomic force microscopy presented the morphological structure of the carbon beads surface and a global view of pores. The dispersion of nickel crystallites on the carbon beads surface was characterized by electron microprobe analysis. This study reveals that uniform surface morphological structure leads to the fine dispersion of metal crystallites.     

Automatic inpainting by removing fence-like structures in RGBD images

Recent inpainting techniques usually require human interactions which are labor intensive and dependent on the user experiences. In this paper, we introduce an automatic inpainting technique to remove undesired fence-like structures from images. Specifically, the proposed technique works on the RGBD images which have recently become cheaper and easier to obtain using the Microsoft Kinect. The basic idea is to segment and remove the undesired fence-like structures by using both depth and color information, and then adapt an existing inpainting algorithm to fill the holes resulting from the structure removal. We found that it is difficult to achieve a satisfactory segmentation of such structures by only using the depth channel. In this paper, we use the depth information to help identify a set of foreground and background strokes, with which we apply a graph-cut algorithm on the color channels to obtain a more accurate segmentation for inpainting. We demonstrate the effectiveness of the proposed technique by experiments on a set of Kinect images.     

隧道窑烟气废热回收利用技术

本文主要介绍了该项目在湖南省铜官陶瓷总公司推广应用实例，论述本技术改革传统隧道窑预热带及冷却带的结构．开发利用隧道密的烟气度热．进一步挖掘冷却带余热的潜力．使隧道窑余热利用率由３０％左右提高到５０％以上。用来烘干陶瓷半成品、石膏模、匣体取代锅炉蒸汽干燥，节能显著。     

光学纯去氢枞酸的制备与表征

用化学方法由歧化松香制得光学纯去氢枞酸，并以ＵＶ、ＩＲ、＾１ＨＮＭＲ、ＭＳ、元素分析和旋光对其结构进行了表征。     

Production of human normal adult and fetal hemoglobins in Escherichia coli

A hemoglobin expression system in Escherichia coli is described. In order to produce authentic human hemoglobin, we need to co-express both methionine aminopeptidase and globin genes under the control of a strong promoter. We have constructed three plasmids, pHE2, pHE4 and pHE7, for the expression of human normal adult hemoglobin and a plasmid, pHE9, for the expression of human fetal hemoglobin, in high yields. The globin genes can be derived from either synthetic genes or human globin cDNAs. The extra amino-terminal methionine residues of the expressed globins can be removed by the co-expressed methionine aminopeptidase. The heme is inserted correctly into the expressed alpha- globin from our expression plasmids. A fraction (approximately 25%) of the heme is not inserted correctly into the expressed beta- or gamma- globin. However, the incorrectly inserted hemes can be converted into the correct conformation by carrying out a simple oxidation-reduction process on the purified hemoglobin molecule. We have investigated the functional properties of the expressed hemoglobins by measuring their oxygen-binding properties and their structural features by obtaining their 1H-NMR spectra. Our results show that authentic human normal adult and fetal hemoglobins can be produced from our expression plasmids in E. coli and in high yields. Our expression system allows us to design and to produce any recombinant hemoglobins needed for our research on the structure-function relationship in hemoglobin.      

基于多子群的社会群体优化算法

社会群体优化算法(social group optimization,SGO)是一种基于社会群体学习而提出的一种新型优化算法。针对社会群体优化算法易于陷入局部最优问题,提出了一种多群社会群体学习算法（MPSGO）。本算法采用多子群学习方法,对算法两个阶段的个体学习方法进行改进,在维持群体收敛性能的前提下提高群体多样性,同时对部分个体中引入量子学习,使个体学习的有用信息得以增强;此外,每隔一定代数对子群进行随机重组,既能保证各子群个体充分进化,又维持了子群多样性。在设计算法的基础上,分析了其收敛性和多样性;通过与其他四种算法进行对比实验,验证了改进后算法性能更优。     

双阳煤在PKM气化炉试烧总结

介绍了在PKM气化炉中弱粘结性双阳煤的试烧情况,并给出了主要工艺参数控制范围。试烧结果表明:依兰煤中配入50%双阳煤,汽氧比6.0:1时,气化炉工况良好。     

离子自拆分法合成D-(一)-对羟基苯甘氨酸

研究了用离子自拆分方法拆分外消旋对羟基苯甘氨酸(DL-HPG)而合成D-(—)-对羟基苯甘氨酸(D-HPG)。采用正交试验确定了最佳反应条件:在丙酮和水的混合溶剂中,等物质的量的DL-HPG和硫酸在60℃下加入D-HPG,搅拌反应15min左右,降温过滤得到D-HPG的硫酸盐,水解即可得到D-HPG(光学纯度99％),一次性总收率达到20％。适于工业生产。     

Manipulating the phase morphology in PPS/PA66 blends using clay

By adding a small amount of clay into poly(p‐phenylene sulfide) (PPS)/polyamide 66 blends, the morphology was found to change gradually from sea–island into cocontinuity and lamellar supramolecular structure, as increasing of clay content. Clay was selectively located in the PA66 phase, and the exfoliated clay layers formed an edge‐contacted network. The change of morphology is not caused by the change of volume ratio and viscosity ratio but can be well explained by the dynamic interplay of phase separation between PPS and PA66 through preferential adsorption of PA66 onto the clay layers and through layer–layer repulsion. This provides a means of manipulating the phase morphology for the immiscible polymer blends. The mechanical and tribological properties of PPS/PA66 blends with different phase morphologies (different clay contents) were studied. Both tensile and impact strength of the blends were found obviously increased by the addition of clay. The antiwear property was greatly improved for the blends with cocontinuous phase form. Our work indicates that the phase‐separating behavior of polymer blends contained interacting clay can be exploited to create a rich diversity of new structures and useful nanocomposites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007