Where Everybody Knows Your (Screen) Name: Online Games as "Third Places"

This article examines the form and function of massively multiplayer online games (MMOs) in terms of social engagement. Combining conclusions from media effects research informed by the communication effects literature with those from ethnographic research informed by a sociocultural perspective on cognition and learning, we present a shared theoretical framework for understanding (a) the extent to which such virtual worlds are structurally similar to "third places" ( Oldenburg, 1999 ) for informal sociability, and (b) their potential function in terms of social capital ( Coleman, 1988; Putnam, 2000 ). Our conclusion is that by providing spaces for social interaction and relationships beyond the workplace and home, MMOs have the capacity to function as one form of a new "third place" for informal sociability. Participation in such virtual "third places" appears particularly well suited to the formation of bridging social capital—social relationships that, while not usually providing deep emotional support, typically function to expose the individual to a diversity of worldviews.     

Recent Progress of In Situ Transmission Electron Microscopy for Energy Materials

In situ transmission electron microscopy (TEM) is one of the most powerful approaches for revealing physical and chemical process dynamics at atomic resolutions. The most recent developments for in situ TEM techniques are summarized; in particular, how they enable visualization of various events, measure properties, and solve problems in the field of energy by revealing detailed mechanisms at the nanoscale. Related applications include rechargeable batteries such as Li-ion, Na-ion, Li–O₂, Na–O₂, Li–S, etc., fuel cells, thermoelectrics, photovoltaics, and photocatalysis. To promote various applications, the methods of introducing the in situ stimuli of heating, cooling, electrical biasing, light illumination, and liquid and gas environments are discussed. The progress of recent in situ TEM in energy applications should inspire future research on new energy materials in diverse energy-related areas.     

Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates

Formic acid and formates are often produced by hydrogenation of CO₂ with hydrogen over homogeneous catalysts. The present review reports recent achievements in utilization of heterogeneous catalysts. It shows that highly dispersed supported metal catalysts are able to carry out this reaction by providing activation of hydrogen on the metal sites and activation of CO₂ or bicarbonate on the support sites. Important advances have recently been achieved through utilization of catalysts using C_xN_y materials as supports. The high activity of these catalysts could be assigned to their ability to stabilize the active metal in a state of single-metal atoms or heterogenized metal complexes, which may demonstrate a higher activity than metal atoms on the surface of metal nanoparticles.     

Seeded growth of highly luminescent CdSe/CdS nanoheterostructures with rod and tetrapod morphologies

We have demonstrated that seeded growth of nanocrystals offers a convenient way to design nanoheterostructures with complex shapes and morphologies by changing the crystalline structure of the seed. By using CdSe nanocrystals with wurtzite and zinc blende structure as seeds for growth of CdS nanorods, we synthesized CdSe/CdS heterostructure nanorods and nanotetrapods, respectively. Both of these structures showed excellent luminescent properties, combining high photoluminescence efficiency (approximately 80 and approximately 50% for nanorods and nanotetrapods, correspondingly), giant extinction coefficients (approximately 2 x 10(7) and approximately 1.5 x 10(8) M(-1) cm(-1) at 350 nm for nanorods and nanotetrapods, correspondingly), and efficient energy transfer from the CdS arms into the emitting CdSe core.     

Stability of nanocrystallites dispersed in Cu50Zr45Ti5 metallic glass under electron irradiation

Effect of electron irradiation on stability of nanocrystallites dispersed in a glassy matrix of a Cu50Zr45Ti5 bulk metallic glass (BMG) alloy was investigated. Microstructural evolution during electron irradiation was observed and analyzed by means of conventional and high-resolution transmission electron microscopy (CTEM and HRTEM) and X-ray energy dispersive spectroscopy (EDS). The crystalline nanoparticles of monoclinic CuZr phase formed in-situ in as-cast Cu50Zr45Ti5 alloy exhibited a high stability against electron irradiation. No obvious changes in their size, morphology, and crystal structure were observed during electron irradiation, though new crystalline nanoparticles nucleated and precipitated in the glassy matrix under electron irradiation. The new nanoparticles formed upon irradiation have a similar composition and crystal structure to those formed in-situ in the as-cast alloy. The nanocrystalline precipitates in the glassy matrix are proposed to be mainly due to electron knock-on effect under electron irradiation, which promotes atomic diffusion and assists the crystallization of the glassy phase. The present result indicates that electron irradiation to metallic glasses has potential for producing nanocrystalline structure and nanocrystalline-glassy composite structure.     

Deformation-driven electrical transport of individual boron nitride nanotubes

In contrast to standard metallic or semiconducting graphitic carbon nanotubes, for years their structural analogs, boron nitride nanotubes, in which alternating boron and nitrogen atoms substitute for carbon atoms in a graphitic network, have been considered to be truly electrically insulating due to a wide band gap of layered BN. Alternatively, here, we show that under in situ elastic bending deformation at room temperature inside a 300 kV high-resolution transmission electron microscope, a normally electrically insulating multiwalled BN nanotube may surprisingly transform to a semiconductor. The semiconducting parameters of bent multiwalled BN nanotubes squeezed between two approaching gold contacts inside the pole piece of the microscope have been retrieved based on the experimentally recorded I-V curves. In addition, the first experimental signs suggestive of piezoelectric behavior in deformed BN nanotubes have been observed.     

Defect-tolerant architectures for nanoelectronic crossbar memories

We have calculated the maximum useful bit density that may be achieved by the synergy of bad bit exclusion and advanced (BCH) error correcting codes in prospective crossbar nanoelectronic memories, as a function of defective memory cell fraction. While our calculations are based on a particular ("CMOL") memory topology, with naturally segmented nanowires and an area-distributed nano/CMOS interface, for realistic parameters our results are also applicable to "global" crossbar memories with peripheral interfaces. The results indicate that the crossbar memories with a nano/CMOS pitch ratio close to 1/3 (which is typical for the current, initial stage of the nanoelectronics development) may overcome purely semiconductor memories in useful bit density if the fraction of nanodevice defects (stuck-on-faults) is below approximately 15%, even under rather tough, 30 ns upper bound on the total access time. Moreover, as the technology matures, and the pitch ratio approaches an order of magnitude, the crossbar memories may be far superior to the densest semiconductor memories by providing, e.g., a 1 Tbit/cm2 density even for a plausible defect fraction of 2%. These highly encouraging results are much better than those reported in literature earlier, including our own early work, mostly due to more advanced error correcting codes.