Use of Corundum Ceramics for Fine Milling of Various Materials

The wear resistance of corundum milling bodies developed by the authors is estimated compared to foreign analogs. It is established that domestic ceramics, with respect to its abrasion rate in milling electrocorundum and quartz sand, is not inferior to foreign ceramics. The kinetics of milling the specified materials is analyzed.__________Translated from Steklo i Keramika, No. 1, pp. 17 – 18, January, 2005.     

Generalized Transfer Subspace Learning Through Low-Rank Constraint

It is expensive to obtain labeled real-world visual data for use in training of supervised algorithms. Therefore, it is valuable to leverage existing databases of labeled data. However, the data in the source databases is often obtained under conditions that differ from those in the new task. Transfer learning provides techniques for transferring learned knowledge from a source domain to a target domain by finding a mapping between them. In this paper, we discuss a method for projecting both source and target data to a generalized subspace where each target sample can be represented by some combination of source samples. By employing a low-rank constraint during this transfer, the structure of source and target domains are preserved. This approach has three benefits. First, good alignment between the domains is ensured through the use of only relevant data in some subspace of the source domain in reconstructing the data in the target domain. Second, the discriminative power of the source domain is naturally passed on to the target domain. Third, noisy information will be filtered out during knowledge transfer. Extensive experiments on synthetic data, and important computer vision problems such as face recognition application and visual domain adaptation for object recognition demonstrate the superiority of the proposed approach over the existing, well-established methods.     

Harnessing the Melting Peculiarities of Ultra‐High Molecular Weight Polyethylene Fibers for the Processing of Compacted Fiber Composites

Summary: Compacted fiber composites offer unique properties due to their lack of an extraneous matrix. The conditions of processing ultra‐high molecular weight polyethylene (UHMWPE) fibers were simulated in a heated pressure cell. In situ X‐ray diffraction measurements were used to follow the relevant transitions and the changes in the degree of crystallinity during melting and crystallization. The results strongly support the suggestion that the hexagonal crystal phase, in which the chain conformation is extremely mobile on the segmental level, constitutes the physical basis of compaction technologies for processing UHMWPE fibers into a single‐polymer composite. This report suggests that using a pseudo‐phase diagram outlining the occurrence of different phases during slow heating and the degree of crystallinity can provide valuable insight into the technological parameters relevant for optimal processing conditions.

Degree of crystallinity as a function of pressure and temperature in a region relevant to compaction processes.     

Development of New Generation Ceramics for Their Potential Use in Domestic Industries

A brief survey of four groups of ceramic materials with a potential for effective use in science and technology is given. Durable ceramics based on Al₂O₃ and ZrO₂ are considered and areas of application are outlined. Corundum ceramics using eutectic additives that allow the sintering to be conducted at lower temperatures are discussed; structural features and properties of new materials and areas of application are considered. The use of porous ceramic materials for filtering cells and catalyst carriers is discussed. Bioceramics with a dense and porous structure based on hydroxyapatite that find ever-increasing interest for use in medicine are considered.     

Hydrogenation of Citral Over a Polymer Fibre Catalyst

A polymer-supported Pd catalyst was investigated in hydrogenation of citral (3,7-dimethyl-2,6-octadienal), which is a stereoisomer with an isolated and a conjugated double bond as well as a carbonyl group. The catalyst was a fibrous polymer-supported catalyst modified with functional groups and immobilized metals. A comparison of the polymer-supported catalyst with conventional catalysts was made.     

Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates.

Graphical Abstract