Molar absorptivity of poly(methyl methacrylate) in the near-ultraviolet region

The molar absorptivities of methyl methacrylate monomer and of thermally polymerized, monomer-free poly(methyl methacrylate) have been measured in the range 2200–3000 Å, and smoothed values are presented at wavelength intervals of 20 Å over much of this range. Typical amounts of monomer present in a thermally polymerized bulk polymer and in films cast from CH₂Cl₂ solutions of the bulk polymer have been ascertained. The use of such absorptivity values to determine the amount of monomer present in polymer samples is evaluated.     

Prevention of water pollution problems in mining: The bactericide technology

In pyritic environments, the bacteriaThiobacillus ferrooxidans catalyze acid formation by increasing the oxidation rate of pyrite by a factor of one million. This acid solubilizes metals and pollutes adjacent streams and lands. Bactericide sprays during mining and waste disposal operations attack the source of the problem by preventing acid formation and metals solubilization. Used in conjunction with current water treatment systems, bactericides can dramatically reduce operating costs. Controlled release bactericides contribute to successful reclamation by providing assurance against revegetation failure and post-reclamation water quality problems that can necessitate perpetual water treatment. While inhibitingT. ferrooxidans these organic compounds aid in the establishment of beneficial heterotrophic bacteria which support vegetation. These conditions continue to persist after the bactericide is depleted from the controlled release system. Case Studies I and II show that bactericides inhibit acid generation during hard rock and coal mining operations and they are cost effective. Case Studies III and IV illustrate the improvement in water quality and vegetation after reclamation when controlled release bactericides were used. Economic analyses show cost benefits are achieved when controlled-release bactericides are part of the reclamation plan.     

An investigation of phase transformation behavior in sputter-deposited PtMn thin films

Sputter-deposited, equiatomic PtMn thin films have application in giant magnetoresistive spin valves, tunneling magnetoresistive spin valves, and magnetic random access memory. However, the as-deposited films are found to be a disordered A1 phase in a paramagnetic state rather than an antiferromagnetic phase with L1₀ structure, which is needed for device operation. Therefore, a postannealing step is required to induce the phase transformation from the asdeposited A1 face-centered-cubic phase to the antiferromagnetic L1₀ phase. The A1 to L1₀ metastable transformation was studied by x-ray diffraction and differential-scanning calorimetry. An exothermic transformation enthalpy of −12.1 kJ/mol of atoms was determined. The transformation kinetics were simulated using the Johnson-Mehl-Avrami analysis.     

Thiamine concentrations in lake whitefish eggs from the upper Great Lakes are related to maternal diet

Thiamine deficiency is responsible for reproductive impairment in several species of salmonines in the Great lakes, and is thought to be caused by the consumption of prey containing thiaminase, a thiamine-degrading enzyme. Because thiaminase levels are extremely high in dreissenid mussels, fish that prey on them may be susceptible to thiamine deficiency. We determined thiamine concentrations in lake whitefish Coregonus clupeaformis eggs from the upper Laurentian Great Lakes to assess the potential for thiamine deficiency and to determine if thiamine concentrations in lake whitefish eggs were related to maternal diet. Mean thiamine concentrations in lake whitefish eggs were highest in Lake Huron, intermediate in Lake Superior, and lowest in Lake Michigan. Some fish had thiamine concentrations below putative thresholds for lethal and sublethal effects in salmonines, suggesting that some larval lake whitefish may currently be at risk of at least sublethal effects of low thiamine concentrations, although thiamine thresholds are unknown for lake whitefish. Egg thiamine concentrations in lake whitefish eggs were statistically significantly related to isotopic carbon signatures, suggesting that egg thiamine levels were related to maternal diet, but low egg thiamine concentrations did not appear to be associated with a diet of dreissenids. Egg thiamine concentrations were not statistically significantly related to multifunction oxidase induction, suggesting that lower egg thiamine concentrations in lake whitefish were not related to contaminant exposure.     

Relationship between the attenuation of downwelling irradiance at 490 nm with the attenuation of PAR (400 nm-700 nm) in the Baltic Sea

The vertical attenuation coefficient of diffuse downwelling irradiance at 490 nm (K_d 490) is a parameter that we routinely derive from SeaWiFS images of the Baltic Sea. Here, through model simulations, we examine the relationship between K_d(490), and the vertical attenuation coefficient of PAR (K_d PAR), as this later coefficient determines the light available for aquatic photosynthesis. A simple semi-analytical model is used to predict K_d(490) and K_d(PAR), as a function of the concentrations of chlorophyll, colored dissolved organic material (CDOM), suspended inorganic, and suspended organic particulate material. A series of model simulations based on variations in these optically significant constituents over a range realistic for the Baltic Sea, are used to define the relationship between the two attenuation coefficients.

Kd(PAR)=0.6677Kd^0.6763(490).     

Priority-based rate control for service differentiation and congestion control in wireless multimedia sensor networks

In wireless multimedia sensor networks (WMSNs) a sensor node may have different types of sensor which gather different kinds of data. To support quality of service (QoS) requirements for multimedia applications having a reliable and fair transport protocol is necessary. One of the main objectives of the transport layer in WMSNs is congestion control. We observe that the information provided may have different levels of importance and argue that sensor networks should be willing to spend more resources in disseminating packets carrying more important information. Some applications of WMSNs may need to send real time traffic toward the sink node. This real time traffic requires low latency and high reliability so that immediate remedial and defensive actions can be taken when needed. Therefore, similar to wired networks, service differentiation in wireless sensor networks is also an important issue. We present a priority-based rate control mechanism for congestion control and service differentiation in WMSNs. We distinguish high priority real time traffic from low priority non-real time traffic, and service the input traffic based on its priority. Simulation results confirm the superior performance of the proposed model with respect to delays, delay variation and loss probability.     

Effectiveness of participatory ergonomic interventions on health outcomes: a systematic review

The objective of this study was to conduct a systematic review of the literature on the effectiveness of participatory ergonomic (PE) interventions for improving workers' health. The search strategy targeted six electronic databases and identified 442 potential articles. Each article was examined by pairs of reviewers for relevance (assessed a participative ergonomic workplace intervention, with at least one health outcome, published in English in peer reviewed literature). Twenty-three articles met relevance criteria and were then appraised for methodological strength. Using a best evidence synthesis approach, 12 studies that were rated as 'medium' or higher provided partial to moderate evidence that PE interventions have a positive impact on: musculoskeletal symptoms, reducing injuries and workers' compensation claims, and a reduction in lost days from work or sickness absence. However, the magnitude of the effect requires more precise definition.     

Severity of delayed (“secondary”) cerebral energy failure after acute hypoxia-ischemia is related to the time integral of acute ATP depletion

The aim of this study was to reproduce the delayed (secondary) cerebral energy failure previously described in birth-asphyxiated newborn infants and to investigate relationships between primary insult severity and the extent of the delayed energy failure. Phosphorus (³¹P) magnetic resonance spectroscopy (MRS) at 7 T was used to study the brains of 12 newborn piglets during an acute, reversible, cerebral hypoxic-ischemic episode which continued until nucleotide triphosphates (NTP) were depleted. After reperfusion and reoxygenation, spectroscopy was continued for 48 h. High-energy metabolite concentrations returned to near normal levels after the insult, but later they fell as delayed energy failure developed. The time integral of NTP depletion in the primary insult correlated strongly with the minimum [phosphocreatine (PCr)]/[inorganic orthophosphate (P_i)] observed 24–48 h after the insult. (Linear regression analysis gave slope –8.04 h^–1; ordinate intercept=1.23;r=0.92;P<0.0001.) This model is currently being used to investigate the therapeutic potential of various cerebroprotective strategies including hypothermia.     

SATCHMORE: SATCHMO with RElevancy

We introduce a relevancy detection algorithm to be used in conjunction with the SATCHMO prover. The version of SATCHMO considered here is essentially a bidirectional prover, utilizing Prolog (back chaining) on Horn clauses and forward chaining on non-Horn clauses. Our extension, SATCHMORE (SATCHMO with RElevancy), addresses the major weakness of SATCHMO: the uncontrolled use of forward chaining. By marking potentially relevant clause head literals, and then requiring that all the head literals be marked relevant (be totally relevant) before a clause is used for forward chaining, SATCHMORE is able to guide the use of these rules. Furthermore, the relevancy testing is performed without extending the proof search beyond what is done in SATCHMO. A simple implementation of the extended SATCHMO can be written in Prolog. We describe our relevancy testing approach, present the implementation, prove soundness and completeness, and provide examples that demonstrate the power of relevancy testing.This research was partially supported by NSF Grants IRI-8805696 and CCR-9116203. This paper is a major revision of Wilson and Loveland (1989).     

Sparse online kernelized actor-critic Learning in reproducing kernel Hilbert space

In this paper, we develop a novel non-parametric online actor-critic reinforcement learning (RL) algorithm to solve optimal regulation problems for a class of continuous-time affine nonlinear dynamical systems. To deal with the value function approximation (VFA) with inherent nonlinear and unknown structure, a reproducing kernel Hilbert space (RKHS)-based kernelized method is designed through online sparsification, where the dictionary size is fixed and consists of updated elements. In addition, the linear independence check condition, i.e., an online criteria, is designed to determine whether the online data should be inserted into the dictionary. The RHKS-based kernelized VFA has a variable structure in accordance with the online data collection, which is different from classical parametric VFA methods with a fixed structure. Furthermore, we develop a sparse online kernelized actor-critic learning RL method to learn the unknown optimal value function and the optimal control policy in an adaptive fashion. The convergence of the presented kernelized actor-critic learning method to the optimum is provided. The boundedness of the closed-loop signals during the online learning phase can be guaranteed. Finally, a simulation example is conducted to demonstrate the effectiveness of the presented kernelized actor-critic learning algorithm.