Physico-chemical characterization of hybrid polymers obtained by 2-hydroxyethyl(methacrylate) and alkoxides of zirconium

Hybrid monolithic materials were prepared through polymerisation of 2-hydroxyethyl methacrylate (HEMA) mixed with zirconium alkoxides (Zr(OBuⁿ)₄, Zr(OPrⁿ)₄ and Zr(OEt)₄), modified by acetylacetonate groups. The molar ratio HEMA/Zr varied between 1 and 4. Thermo-Gravimetry coupled with Mass Spectroscopy (TG-MS) analyses, ¹³C MAS NMR and Dynamical Mechanical Thermal Analysys (DMTA) indicated the polymeric chains were interconnected by the inorganic component.The presence of zirconium alkoxides modified substantially the poly-HEMA properties. Glass transition temperature of hybrid materials derived from butoxy and propoxy was found in the range 50-80 °C, depending on the composition. The typical swelling of p-HEMA in the water, was suppressed by the presence of zirconium compounds. After immersion in distilled water, hybrid polymers showed an initial slight weight increase, followed by a small mass loss, which increases proportionally to the length of alkoxyl group (ethoxide(propoxide(butoxide) and reaches a constant value after about 40 days. The hybrids remained always rigid and transparent. Flexural modulus and strength of about 400-900 and 4-8 MPa were measured.     

合成丁苯嵌段共聚物的影响因素

采用负离子溶液聚合方法制备了丁苯嵌段共聚物，研究了引发剂、活化剂、偶合剂、终止剂对聚合产物性能的影响。     

A printer model using signal processing techniques

An accurate printer model that is efficient enough to be used by halftoning algorithms is proposed. The proposed signal processing model (SPM) utilizes a physical model to train adaptive linear combiners (ALCs), after which the average exposure of each subpixel for any input pattern can be calculated using the optimized weight vector. The SPM can be used to model multi-level halftoning and resolution enhancement, as well as traditional halftoning. The SPM is comprised of a single ALC layer followed by a peak-to-average ratio (PAR) correction layer, which serves to produce a PAR of less than 1.5 in the modeled exposure. The PCN (PAR correction network) employs one ALC/pixel and exploits the physics governing the characteristics of exposure in small regions. A relatively small number of training patterns suffices to train the SPM.     

视频流无缝拼接中的帧转换

帧转换在MPEG-2视频流无缝拼接中有着非常重要的作用。文中就压缩域视频流的无缝拼接中的帧转换技术进行了深入的分析。文中以12帧IBBP结构的GOP为例分析了拼接点处应采用的帧转换方案,在此基础上给出帧转换的具体实现,并通过一个帧转换实验对之进行了验证。     

600 A IGBT开关电路及其散热系统设计

采用IGBT开关电路，对大功率电阻带进行直流脉宽调制控制，实现了内燃机车大功率直流发电机负载实验中的负载大小的连续调节。为了避免在实验过程中IGBT器件的温度过高，采用独特的双管IGBT结构和双向强迫风冷的散热系统。实验表明该电路运行稳定、可靠。     

小型月球探测器高精度姿态指向控制

针对小型月球探测器三轴姿态高指向精度和高稳定度的要求 ,采用欧拉动力学和四元数方法描述 ,建立了小型月球探测器环月阶段动力学模型 ,分析了由 3个轻型反作用轮正交安装组成的姿态稳定控制系统 ,给出了一种拟PD姿态指向控制规律。对所设计的指向控制律进行了数学仿真 ,结果表明可达到 0 .0 1°/s的稳定度和 0 .3°的指向精度 ,验证了该控制规律的可行性。     

三江盆地西部藻类地层学特征

本文依据三江盆地西部4口井的藻类分布特征，自下而上划分9个组合，并对各组合的时代及沉积环境进行了探讨。     

利用黄河泥沙加固下游大堤

黄河是一条举世闻名的多泥沙河流，善淤、善决、善徒给沿河人民带来对过深重灾难，防洪问题一直是国家的心腹之患。泥沙问题是黄河防洪问题的症结所在。在总结固大堤经验的基础，进行挖河疏浚，淤筑“相对地下河”，已作为黄河治理的一项重大决策付诸实施。     

PMN-PT陶瓷中的氧缺位及其消除

研究了组成中Pb含量的变化对组成为Pbx(Mg1/3Nb2/3)0.65Ti0.35O3的铌镁酸铅-钛酸铅(PMN-PT)陶瓷压电性能的影响,发现化学计量比组成(x=1)的Pbx(Mg1/3Nb2/3)0.65Ti0.35O3陶瓷经常出现压电性能的大幅度退化现象,而A位适量缺Pb能稳定地获得高性能的Pbx(Mg1/3Nb2/3)0.65Ti0.35O3陶瓷。XPS元素价态分析的结果表明,化学计量比的Pbx(Mg1/3Nb2/3)0.65Ti0.35O3陶瓷中含有较多的氧缺位,氧缺位的产生源于MgNb2O6(MN)合成过程中的气氛差异,A位适量缺Pb能有效地消除这种氧缺位而稳定地获得正常的压电性能,其机理被认为是氧缺位与铅缺位的复合。     

Mechanical Model on Brittle Crack Initiation and Propagation

A mechanical model is presented in this paper to describe the initiating and propagating of brittle cracks. Two criteria have been deduced from the model to determine the effects of such factors as local stress state, surface and grain boundary energies as well as local grain boundary orientation on the initiating and propagating of both intergranular and transgranular brittle cracks. By which the role of adding B in Ni3Al base alloys to improve their ductility,temper and hydrogen embrittlements in steels and other alloys as well as the random feature of brittle crack initiation could be explained