Virtual Organizations in Arigatoni

Arigatoni is a lightweight overlay network that deploys the Global Computing Paradigm over the Internet. Communication for over the behavioral units of the overlay is performed by a simple resource discovery protocol (RDP). Basic Global Computers Units (GC) can communicate by first registering to a brokering service and then by mutually asking and offering services.Colonies and communities are the main entities in the model. A colony is a simple virtual organization composed by exactly one leader and some set (possibly empty) of individuals. A community is a raw set of colonies and global computers (think it as a soup of colonies and global computer without a leader).We present an operational semantics via a labeled transition system, that describes the main operations necessary in the Arigatoni model to perform leader negotiation, joining/leaving a colony, linking two colonies and moving one GC from one colony to another. Our formalization results to be adequate w.r.t. the algorithm performing peer logging/delogging and colony aggregation.     

Cooperative energy management in distributed wireless real-time systems

This work is based on the observation that existing energy management techniques for mobile devices, such as Dynamic Voltage Scaling (DVS), are non-cooperative in the sense that they reduce the energy consumption of a single device, disregarding potential consequences for other constraints (e.g., end-to-end deadlines) and/or other devices (e.g., energy consumption on neighboring devices). This paper argues that energy management in distributed wireless real-time systems has to be end-to-end in nature, requiring a coordinated approach among communicating devices. A cooperative distributed energy management technique (Co-DVS) is proposed that (1) adapts and maintains end-to-end latencies within specified timeliness requirements (deadlines) and (2) enhances energy savings at the devices with the highest pay-off factors that represent the relative benefits or significance of conserving energy at a device. The proposed technique employs a feedback-based approach to dynamically distribute end-to-end slack among the devices based on their pay-off factors.     

A sub-space method to detect multiple wireless microphone signals in TV band white space

The main hurdle in the realization of dynamic spectrum access systems from the physical layer perspective is the reliable sensing of low power licensed users. One such scenario shows up in the unlicensed use of the TV bands where the TV band devices are required to sense extremely low power wireless microphones (WMs). The lack of technical standards among various wireless manufacturers and the resemblance of certain WM signals to narrow-band interference signals, such as spurious emissions, further aggravate the problem. Due to these uncertainties, it is extremely difficult to abstract the features of WM signals and hence develop robust sensing algorithms. To partly counter these challenges, we develop a two-stage sub-space algorithm that detects multiple narrow-band analog frequency-modulated signals generated by WMs. The performance of the algorithm is verified by using the real WM signals experimentally captured under low SNR conditions. The problem of differentiating between the WM and other narrow-band signals is left as future work.     

On the Effect of Birefringence on Light Transmission in Polycrystalline Magnesium Fluoride

Light transmission in polycrystalline magnesium fluoride was studied as a function of the mean grain size at different wavelengths. The mean grain size was varied by annealing hot‐pressed billets in argon atmosphere at temperatures ranging from 600°C to 800°C for 1 h. The grain‐size and grain‐orientation distributions were characterized by electron back scatter diffraction. The scattering coefficients were calculated from the in‐line transmittance measured at various wavelengths. The scattering coefficient of polycrystalline magnesium fluoride increased linearly with the mean grain size and inversely with the square of the wavelength of light. It is shown that these trends are consistent with theoretical models based on both a limiting form of the Raleigh–Gans–Debye (RGD) theory of particle scattering and light retardation theories that take refractive index variations along the light path. Quantitative predictions of the theories are, however, subject to uncertainly due to the restrictive assumptions made in the theories and difficulties in representing the microstructure in the theoretical models. In particular, grain‐size distribution has a significant influence on the scattering coefficient calculated using particle scattering models.     

A socio-ecological analysis of hospital resilience to extreme weather events

Hospitals play a critical role in helping communities respond effectively to extreme weather events (EWEs). Despite predictions of more EWEs, little is known about the process by which hospital infrastructure resilience to such events can be built. Using Gunderson and Holling’s Adaptive Cycle, a new theoretical perspective based on socio-ecological resilience theory is provided to understand this process. Data were collected using semi-structured interviews, observations of disaster drills and disaster planning meetings, as well as additional documentary analysis of past incident reports. The research findings were then refined and validated in a focus group meeting with respondents. The findings indicate that there are significant organizational barriers which prevent facilities managers improving the resilience of hospital facilities to future EWEs. It was found that the disaster planning process is ad hoc and non-inclusive, focused on man-made disasters and compliance driven, top-down approach, under-resourced and is driven by a general ignorance of the importance of resilient-built facilities to health care delivery during an EWE. It is concluded that to produce more resilient hospital infrastructure, there needs to be a more well-resourced, integrated and collaborative approach to disaster management planning which enables health facilities managers to play a more central role in disaster planning decisions. There also need to be better systems, technologies and training implemented to manage information about health infrastructure performance before, during and after EWEs.     

Vapor Phase Selective Catalytic Oxidation of Cyclohexane over 13X Supported Metal Oxides in the Presence of Ozone

This article reports the application of ozone for the selective oxidation of cyclohexane over 13X molecular sieve supported various metal oxides at ambient temperatures. From the SEM, XRD and HR-TEM results, the impregnated metal oxides are highly dispersed on the support. The activity results reveal that Co/MS, Mo/MS, Cu/MS, and Ag/MS catalysts produce cyclohexanone/cyclohexanol as selective oxidation products, whereas Ce/MS, Mn/MS, and V/MS catalysts yield, predominantly, CO and CO₂. Among them, Co/MS catalyst exhibits better conversion of 12.2% with selectively of 58% to cyclohexanone/cyclohexanol, which is attributed to the simultaneous activation of ozone and cyclohexane (-C-H bond) at ambient conditions.     

An Assessment of the Applicability of Particle Light Scattering Theories to Birefringent Polycrystalline Ceramics

The applicability of particle light scattering theories to light attenuation in birefringent polycrystalline ceramics was investigated by measuring light transmittance in a model two‐phase system. The system consisted of microspheres of silica dispersed in a solution of glycerol in water. The composition of the liquid medium was chosen to produce a mismatch between the refractive index of the particles (n_p) and of the medium (n_m) equal to the root mean square of the refractive index variation in polycrystalline magnesium fluoride. The variations of the scattering coefficients (γ) with volume fraction of silica microspheres for three different particle diameters (0.5, 1.0 and 1.5 μm) were compared with theoretical predictions based on scattering efficiency of single particles (K) and linear extrapolation to multiparticle dispersed systems. The measured scattering coefficients were significantly greater than the theoretical values for particle volume fractions greater than 0.2. These results suggest that application of particle scattering theories to a birefringent polycrystalline ceramic, an intrinsically high volume fraction system, is tenuous at best.     

A Functionally Graded Carbide in the Ta–C System

Hard materials used in such abrasive wear applications as cutting tools and wear inserts in drilling tools require high hardness to resist wear, high fracture toughness to withstand mechanical and thermal shock, and high chemical and thermal stability. Such a combination of properties is difficult to achieve in single‐phase materials. Functional grading is an approach that overcomes this limitation by designing and processing a graded microstructure that provides high hardness and chemical resistance at the surface with a tough interior or bulk. While functional grading is a widely used practice in the cemented carbides industry, it has not been demonstrated with “pure” carbides. This article reports the feasibility of designing and processing a graded carbide in the Ta–C binary system. It is shown that a simple carburization treatment of the high‐toughness carbide, ζ‐Ta₄C_3?x, can lead to the formation of the hard carbide phase, γ‐TaC_y, on the surface. The thickness, microstructure (grain size), and composition (C/Ta atomic ratio, y) of the γ‐TaC_y layer can be optimized to obtain both high hardness and high strength for the graded material.     

Analysis of Polycyclic Aromatic Hydrocarbon,Toxic Equivalency Factor and Related Carcinogenic Potencies in Roadside Soil within a Developing City of Northern India

Preliminary analysis was performed to assess contamination levels in roadside soils, distribution behavior and human exposure with Polycyclic Aromatic Hydrocarbons (PAHs) during summer, winter, rainy, and autumn during 2013 in one of the developing cities of northern India. The concentration of PAHs was measured at ten different locations (at 1, 2, and 3 m) from roadside soil. Recovery range was 30% and 80% with lower value corresponding to the lower molecular weight PAHs compound. Identification and quantification of PAHs was done by GC-FID. Average PAHs concentration (city average) was found to be 16.53, 4.04, 17.49, and 7.82 μg g^?1, during summer, winter, autumn, and the rainy seasons, respectively. Average concentration of low and high carcinogenic PAHs during summer, winter, autumn, and rainy was 5.1 and 31.29, 2.1 and 6.4, 4.74 and 35.08, 3.97 and 12.77μg g^?1_, respectively. The average ratio of low and high carcinogenic PAHs was found to be 1:6, 1:3, 1:7.6, and 1:3.21 during summer, winter, autumn, and the rainy seasons at most intercepts. Dib(ah)A and B(a)P were the two individual PAHs found in highest concentration during summer, winter, and the rainy seasons, whereas B(a)P and IP were individual PAHs found in highest concentration during autumn. It was also analyzed that high carcinogenic PAHs concentration was quite higher (around 85%) in comparison to low carcinogenic PAHs (around 15%) at most intercepts. This article also deals with the behavior of PAHs at places of average/high population and traffic density intercepts. Five-ringed PAHs were in highest concentration at all intercepts and seasons. Two-tailed T test was applied for authenticity of the data and results. Toxic equivalency factor of B(a)P and Dib(ah)A was maximum as compared to other PAHs.     

Minocycline Loaded Hybrid Composites Nanoparticles for Mesenchymal Stem Cells Differentiation into Osteogenesis

Bone transplants are used to treat fractures and increase new tissue development in bone tissue engineering. Grafting of massive implantations showing slow curing rate and results in cell death for poor vascularization. The potentials of biocomposite scaffolds to mimic extracellular matrix (ECM) and including new biomaterials could produce a better substitute for new bone tissue formation. A purpose of this study is to analyze polycaprolactone/silk fibroin/hyaluronic acid/minocycline hydrochloride (PCL/SF/HA/MH) nanoparticles initiate human mesenchymal stem cells (MSCs) proliferation and differentiation into osteogenesis. Electrospraying technique was used to develop PCL, PCL/SF, PCL/SF/HA and PCL/SF/HA/MH hybrid biocomposite nanoparticles and characterization was analyzed by field emission scanning electron microscope (FESEM), contact angle and Fourier transform infrared spectroscopy (FT-IR). The obtained results proved that the particle diameter and water contact angle obtained around 0.54 ± 0.12 to 3.2 ± 0.18 µm and 43.93 ± 10.8° to 133.1 ± 12.4° respectively. The cell proliferation and cell-nanoparticle interactions analyzed using (3-(4,5-dimethyl thiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium inner salt) MTS assay (Promega, Madison, WI, USA), FESEM for cell morphology and 5-Chloromethylfluorescein diacetate (CMFDA) dye for imaging live cells. Osteogenic differentiation was proved by expression of osteocalcin, alkaline phosphatase activity (ALP) and mineralization was confirmed by using alizarin red (ARS). The quantity of cells was considerably increased in PCL/SF/HA/MH nanoparticles when compare to all other biocomposite nanoparticles and the cell interaction was observed more on PCL/SF/HA/MH nanoparticles. The electrosprayed PCL/SF/HA/MH biocomposite nanoparticle significantly initiated increased cell proliferation, osteogenic differentiation and mineralization, which provide huge potential for bone tissue engineering.