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941.
942.
Ja Young Park Mi Ae Kim Seung Jae Lee Jongjin Jung Hye Mi Jang Pravin P. Upare Young Kyu Hwang Jong-San Chang Joung Kyu Park 《Journal of Materials Science》2015,50(1):334-343
This study describes the synthesis of carbon-encapsulated iron nanoparticles using an ultrasonic method and also investigates their catalytic activity. These nanoparticles have been prepared using ultrasonic irradiation followed by annealing at various temperatures. As the annealing temperature of as-prepared α-Fe2O3 nanoparticles increased, the sample transformed into γ-Fe2O3, Fe3O4, and Fe nanoparticles via the reduction process without requiring any additional reducing agents such as H2 gas, thus, creating a carbon shell surrounding the nanoparticles. By controlling the experimental conditions, Fe nanoparticles of various sizes can be formed with diameters in the range 100–800 nm; these nanoparticles are tightly encapsulated by 20-nm-thick carbon shells. Because of their high saturation magnetization 212 emu g?1, the carbon-encapsulated Fe nanoparticles can be used for magnetic resonance imaging with a dramatically enhanced efficiency compared to commercially available T 2 contrast agents. Moreover, the carbon-encapsulated Fe nanoparticles showed its superior catalytic activity and reusability for the hydrogenation of biomass-derived levulinic acid to GVL (99.6 %) in liquid phase. 相似文献
943.
944.
945.
946.
Transient Electronics: Thermally Triggered Degradation of Transient Electronic Devices (Adv. Mater. 25/2015)
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947.
DNA/Tannic Acid Hybrid Gel Exhibiting Biodegradability,Extensibility, Tissue Adhesiveness,and Hemostatic Ability
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Mikyung Shin Ji Hyun Ryu Joseph P. Park Keumyeon Kim Jae Wook Yang Haeshin Lee 《Advanced functional materials》2015,25(8):1270-1278
DNA has emerged as a novel material in many areas of materials science due to its programmability. Especially, DNA hydrogels have been studied to incorporate new functions into gels. To date, only a few methods have been developed for fabricating DNA hydrogels, such as the use of complementary sequences or covalent bond. Herein, it is demonstrated that one of the most well‐known plant‐derived polyphenols, tannic acid (TA), can form a DNA hydrogel which is named TNA hydrogel ( T A + D NA ). TA plays a role as a “molecular glue” by a new mode of action reversibly connecting between phosphodiester bonds, which is different from the crosslinking utilizing complementary sequences. TA intrinsically degrades due to ester bonds connecting between pyrogallol groups, causing a degradable DNA hydrogel. Furthermore, TNA gel is multifunctional in that the gel is extensible upon pulling and adhesive to tissues because of the rich polyphenol groups in TA (ten phenols per TA). Unexpectedly, TNA gel exhibits superior in vivo hemostatic ability that can be useful for biomedical applications. This new DNA hydrogel preparation method represents a new technique for fabricating a large amount of DNA‐based hemostatic hydrogel without chemically modifying DNA or requiring the crosslinking by complementary sequences. 相似文献
948.
Yu Ra Jeong Heun Park Sang Woo Jin Soo Yeong Hong Sang‐Soo Lee Jeong Sook Ha 《Advanced functional materials》2015,25(27):4228-4236
Stretchable electronics have recently been extensively investigated for the development of highly advanced human‐interactive devices. Here, a highly stretchable and sensitive strain sensor is fabricated based on the composite of fragmentized graphene foam (FGF) and polydimethylsiloxane (PDMS). A graphene foam (GF) is disintegrated into 200–300 μm sized fragments while maintaining its 3D structure by using a vortex mixer, forming a percolation network of the FGFs. The strain sensor shows high sensitivity with a gauge factor of 15 to 29, which is much higher compared to the GF/PDMS strain sensor with a gauge factor of 2.2. It is attributed to the great change in the contact resistance between FGFs over the large contact area, when stretched. In addition to the high sensitivity, the FGF/PDMS strain sensor exhibits high stretchability over 70% and high durability over 10 000 stretching‐releasing cycles. When the sensor is attached to the human body, it functions as a health‐monitoring device by detecting various human motions such as the bending of elbows and fingers in addition to the pulse of radial artery. Finally, by using the FGF, PDMS, and μ‐LEDs, a stretchable touch sensor array is fabricated, thus demonstrating its potential application as an artificial skin. 相似文献
949.
High‐Performance Transition Metal Dichalcogenide Photodetectors Enhanced by Self‐Assembled Monolayer Doping
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Dong‐Ho Kang Myung‐Soo Kim Jaewoo Shim Jeaho Jeon Hyung‐Youl Park Woo‐Shik Jung Hyun‐Yong Yu Chang‐Hyun Pang Sungjoo Lee Jin‐Hong Park 《Advanced functional materials》2015,25(27):4219-4227
Most doping research into transition metal dichalcogenides (TMDs) has been mainly focused on the improvement of electronic device performance. Here, the effect of self‐assembled monolayer (SAM)‐based doping on the performance of WSe2‐ and MoS2‐based transistors and photodetectors is investigated. The achieved doping concentrations are ≈1.4 × 1011 for octadecyltrichlorosilane (OTS) p‐doping and ≈1011 for aminopropyltriethoxysilane (APTES) n‐doping (nondegenerate). Using this SAM doping technique, the field‐effect mobility is increased from 32.58 to 168.9 cm2 V?1 s in OTS/WSe2 transistors and from 28.75 to 142.2 cm2 V?1 s in APTES/MoS2 transistors. For the photodetectors, the responsivity is improved by a factor of ≈28.2 (from 517.2 to 1.45 × 104 A W?1) in the OTS/WSe2 devices and by a factor of ≈26.4 (from 219 to 5.75 × 103 A W?1) in the APTES/MoS2 devices. The enhanced photoresponsivity values are much higher than that of the previously reported TMD photodetectors. The detectivity enhancement is ≈26.6‐fold in the OTS/WSe2 devices and ≈24.5‐fold in the APTES/MoS2 devices and is caused by the increased photocurrent and maintained dark current after doping. The optoelectronic performance is also investigated with different optical powers and the air‐exposure times. This doping study performed on TMD devices will play a significant role for optimizing the performance of future TMD‐based electronic/optoelectronic applications. 相似文献
950.
Kim JeongJu Sohn Ho-Seong Park Hee Seung Hsu Wei-Ting Ueda Osamnu Cho Hyung Hee 《Journal of Mechanical Science and Technology》2021,35(10):4575-4583
Journal of Mechanical Science and Technology - Recently, domestic gas turbines are primarily operated under partial loads. Hence, thermal expansion of components decreases, leading to a... 相似文献