Transient and steady-state analysis of catalyst poisoning and mixed potential formation in direct methanol fuel cells

The present dynamic model is developed to investigate the coupled reaction mechanisms in a DMFC and therein associated voltage losses in the catalyst layers. The model describes a complete five-layer membrane electrode assembly (MEA), with gas diffusion layers, catalyst layers and membrane. The analysis of the performance losses are mainly focused on the electrochemical processes. The model accounts for the crossover of both, methanol from anode to cathode and oxygen from cathode to anode. The reactant crossover results in parasitic internal currents that are finally responsible for high overpotentials in both electrodes, so-called mixed potentials. A simplified and general reaction mechanism for the methanol oxidation reaction (MOR) was selected, that accounts for the coverage of active sites by intermediate species occurring during the MOR. The simulation of the anode potential relaxation after current interruption shows an undershoot behavior like it was measured in the experiment [1]. The model gives an explanation of this phenomenon by the transients of reactant crossover in combination with the change of CO and OH coverages on Pt and Ru, respectively.     

Durability of Brick Lined Steel Ladles from a Mechanical Point of View

The refractory lining in steel ladles is exposed to chemical and mechanical loads during the heats. Mechanical loads develop from the thermal expansion of the refractories which is confined either by the steel construction or by regions of different temperature within the refractory material. The aim of this work was the investigation of factors influencing the mechanical durability of refractory steel ladle linings and the clarification of failure mechanisms. Especially irreversible strains at the hot face of the working lining caused by compressive stresses induce an opening of joints at the hot face. The irreversible strains reduce the compressive stresses in circumferential direction and increase the probability of tensile failure. A further effect of the irreversible strains is a reduced stability of the working lining. Of special interest in this context is a possible controlled expansion of bricks to counterbalance the irreversible compressive strains.     

A new load cell for measuring normal and shear stresses

A special stress measuring device for determining the normal and shear stresses acting on silo walls was developed and tested. The load cell can be used for measuring simultaneously the normal stress as well as the intensity and direction of the shear stress.     

Phase Transformation Modelling and Parameter Identification from Dilatometric Investigations

The goal of this paper is to propose a new approach towards the evaluation of dilatometric results, which are often employed to analyse the phase transformation kinetics in steel, especially in terms of continuous cooling transformation (CCT) diagram. A simple task of dilatometry is deriving the start and end temperatures of the phase transformation. It can yield phase transformation kinetics provided that plenty metallographic investigations are performed, whose analysis is complicated especially in case of several coexisting product phases. The new method is based on the numerical solution of a thermomechanical identification problem. It is expected that the phase transformation kinetics can be derived by this approach with less metallographic tasks. The first results are remarkably promising although further investigations are required for the numerical simulations.     

Biodegradable polymers applied in tissue engineering research: a review

Typical applications and research areas of polymeric biomaterials include tissue replacement, tissue augmentation, tissue support, and drug delivery. In many cases the body needs only the temporary presence of a device/biomaterial, in which instance biodegradable and certain partially biodegradable polymeric materials are better alternatives than biostable ones. Recent treatment concepts based on scaffold‐based tissue engineering principles differ from standard tissue replacement and drug therapies as the engineered tissue aims not only to repair but also regenerate the target tissue. Cells have been cultured outside the body for many years; however, it has only recently become possible for scientists and engineers to grow complex three‐dimensional tissue grafts to meet clinical needs. New generations of scaffolds based on synthetic and natural polymers are being developed and evaluated at a rapid pace, aimed at mimicking the structural characteristics of natural extracellular matrix. This review focuses on scaffolds made of more recently developed synthetic polymers for tissue engineering applications. Currently, the design and fabrication of biodegradable synthetic scaffolds is driven by four material categories: (i) common clinically established polymers, including polyglycolide, polylactides, polycaprolactone; (ii) novel di‐ and tri‐block polymers; (iii) newly synthesized or studied polymeric biomaterials, such as polyorthoester, polyanhydrides, polyhydroxyalkanoate, polypyrroles, poly(ether ester amide)s, elastic shape‐memory polymers; and (iv) biomimetic materials, supramolecular polymers formed by self‐assembly, and matrices presenting distinctive or a variety of biochemical cues. This paper aims to review the latest developments from a scaffold material perspective, mainly pertaining to categories (ii) and (iii) listed above. Copyright © 2006 Society of Chemical Industry     

Die Bewertung von Kreditgarantien mittels Hyperoptionen

Zusammenfassung. Aus finanzwirtschaftlicher Sicht k?nnen Kreditgarantien als Verkaufsoptionen auf das anteilige Gesamtverm?gen einer Unternehmung interpretiert werden. Die Bewertung von Kreditgarantien erfolgt üblicherweise mit dem Ansatz von Merton. Bei diesem Modell wird jedoch unterstellt, da? sowohl für den garantierten Kredit als auch für das nicht garantierte Fremdkapital vor Ablauf der Laufzeit keinerlei Zins– und Tilgungszahlungen geleistet werden. Unsere Arbeit pr?sentiert ein Modell zur Bewertung von Garantien auf Kredite mit beliebigen Zins– und Tilgungsmodalit?ten. Das vorgeschlagene Bewertungsmodell wird auf Kredite mit unterschiedlichen Tilgungsformen angewendet. Darüber hinaus werden Sensitivit?tsanalysen bezüglich der Einflu?faktoren auf die aus dem Modell resultierenden Pr?miens?tze durchgeführt. Eingegangen: 2. Februar 1999 / Angenommen: 9. Dezember 1999     

Pooling for Combination of Multilevel Forecasts

In this paper, we provide a theoretical analysis of effects of applying different forecast diversification methods on the structure of the forecast error covariance matrices and decomposed forecast error components based on the bias-variance-Bayes error decomposition of James and Hastie. We express the "diversity” of different forecasts in relation to different error components and propose a measure in order to quantify it. We illustrate and discuss typical inhomogeneities frequently occurring in the forecast error covariance matrices and show that previously proposed pooling based only on error variances cannot fully exploit the complementary information present in a set of diverse forecasts to be combined. If covariance values could be reliably calculated, they could be taken into account during the pooling process. We study the difficult case in which covariance information cannot be measured properly and propose a novel simplified representation of the covariance matrix, which is only based on knowledge about the forecast generation process. Finally, we propose a new pooling approach that avoids inhomogeneities in the forecast error covariance matrix by considering the information contained in the simplified covariance representation and compare it with the error-variance-based pooling approach introduced by Aiolfi and Timmermann. Applying our approach more than once leads to the generation of multistep and multilevel forecast combination structures, which have generated significantly improved forecasts in our previous extensive experimental work; the summary of which is also provided.