Use of float consumption rate in resource leveling of construction projects

The management of resources has been claimed to be as important as scheduling methods. Inefficiency in managing resources may bring about severe delays and cost overruns caused by resource shortages in some cases and/or idle resources in others. Therefore, resources should be utilized efficiently to prevent project failures. Resource leveling is one of the approaches that are used for the management of resources. It aims to minimize fluctuations, peaks, and valleys in resource utilization without changing the completion time of a project and the number of resources required. Although the main principle behind traditional resource leveling is achieving an even flow of resources while the original project duration remains unchanged, the literature supports the need to develop an efficient model that discriminates among the activities that are selected for participation in resource leveling. For this purpose, this study has developed a model that considers the float consumption rates of activities in resource leveling. The float consumption rate is the percentage that is set to determine the maximum amount of float which will be consumed to shift the start time of the activity. The proposed model allows a scheduler to assign float consumption rates to each activity that can be used during the resource leveling procedure. When the required information is inputted, the proposed model automatically changes the required daily resources as it shifts the noncritical activities along their available total float times. The proposed model is expected to minimize the likelihood of severe delays and cost overruns. The model is demonstrated by constructing a network and its resource utilization histograms.     

Formulation and Characterization of Formaldehyde Cross-linked Degradable Starch Microspheres Containing Terbutaline Sulfate

ABSTRACT

Preparation of starch microspheres using epichlorohydrin is a time consuming method and requires around 18 hr for cross-linking reaction. To reduce reaction time, terbutaline sulfate (TBS) loaded degradable starch microspheres (DSM) were prepared using formaldehyde as the cross-linking agent. All microspheres were spherical in shape and had a porous, rough surface with a mean particle size of 18–24 μm. Whatever the cross-linking time, it was seen that the release of the TBS was not complete during the release experiments. The influence of enzyme on the degradation of microspheres was moderate. Following intravenous administration, initial uptake of microspheres by the lung was higher than those of other organs.     

Fuzzy α-discounting method for multi-criteria decision-making

The α-Discounting Method was developed to be an alternative to and extension of the Analytical Hierarchy Process (AHP) to solve multi-criteria decision-making (MCDM) problems with non-commensurable and conflicting criteria. In contrast to the AHP, this method works not only for pairwise comparisons but also for n-wise comparisons if relative importance of criteria can be expressed in a system of linear homogenous equations. This method also has a comparative advantage as it can transform those MCDM problems, classified as inconsistent by the AHP, into a consistent form. This study briefly compares the two methods and then develops the Fuzzy α-Discounting Method for Multi-Criteria Decision Making (Fα-DM MCDM). Two illustrative fuzzy MCDM problems from the literature have been solved to show how the Fα-DM MCDM works.     

An eclectic approach to design tunable amplifiers

Broadband amplifiers that can accommodate commercial communication standards such as GSM, UMTS, Wi‐Fi, and Wi‐Max are extremely important for radio equipment manufacturers. To achieve this coverage, the amplifier should provide high gain and efficiency over a band from 800 to 5200 MHz. Although there are transistor devices that have cut‐off frequencies well over these frequencies, amplifiers covering such a broad‐bandwidth are difficult to design due to the requirement of broadband matching networks. In this work, design of broadband tunable matching networks is investigated using Real Frequency Direct Computational Technique (RF‐DCT). In order to be able to work on sample structures, impedance transforming filters are chosen and a broadband tunable matching network has been designed. Implementation of tunable inductors is investigated and the performance of a tunable matching network using tunable inductors and capacitors is demonstrated. Eventually a broadband frequency tunable amplifier has been designed using the tunable inductor concept. © 2013 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2013.     

Isopropyl alcohol: an unusual, powerful, ‘green’ solvent for the preparation of silicone–urea copolymers with high urea contents

Isopropyl alcohol (IPA) is used as the reaction solvent for the preparation of silicone–urea copolymers. Reactivity of isopropanol with bis(4-isocyanatocyclohexyl)methane (HMDI) was investigated at 23 °C using infrared spectroscopy. Spectroscopic studies indicated very low reactivity of IPA towards HMDI at 23 °C. High molecular weight segmented silicone–urea copolymers were prepared through the reaction of HMDI with aminopropyl and N-methylaminopropyl terminated polydimethylsiloxane (PDMS) oligomers and three different chain extenders, ethylene diamine (ED), hexamethylene diamine (HMDA) and 2-methyl-1,5-diaminopentane (Dytek A). Number average molecular weights of PDMS oligomers varied between 900 and 7000 g/mol, respectively. Reactions were carried out at room temperature in IPA. Silicone–urea copolymers with urea hard segment content between 10 and 42% by weight were prepared. Thermal and mechanical characterization of the copolymers indicated the formation of microphase-separated systems with excellent tensile strengths. Interestingly, structure of the diamine chain extender did not show any influence on the mechanical properties of the homologous series of silicone–urea copolymers.     

Non‐covalent interactions of pyrene end‐labeled star poly(ɛ‐caprolactone)s with fullerene

Pyrene end‐labeled star poly(?‐caprolactone)s (PCLs) with polyhedral oligomeric silsesquioxane (POSS) core were prepared by combination of copper(I)‐catalyzed azide–alkyne cycloaddition (CuAAC) click chemistry and ring‐opening polymerization techniques. First, ?‐caprolactone (?‐CL) is polymerized by using 1‐pyrene methanol as initiator and stannous octoate as catalyst to obtain α‐pyrene‐ω‐hydroxyl telechelic PCL with different chain lengths. Then, its hydroxyl group is converted to acetylene functionality by esterification reaction with propargyl chloroformate. Finally, the CuAAC click reaction of α‐pyrene‐ω‐acetylene telechelic PCL with POSS‐(N₃)₈ leads to corresponding pyrene end‐labeled star‐shaped PCLs. The successful synthesis of pyrene end‐labeled star polymers is clearly confirmed by ¹H‐nuclear magnetic resonance, Fourier transform infrared, gel permeation chromatograph, differential scanning calorimeter, and thermogravimetric analysis. Furthermore, non‐covalent interactions of obtained star polymers with fullerene are investigated in liquid media. Based on Raman spectroscopy and visual investigations, the star polymer having shorter chain length exhibited better and more stable dispersion with fullerene. The amount of pyrene units present per polymer chains can directly influence the dispersion stability of fullerene. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46520.     

Nutrient composition of hazelnut (Corylus avellana L.) varieties cultivated in Turkey

In this study, chemical composition of the 17 different hazelnut varieties grown in the Black Sea Region of Turkey was investigated. The main fatty acids in hazelnut varieties were oleic (79.4%), linoleic (13.0%) and palmitic acid (5.4%). The ratios of polyunsaturated/saturated and unsaturated/saturated fatty acids of hazelnuts varieties were found to be between 1.23 and 2.87, and 11.1 and 16.4, respectively. The average niacin, vitamin B₁, vitamin B₂, vitamin B₆, ascorbic acid, folic acid, retinol and total tocopherol contents of hazelnut kernels were 1.45 mg/100 g, 0.28 mg/100 g, 0.05 mg/100 g, 0.5 mg/100 g, 2.45 mg/100 g, 0.043 mg/100 g, 3.25 mg/100 g and 26.9 mg/100 g, respectively. The amount of the essential amino acids, mostly as arginine (2003 mg/100 g) and leucine (1150 mg/100 g), and the non-essential amino acids, mostly as glutamic acid (2714 mg/100 g) and aspartic acid (1493 mg/100 g) were also determined in the hazelnut varieties. Mineral compositions of the hazelnut varieties, e.g., K, Mn, Mg, Ca, Fe, Zn, Na and Cu were (averagely) measured as 863 mg/100 g, 186 mg/100 g, 173 mg/100 g, 5.6 mg/100 g, 4.2 mg/100 g, 2.9 mg/100 g, 2.6 mg/100 g and 2.3 mg/100 g, respectively.     

Methylene blue adsorption from aqueous solutions to flexible poly(vinyl chloride) silica composites

Methylene blue (MB) adsorption studies were performed with poly(vinyl chloride)‐(dioctyl phthalate)‐silica composites, which were obtained by using plastisol‐plastigel technology. The films were flexible, having elastic modulus of 1.0–1.5 GPa. Diminishing MB concentration in the aqueous phase was followed as the adsorption process advanced by using visible spectroscopy. Contributions of the individual components of the composites to adsorption were also investigated. Although the MB adsorption capacity was extensively high for silica, it was moderate for the composite, most likely owing to the occlusion of pores of silica by plasticizer to some extent. The improvement of MB adsorption capacity of the composites as the silica ratio increased was explicitly deduced from the optical microscopy photographs. The diffusion coefficients of MB through the composites were 5 × 10^?13, 6 × 10^?13, and 3 × 10^?13 m² s^?1 with regression coefficients of 0.73, 0.89, and 0.88 for 0, 2, and 16% silica‐containing composites, respectively. Because of the slow diffusion of MB in poly(vinyl chloride)‐silica composites, using them as dynamic column adsorbent was not practical. However, these versatile plastics can be used as plastic labels, colored clothing, leather substitutes, antimicrobial medical devices, and laser printable surfaces. J. VINYL ADDIT. TECHNOL., 21:42–50, 2015. © 2014 Society of Plastics Engineers     

Photocurable cyanate ester containing hybrid coatings by an anhydrous sol–gel technique

This work reports the synthesis and characterization of hybrid coatings obtained by UV curable anhydrous sol–gel process. Chemical structure of the products was confirmed using spectroscopic methods such as infrared and nuclear magnetic resonance spectroscopy. The properties of the hybrid coatings such as thermal and mechanical properties were investigated in detail by scanning electron microscope, thermogravimetric analysis, and mechanical measurement. Cure kinetics of the coating formulations was investigated by differential scanning photo-calorimetry (Photo-DSC). Cross cut adhesion, pendulum hardness, gloss, pencil hardness, MEK rub test were also performed to measure the coating performance of the hybrid coatings. The results indicate that the addition of the appropriate amount of CPM and sol–gel can effectively improve the thermal and mechanical properties.     

NATURAL ZEOLITES IN AIR DRYING

ABSTRACT

The local clinoptilolite from Bigadis region in Turkiye, was used for air drying in packed column. The effective diffusion coefficient of water in natural zeolite was found as 5×10^?10 m² s^?1 from isothermal uptake measurements. Effects of packing height and airvelocity on breakthrough curves were studied.