Design and simulation of the PV/PEM fuel cell based hybrid energy system using MATLAB/Simulink for greenhouse application

In this study, design and optimization of the hybrid renewable energy system consisting of Photovoltaic (PV)/Electrolyzer/Proton Exchange Membrane Fuel Cell (PEMFC) was investigated to provide electricity and heat for Greenhouse in ?anl?urfa (Turkey). The coupling of a photovoltaic system with PEMFC was preferred to supply continuous production of electric energy throughout the year. Additionally, produced heat from PEMFC was used to heating of the greenhouse by micro cogeneration application. The MATLAB/Simulink was applied to the design and optimization of the proposed hybrid system. In the designed system, solar energy was selected to produce the Hydrogen (H₂) required to run the electrolyzer. In cases where the solar energy is not sufficient and cannot meet the electricity requirement for the electrolyzer; the H₂ requirement for the operation of the PEMFC was met from the H₂ storage tanks and energy continuity was ensured. The electrolyzer was designed for H₂ demand of the 3 kW PEMFC which were met the greenhouse energy requirement. PEMFC based hybrid system has 48% electrical and 45% thermal efficiencies. According to optimization results obtained for the proposed hybrid system, the levelized cost of energy was found 0.117 $/kWh. The obtained results show the proposed PV/Electrolyzer/PEMFC hybrid power system provides an applicable option for powering stand-alone application in a self-sustainable expedient.     

PCDD,PCDF and PCB contamination in Atherina boyeri (Risso, 1810) from Turkey

The levels of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyls (DL-PCBs) and indicator polychlorinated biphenyls were measured in Atherina boyeri (Risso, 1810) samples collected from Hirfanl? Dam Lake, Turkey in 2008 and 2009.Concentrations of PCDDs–PCDFs were detected as 0.16 and 0.17 pg TEQ₍₁₉₉₈₎ g^?1 wet weight while contamination levels of DL-PCBs were found as 0.42 and 0.38 pg TEQ₍₁₉₉₈₎ g^?1 wet weight in fish samples. The concentrations of total indicator PCBs in fish samples were found as 1.5 ng g^?1 and 0.9 ng g^?1 wet weight. Concentrations of PCDDs–PCDFs and DL-PCBs were below the EU regulation limits.     

Neither oxidized nor anti-oxidized low-density lipoprotein level is associated with atherosclerosis or mortality in hemodialysis patients

It is anticipated that oxidized low‐density lipoprotein (oxLDL) and anti‐oxLDL are associated with atherosclerosis and mortality. However, data on this issue are controversial and limited. We aimed to investigate the effect of these two markers on the extent and progression of atherosclerosis and mortality in a group of hemodialysis patients. In this prospective observational study with a follow‐up of 36 months, 124 hemodialysis patients were studied. Ninety‐five patients underwent carotid intima media thickness (CA‐IMT) measurement by B‐Mode ultrasonography both at baseline and at the end of the study. oxLDL and anti‐oxLDL were measured by enzyme‐linked immunosorbent assay. The extent and progression of CA‐IMT, along with overall and cardiovascular mortality, were assessed. The mean age at baseline was 54.0 ± 14.8 years, 57.3% male and 20% diabetic. The mean oxLDL and anti‐oxLDL levels were 8.11 ± 3.16 mU/L and 1.30 ± 0.31, respectively. Baseline mean CA‐IMT was 0.82 ± 0.20 mm. Fifteen patients died during a follow‐up period of 28.5 ± 6.6 months, 11 from cardiovascular causes. Only oxLDL, not anti‐oxLDL, was correlated with the extent of atherosclerosis at baseline. However, both had no role in the progression of atherosclerosis. Also, in unadjusted and adjusted models, both parameters were not associated with overall or cardiovascular mortality. Neither oxLDL nor anti‐oxLDL level is associated with the progression of atherosclerosis or mortality in hemodialysis patients.     

Electropolymerization and ion sensitivity of chemiluminescent thienyl systems

Redox driven chemiluminescent (CL) compounds based on thienyl and pyridazine systems, namely 2,3-dihydrothieno(3,4-d)pyridazine-1,4-dione (T-Lum) and 5,7-di-thiophen-2-yl-2,3-dihydro-thieno[3,4-d]pyridazine-1,4-dione (TTT-Lum), were synthesized. Soluble compounds both in organic media and basic aqueous solution were found to give CL and electroluminescent (EL) reactions by the treatment of oxidants (H₂O₂ and KMnO₄) and by an external potential pulse on the working electrode, respectively. Furthermore, the CL reaction can be speeded up by Fe³⁺ ion or blood samples. On the other hand, one of the compounds, TTT-Lum, can be polymerized successfully via electrochemically both in 0.1 M LiClO₄/acetonitrile containing 5% of borontrifluoro diethylether (BF₃-Et₂O) and neat BF₃-Et₂O solution. The corresponding polymer film (PTTT-Lum) bearing CL units has a very stable and a well-defined reversible redox couple. Also, the electrochromic polymer film has a band gap of 1.74 eV and exhibits EL behavior.     

Effects of controlled atmosphere storage and low-dose irradiation on potato tuber components affecting acrylamide and color formations upon frying

The effects of normal and controlled atmosphere combinations on tuber components responsible for acrylamide formation were studied during prolonged storage at 9±1 °C using the tubers of “Agria” and “Russet Burbank.” The effects of low-dose irradiation (50, 200 Gy) prior to normal atmosphere storage were also studied. There was only a limited increase in the concentrations of sugars during 6 month of storage under normal atmosphere conditions. Low-dose irradiation slightly decreased the rate of sweetening in the tubers. The potential of acrylamide formation remained almost the same; however, the loss of firmness became clearer during 6 month of storage under normal atmosphere conditions. Controlled atmosphere storage in which O₂ was deficient to a sufficient respiration increased the concentrations of sugars, and thus, the potential of acrylamide formation in potatoes upon frying at 170 °C for 10 min. The sum of glucose and fructose concentrations showed a good correlation (r ²∼0.90) with the potential of acrylamide formation for both cultivars.     

Bubbly cavitating flow generation and investigation of its erosional nature for biomedical applications

This paper presents a study that investigates the destructive energy output resulting from hydrodynamic bubbly cavitation in microchannels and its potential use in biomedical applications. The research performed in this study includes results from bubbly cavitation experiments and findings showing the destructive effects of bubbly cavitating flow on selected solid specimens and live cells. The bubbles generated by hydrodynamic cavitation are highly destructive at the surfaces of the target medium on which they are carefully focused. The resulting destructive energy output could be effectively used for biomedical treatments, such as destroying kidney stones (renal calculi) or killing cancer cells. Motivated by this potential, the cavitation damage to cancerous cells and material removal from chalk pieces (which possess similar material properties as some kidney stones) was investigated. Our results showed that cavitation could induce damage both on chalk pieces and leukemia/lymphoma cells. We discovered that hydrodynamic cavitation exposure had early and delayed effects on cancer cell survival. Hence, the potential of hydrodynamic bubbly cavitation generated at the microscale for biomedical treatments was revealed using the microchannel configuration as a microorifice (with an inner diameter of 147 μm and a length of 1.52 cm), which acts as the source of bubbly cavitating flows.     

Tetrakis(alkylthio)-substituted lutetium bisphthalocyanines for sensing NO2 and O3

In this study, the nitrogen dioxide (NO₂) and ozone (O₃) sensing properties of a series bis[tetrakis(alkylthio) phthalocyaninato] lutetium(III) complexes [(C_nH_2n+1S)₄Pc]₂Lu(III) (n = 6, 10, 16) are investigated as a function of concentration in the temperature range between 25 °C and 150 °C. The concentration ranges were 1–10 ppm for NO₂, and 50 ppb–1 ppm for O₃. The response time and the sensor response to NO₂ are measured for approximately 1 min and 100% ppm⁻¹, respectively, for compound 1 at room temperature. At room temperature, all compounds are in the solid phase. The response time decreases to a few seconds with increasing operation temperature to 150 °C. At this temperature, all compounds are in the liquid crystal phase. The fastest response to oxidizing gases is observed at the liquid crystal phase of the Pcs. It has also been observed that the response time and the sensor response depend on the alkyl chain lengths of the Pcs. The doping effect of oxygen has been determined under high purity nitrogen N₂ flow, after exposure to dry air, at a different period of time and after annealing. It has been found that the conductivities of [(C_nH_2n+1S)₄Pc]₂Lu(III) thin films increased after exposure to dry air and the conduction mechanism also changed from ohmic behavior to space-charge-limited conduction.     

A new electrochromic copolymer based on dithienylpyrrole and EDOT

A new compound, namely diethyl 2,5-di(thiophen-2-yl)-1H-pyrrole-3,4-dicarboxylate (1), was copolymerized with 3,4-ethylenedioxythiophene (EDOT) via electrochemical method. The copolymer exhibits multicolor electrochromic property: It is found that the copolymer, poly(1-co-EDOT), has a specific optical band gap (1.71 eV) to reflect and/or transmit reddish brown color in the neutral state, and it can be switched to reddish orange, orange, yellowish green and blue colors upon oxidation in a low switching time (1.0 s). Importantly, these colors are essential for camouflage and/or full color electrochromic device/display applications. In addition to these, the obtained copolymer has a coloration efficiency of 173 cm²/C at 500 nm.     

DressBoard: An Embedded Virtual Try-On System for Ties and Bowties

In real life, trying a dress is generally physically exhausting and time consuming. In this study, a novel embedded virtual try-on system for ties and bowties is proposed, which will save time and enhance the shopping experience. The presented system is based on human computer interaction with embedded design, where the goal is to simulate tie/bowtie trial on a person in the camera view. Users can choose a tie/bowtie model available in the database via a touch screen. The system will then fit the selected model rapidly and accurately, and display the fitting result. Performance of the proposed system is experimentally evaluated on images acquired in a real-life scenario. The results showed that both fitting accuracy and process time vary almost-linearly with image resolution, where real-time and accurate (average error varies in the 0.5–5.0 cm range by resolution) performance can be achieved. In addition, the proposed system can handle fitting in videos, where experimental evaluations revealed real-time, accurate, and robust (to illumination change and image variations) performance even in the absence of collared garment.     

The Triple Helix as a model to analyze Israeli Magnet Program and lessons for late-developing countries like Turkey

Although the systemic changes towards innovation networking between university-industry and governmental actors have recently found a place on the international policy and literature agenda, networking between the organizations and people - for the national survival, production and growth - has been deeply rooted in the Israeli system even before the establishment of the Israeli State in 1948. Internal and international constraints fostered the formation of personal links, as did institutional settings that promoted networking. This paper reviews the interaction of societal, organizational and cultural features that render innovation networks in Israel successful. The research focuses on the impacts of the Israeli Magnet Program on the Israeli R&D growth and performance. The implications of innovation networks for a late-developing country like Turkey are reviewed in the contexts of catching-up and cross-regional collaboration between the Israeli and Turkish industries and academies.