Variation of poly(vinylidene fluoride) morphology due to radial cold flow in a flexible pipe

A subsea flexible pipe containing isotropic poly(vinylidene fluoride) (PVDF) layers is subjected to rapid decompression after being put in pressurized equilibrium with a fluid containing supercritical CO₂. The PVDF layers have flowed radially into gaps of adjacent metallic coils forming whitened noses. Microbeam small‐angle X‐ray scattering (SAXS) scanning reveals a considerable morphological gradient in the polymer layers. PVDF layers (inner: wear, outer: barrier) in two zones (undamaged and damaged) are scanned. Far from noses and damage zone, the samples are isotropic without voids. Their morphological parameters are determined and compared to virgin material. Approaching the noses, the structure turns into highly oriented microfibrils perpendicular to the local flow into the gaps. Here, voids extend parallel to the microfibrils. At edges of the metallic structure, they turn more perpendicular to the layer. Crystallite orientation extends out to both sides of the whitened nose regions, but in the undamaged samples, tilting of the orientation direction and void‐formation are restricted to the white regions: successive mechanisms of cold drawing are mapped into space. Under the damaged spot, voids and crystallite orientation extend through the entire layer. POLYM. ENG. SCI., 55:2869–2877, 2015. © 2015 Society of Plastics Engineers     

Anatomical,Morphological, and Phytochemical Effects of Inoculation with Plant Growth- Promoting Rhizobacteria on Peppermint (<Emphasis Type="Italic">Mentha piperita</Emphasis>)

Plant growth-promoting rhizobacteria (PGPR) generally exert their effects through enhancement of plant nutrient status and/or phytohormone production. The effects of PGPR on aromatic plant species are poorly known. We measured plant growth parameters, chlorophyll content, trichome density, stomatal density, and levels of secondary metabolites in peppermint (Mentha piperita) seedlings inoculated with PGPR strains Bacillus subtilis GB03, Pseudomonas fluorescens WCS417r, P. putida SJ04, or a combination of WCS417r?+?SJ04. The treated plants, in comparison with controls, showed increases in shoot biomass, root biomass, leaf area, node number, trichome density, and stomatal density, and marked qualitative and quantitative changes in monoterpene content. Improved knowledge of the factors that control or affect biosynthesis of secondary metabolites and monoterpene accumulation will lead to strategies for improved cultivation and productivity of aromatic plants and other agricultural crops without the use of chemical fertilizers or pesticides.     

A Solvent‐Free Dispersion Method for the Preparation of PET/MWCNT Composites

A simple, easily accessible solvent‐free method for the dispersion of MWCNTs into PET is proposed, based on the preparation of a microparticulate polymer/nanotube masterbatch via cryogenic impact‐milling and its subsequent melt blending with the bulk polymer. Thermal and mechanical properties of nanocomposites prepared using this method were evaluated as a function of nanotube concentration. Thermal stability was improved, and superior crystallization behavior of PET in the nanocomposites was observed. Significant improvements of around 25% in tensile strength and tensile modulus of the nanocomposites was achieved using this strategy, with only 0.25 wt.‐% MWCNT, compared to previous literature data where 1 wt.‐% MWCNT was employed.

     

Motor selection via impedance-matching for driving nonlinearly damped,resonant loads

This paper presents a novel method for selecting the most appropriate motor–gearhead combination for nonlinearly damped, resonant loads. The method extends to the nonlinear damping case the impedance-matching condition which is used to guarantee a maximum power transfer in linear network theory. In particular, the method is applicable in general to resonant loads where the damping is an odd and memoryless nonlinear function of the velocity. This condition is very common in biomimetic robotics, in particular when designing propulsion systems based on flapping appendages, such as wings or fins, in viscous fluids, such as air or water. The method is graphical in nature and is based on a power vs. impedance-mismatch factor. Such a factor is function of the ratio of the motor armature resistance to the load equivalent resistive impedance reflected at the motor armature, where the latter is nonlinear and depends on the desired kinematics as well as on the transmission ratio and efficiency. The method allows comparing, for a given desired appendage kinematics, all motor–gearhead combinations at once while taking into account all possible constraints such as maximum current, power, and torque.     

Widely distributed lysogeny in probiotic lactobacilli represents a potentially high risk for the fermentative dairy industry

Prophages account for most of the genetic diversity among strains of a given bacterial species, and represent a latent source for the generation of virulent phages. In this work, a set of 30 commercial, collection and dairy-isolated Lactobacillus casei group strains were used. A species-specific PCR assay allowed a reclassification, mainly of strains previously considered Lactobacillus casei, into either Lactobacillus paracasei or Lactobacillus rhamnosus. All the strains were induced with mitomycin C, allowing direct recovering of phage DNA in 25 cases, which corroborates the widely occurrence of lysogeny on Lactobacillus genomes, including probiotic strains of Lactobacillus casei group. Ten out of 11 commercial strains studied contained prophages, evidencing the potential risks of their use at industrial scale. Strains were also induced by treatment with different concentrations of hydrogen peroxide but, however, this agent was not able to evidence a prophage release for any of the strains tested. According to a RAPD-PCR fingerprinting with M13, 1254 and G1 primers, most of the commercial strains presented a high degree of homology and, regarding BglII- and BamHI-restriction profiles of phage DNA, six of them harboured the same prophage. Surprisingly, both Lactobacillus paracasei ATCC 27092 and Lactobacillus paracasei ATCC 27139 shared a second prophage with both an INLAIN collection and a commercial Lactobacillus paracasei strains, whereas two collection strains shared a third one. On the other hand, mitomycin C-inducible prophages were detected only on about a half of the strains isolated from dairy products, which had (with only one exception) from moderate to high correlation coefficients according to RAPD-PCR fingerprinting. After induction, supernatants were filtered and tested against nine Lactobacillus strains of the set sensitive to previously assayed virulent phages, allowing isolation of two new virulent phages: ф iLp1308 and ф iLp84. Both phages were able to lyse all but one strains sensitive to previously assayed phage MLC-A.     

Process simulation of a hybrid SOFC/mGT and enriched air/steam fluidized bed gasifier power plant

The aim of this work is to experimentally and numerically analyze the performance of a integrated power plant composed by a steam oxygen fluidized bed biomass gasifier fed by woods, a Solid Oxide Fuel Cell (SOFC) and a micro Gas Turbine (mGT). The numerical analysis is carried out by using ChemCAD software. In particular, SOFC and gasifier were modeled using proper developed Fortran subroutines interfaced to the basic software. The adopted SOFC model was already validated by the authors in previous works, while the gasifier model was here developed and validated by means of experimental activities carried out by using a bench scale gasifier. Different compounds (Benzene, Toluene, Naphthalene, Phenols) were chosen to analyze the tar evolution in the gaseous stream during the gasification process. Hot gas cleaning (based on catalytic ceramic filter candles inserted in the freeboard of the gasifier – UNIQUE concept) was adopted to remove tar and particulates from the fuel hot gas stream. Different moisture contents in the range between 10 and 30% (i.e. in a deviation of 10% around the usual wood moisture content of 20%) were numerically simulated as well as the degree of purity of the oxygen utilized in the power plant (between 25% and 95%, the rest being N₂). The power requirement for pure oxygen production leads to a reduction of the electrical efficiency of the whole power plant. For this reason, a sensitivity analysis was conducted to find the optimal operation conditions in order to maximise the syngas (H₂, CO) content in the produced gas, while maintaining a high overall electrical efficiency.     

A novel method of preparation of silicon-on-diamond materials

A new method of preparation of silicon-on-diamond materials is discussed in detail. Pre-characterization of the samples surfaces has been carried out, in order to calculate the optimal pressure for surface contact before the bonding process. The method is based on pulsed laser irradiation, in the 20 ps–7 ns range, at a wavelength of 355 nm, for which diamond is transparent and silicon highly absorbing. Under these conditions the material melts locally, within 100 nm at the interface, giving rise to amorphous silicon and silicon carbide. The mechanical strength of the bonding has been assessed by adhesion tests. Preliminary result on resistance to thermal annealing at 400 C in air is also reported. Uniformity of the silicon–diamond interface has been verified by scanning electron microscopy. Raman and infrared spectroscopy allowed to detect and estimate quantitatively the amorphous Si and SiC phases at the interface. A finite element simulation has been carried out, taking into account the processes occurring during the laser pulse and the subsequent cooling of the materials. As a result, energy densities per pulse required to melt locally diamond and silicon have been obtained as functions of the pulse width, giving a rationale to the formation of the SiC bond in terms of diamond–silicon inter diffusion. The experimental results of bondings performed at various energy density and pulse widths are in agreement with the model. The experimental results and the theoretical predictions are compared and discussed.     

Distributed measurement systems

In this paper the technologies that permit the development of distributed measurement systems over the internet are discussed. The different concepts of virtual instrumentation are summarized. Two different approaches to measurement system development are compared — the first is based on the commercially available environment , and the second, widely used in the research field, is based on the object-oriented programming.