Electrospun MgO/Nylon 6 Hybrid Nanofibers for Protective Clothing

Nano-Micro Letters - Magnesia (MgO) nanoparticles were produced from magnesite ore (MgCO3) using ball mill. The crystalline size, morphology and specific SSA were characterized by X-ray diffraction...     

Analysis of rectangular laminated composite plates via FSDT meshless method

A meshless approach based on the reproducing kernel particle method is developed for the flexural, free vibration and buckling analysis of laminated composite plates. In this approach, the first-order shear deformation theory (FSDT) is employed and the displacement shape functions are constructed using the reproducing kernel approximation satisfying the consistency conditions. The essential boundary conditions are enforced by a singular kernel method. Numerical examples involving various boundary conditions are solved to demonstrate the validity of the proposed method. Comparison of results with the exact and other known solutions in the literature suggests that the meshless approach yields an effective solution method for laminated composite plates.     

Investigation of Mechanical Properties and Dry Sliding Wear Behaviour of Squeeze Cast LM6 Aluminium Alloy Reinforced with Copper Coated Short Steel Fibers

LM6 aluminium alloy with 2.5–10 wt% of copper coated short steel fiber reinforced composites were prepared using squeeze casting process. Microstructure and mechanical properties viz., hardness, tensile strength and ductility were investigated. Dry sliding wear behaviour was tested by considering sliding distance and load. Fracture surface and worn surface were examined using field emission scanning electron microscope (FESEM). Hardness of composites increased with increasing wt% of fiber. Tensile strength of composites increased up to 19% for 5 wt% fiber composites. Further addition of fibers decreased the tensile strength of composites. Ductility of the composites decreased with the addition of fibers into the matrix. Wt% of fibers significantly decreased the weight loss, coefficient of friction and wear rate. Also the cumulative weight loss decreased up to 57% for 10 wt% of composites compared to LM6 aluminium alloy. Fracture surface of composite tensile specimen showed dimple formation and fiber pullout. Worn surface of matrix showed long continuous grooves due to local delamination on the surface. However, worn surface of composites showed fine and smooth grooves due to ploughing rather than local delamination. Copper coated steel fiber reinforcement in LM6 aluminium alloy exhibited better mechanical properties and wear resistance compared to matrix.     

A partition of unity‐based ‘FE–Meshfree’ QUAD4 element for geometric non‐linear analysis

The recently published ‘FE–Meshfree’ QUAD4 element is extended to geometrical non‐linear analysis. The shape functions for this element are obtained by combining meshfree and finite element shape functions. The concept of partition of unity (PU) is employed for the purpose. The new shape functions inherit their higher order completeness properties from the meshfree shape functions and the mesh‐distortion tolerant compatibility properties from the finite element (FE) shape functions. Updated Lagrangian formulation is adopted for the non‐linear solution. Several numerical example problems are solved and the performance of the element is compared with that of the well‐known Q4, QM6 and Q8 elements. The results show that, for regular meshes, the performance of the element is comparable to that of QM6 and Q8 elements, and superior to that of Q4 element. For distorted meshes, the present element has better mesh‐distortion tolerance than Q4, QM6 and Q8 elements. Copyright © 2009 John Wiley & Sons, Ltd.     

Influence of surface modification on the apatite formation and corrosion behavior of Ti and Ti-15Mo alloy for biomedical applications

Commercially pure Ti and Ti-15Mo specimens were subjected to alkali-hydrogen peroxide and subsequent heat treatment to produce a nanoporous titanate gel layer with anatase phase. The surface morphology of the untreated, alkali-hydrogen peroxide treated and alkali-hydrogen peroxide heat treated specimens before and after 7 days of immersion in simulated body fluid was characterized using X-ray Diffractometer (XRD), Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FT-IR). The formation of nanoporous titanate gel layer and the growth of apatite layer over the surface modified specimens after 7 days of immersion in simulated body fluid were confirmed. Further, the electrochemical corrosion behavior of all the specimens was examined using potentiodynamic polarization and electrochemical impedance spectroscopic techniques.     

Determination of the number of containers,production kanbans and withdrawal kanbans; and scheduling in kanban flowshops - Part 1

In the first part of this paper, we consider a kanban-controlled flowshop and present recursive equations for time-tabling of containers in a given sequence. The flowshop is characterized by the following: a production batch of a part-type (or job) divided into kanban lots or containers; production kanbans to control the loading of containers on machines or workstations; withdrawal kanbans to regulate the movement of containers between two consecutive buffer storages; periodic material handling of containers; dual blocking mechanisms operative on workstations and material handling; and sequence-dependent set-up times of containers. Considering different types of problems, recursive equations have been developed for time-tabling of containers in a given sequence.     

CORROSION INHIBITION OF CARBON STEEL IN LOW CHLORIDE MEDIA BY AN AQUEOUS EXTRACT OF HIBISCUS ROSA-SINENSIS LINN

The inhibition efficiency (IE) of an aqueous extract of white flower, namely, Hibiscus rosa-sinensis Linn., in controlling corrosion of carbon steel immersed in an aqueous solution containing 60 ppm of Cl^-has been evaluated by the mass loss method. The flower extract (FE) shows good IE. In the presence of Zn²⁺, excellent IE is shown by the flower extract. A synergistic effect exists between the flower extract and Zn²⁺. The mechanistic aspects of corrosion inhibition have been investigated by polarization study and AC impedance spectra. Polarization study reveals that the formulation consisting of flower extract and Zn²⁺ functions as a mixed inhibitor. AC impedance spectra reveal that a protective film is formed on the metal surface. The active principle in the flower extract is quercetin-3-O-glucoside. This has been confirmed by UV-visible absorption spectra. The protective film formed on the metal surface has been analyzed by FT-IR and AFM spectra. It is found that the protective film consists of Fe²⁺-quercetin-3-O-glucoside complex and Zn(OH)₂.     

Confocal ultrafast pump-probe spectroscopy: a new technique to explore nanoscale composites

This article is devoted to the exploration of the benefits of a new ultrafast confocal pump-probe technique, able to study the photophysics of different structured materials with nanoscale resolution. This tool offers many advantages over standard stationary microscopy techniques because it directly interrogates excited state dynamics in molecules, providing access to both radiative and non-radiative deactivation processes at a local scale. In this paper we present a few different examples of its application to organic semiconductor systems. The first two are focussed on the study of the photophysics of phase-separated polymer blends: (i) a blue-emitting polyfluorene (PFO) in an inert matrix of PMMA and (ii) an electron donor polythiophene (P3HT) mixed with an electron acceptor fullerene derivative (PCBM). The experimental results on these samples demonstrate the capability of the technique to unveil peculiar interfacial dynamics at the border region between phase-segregated domains, which would be otherwise averaged out using conventional pump-probe spectroscopy. The third example is the study of the photophysics of isolated mesoscopic crystals of the PCBM molecule. Our ultrafast microscope could evidence the presence of two distinctive regions within the crystals. In particular, we could pinpoint for the first time areas within the crystals showing photobleaching/stimulated emission signals from a charge-transfer state.