Super‐Resolution Nonlinear Photothermal Microscopy

Super‐resolution fluorescence microscopy enables imaging of fluorescent structures beyond the diffraction limit. However, this technique cannot be applied to weakly fluorescent cellular components or labels. As an alternative, photothermal microscopy based on nonradiative transformation of absorbed energy into heat has demonstrated imaging of nonfluorescent structures including single molecules and ~1‐nm gold nanoparticles. However, previously photothermal imaging has been performed with a diffraction‐limited resolution only. Herein, super‐resolution, far‐field photothermal microscopy based on nonlinear signal dependence on the laser energy is introduced. Among various nonlinear phenomena, including absorption saturation, multiphoton absorption, and signal temperature dependence, signal amplification by laser‐induced nanobubbles around overheated nano‐objects is explored. A Gaussian laser beam profile is used to demonstrate the image spatial sharpening for calibrated 260‐nm metal strips, resolving of a plasmonic nanoassembly, visualization of 10‐nm gold nanoparticles in graphene, and hemoglobin nanoclusters in live erythrocytes with resolution down to 50 nm. These nonlinear phenomena can be used for 3D imaging with improved lateral and axial resolution in most photothermal methods, including photoacoustic microscopy.     

Magnetic orientation of garden warblers (Sylvia borin) under 1.4 MHz radiofrequency magnetic field

We report on the experiments on orientation of a migratory songbird, the garden warbler (Sylvia borin), during the autumn migration period on the Courish Spit, Eastern Baltics. Birds in experimental cages, deprived of visual information, showed the seasonally appropriate direction of intended flight with respect to the magnetic meridian. Weak radiofrequency (RF) magnetic field (190 nT at 1.4 MHz) disrupted this orientation ability. These results may be considered as an independent replication of earlier experiments, performed by the group of R. and W. Wiltschko with European robins (Erithacus rubecula). Confirmed outstanding sensitivity of the birds'' magnetic compass to RF fields in the lower megahertz range demands for a revision of one of the mainstream theories of magnetoreception, the radical-pair model of birds'' magnetic compass.     

System fault-tolerance analysis of COTS-based satellite on-board computers

Fault-tolerance analysis reveals possible system behavior under the influence of faults. Such analysis is essential for satellites where faults might be caused by space radiation and autonomous recovery is needed. In this paper we present a statistical simulation approach for fault-tolerance analysis of satellite On-Board Computers (OBCs) that are based on Commercial Off-The-Shelf (COTS) components. Since the logic level of COTS electronics is unknown to satellite designers, a new higher-level fault-tolerance analysis is required. We propose such technique that relies on OBC modeling and fault modeling, based on the modeling principle of Single-Event Upsets (SEUs). For the first time we can compare the efficiency of fault-tolerance techniques implemented in software and Field-Programmable Gate Array (FPGA). In addition, our approach enables to analyze system fault-tolerance at early development stages. In a case study the approach is applied to an OBC with a Microsemi SmartFusion SoC, that executes a satellite attitude control algorithm. The gained statistical simulation results enabled 50% reduction in the hardware overhead of the implemented memory scrubbing technique without loss in fault-tolerance. Our method revealed critical fault-tolerance drawbacks of the initial system design that could have lead to satellite mission failure.     

Integration of Production Steps on a Single Equipment

The article describes a new method for integrated processing which combines high-energy heating by high frequency currents (HEH HFC) and abrasive grinding. Research clearly showed that implementation of integrated processing may lead to 2 … 2.5-fold increasing of the processing performance. It was established experimentally that the proposed integrated treatment results in increasing of the microhardness and the level of residual compressive stresses in the surface layer. This increases the contact–fatigue strength of steel parts up to 10% … 16%.     

Degradation of organic solar cells due to air exposure

We present a study of dark air-exposure degradation of organic solar cells based on photoactive blends of the conjugated polymer, poly[2-methoxy-5-(3′,7′-dimethyloctyloxy)-1,4-phenylene vinylene] (MDMO-PPV) with [6,6]-phenyl C₆₁-butyric acid methyl ester (PCBM). Photovoltaic devices were fabricated on indium tin oxide (ITO) glass with or without a layer of poly (3,4-ethylenedioxythiophene):poly(4-styrene sulfonate) (PEDOT:PSS), and were studied without encapsulation. Photovoltaic performance characteristics were measured as a function of time for different ambient conditions (under white light irradiation and in the dark, and under air, dry oxygen and humid nitrogen atmospheres). It was found that a key cause of degradation under air exposure is light independent and results from water adsorption by the hygroscopic PEDOT:PSS layer. Measurements of the charge mobility and hole injection after air exposure showed that the degradation increases the resistance of the PEDOT:PSS/blend layer interface.     

Microfluidic push-pull probe for scanning electrochemical microscopy

This paper presents a microfluidic push-pull probe for scanning electrochemical microscopy (SECM) consisting of a working microelectrode, an integrated counter/reference electrode and two microchannels for pushing and pulling an electrolyte solution to and away from a substrate. With such a configuration, a droplet of a permanently renewed redox mediator solution is maintained just at the probe tip to carry out SECM measurements on initially dry substrates or in microenvironments. For SECM imaging purposes, the probe fabricated in a soft polymer material is used in a contact regime. SECM images of various gold-on-glass samples demonstrate the proof-of-concept of a push-pull probe for local surface activity characterization with high spatial resolution even on vertically oriented substrates. Finite element computations were performed to guide the improvement of the probe sensitivity.     

d-Lactose oxidation over gold catalysts

Various supported gold catalysts were utilized in aerobic lactose oxidation. Comparison between these catalysts revealed, that gold catalysts are sensitive to the type of support. Kinetic regularities, e.g. dependence on pH, temperature and oxygen feed rate were established. Gold catalysts were selective for the production of the first reaction product, sodium salt of lactobionic acid. The electrochemical catalyst potential response was measured “in situ” and then utilized in the reaction process characterization.     

Liquid-phase hydrogenation of diethylbenzenes

Hydrogenation of diethylbenzenes in the liquid phase was studied at 358–418 K and 2–6 MPa over 16.7% Ni/Al₂O₃. The reactivity of diethylbenzene isomers was dependent on the mutual position of the substituents and decreased in the following order: 1,3- > 1,4- > 1,2-. The apparent activation energies were ca. 60 kJ/mol. The cis-to-trans ratio of the corresponding saturated products exhibited only a weak dependence on temperature and hydrogen pressure.     

Toughness-dominated Hydraulic Fracture with Leak-off

This paper considers the problem of a hydraulic fracture in which an incompressible Newtonian fluid is injected at a constant rate to drive a fracture in a permeable, infinite, brittle elastic solid. The two cases of a plane strain and a penny-shaped fracture are considered. The fluid pressure is assumed to be uniform and thus the lag between the fracture front and the fluid is taken to be zero. The validity of these assumptions is shown to depend on a parameter, which has the physical interpretation of a dimensionless fluid viscosity. It is shown that when the dimensionless viscosity is negligibly small, the problem depends only on a single parameter, a dimensionless time. Small and large time asymptotic solutions are derived which correspond to regimes dominated by storage of fluid in the fracture and infiltration of fluid into the rock, respectively. Evolution from the small to the large time asymptotic solution is obtained using a fourth order Runge–Kutta method.     

X-ray topography analysis of acoustic wave fields in the SAW-resonator structures

The formation of fields of standing surface acoustic waves (SAW) in LiNbO3 and La3Ga5SiO14 (LGS) crystals was studied by high-resolution topography method on a laboratory X-ray source. The fields of standing SAW were formed using SAW-resonator structures consisting of interdigital transducer (IDT) and reflecting gratings. The SAW amplitudes and power flow angles were measured by X-ray topography, diffraction in acoustic beam was visualized, and the SAW interaction with the crystal structure defects was studied.