Effect of pore structures on the electrochemical performance of porous silicon synthesized from magnesiothermic reduction of biosilica

Two kinds of porous silicon(PS) were synthesized by magnesiothermic reduction of rice husk silica(RHS) derived from the oxidization of rice husks(RHs). One was obtained from oxidization/reduction at 500 ℃ of the unleached RHs, the other was synthesized from oxidization/reduction at 650 ℃ of the acidleached RHs. The structural difference of the above PS was compared: the former had a high pore volume(PV, 0.31 cm3/g) and a large specific surface area(SSA, 45.2 m~2/g), 138 % and 17 % higher than the latter, respectively. As anode materials for lithium ion batteries, the former had reversible capacity of 1 400.7 m Ah/g, 987 m Ah/g lower than the latter; however, after 50 cycles, the former had 64.5 % capacity retention(907 m Ah/g), which was 41.2 % higher than the latter(555.7 m Ah/g). These results showed that the electrochemical performance of PS was significantly affected by its pore structures, and low reduction temperature played the key role in increasing its porosity, and therefore improving its cycling performance.     

区域电磁环境的动态特性表征

区域电磁环境中各种电磁干扰辐射信号种类繁多、调制体制各异,信号参数的动态变化,传播路径及其相应影响的不确定性,表现为电磁信号在时间、能量上相互干扰发生异常变化造成电磁环境动态性异常激烈,导致区域内接受设备系统性能下降。针对这一问题,提出基于分形理论与数学形态学相结合的方法,研究区域电磁环境动态特征,利用分形维数表征电磁环境动态性。首先,基于信号基础理论对区域接收点处电磁信号的集合进行建模;其次,利用数学形态学滤波原理对接收的电磁信号集合进行交替滤波,滤除电磁信号中的脉冲噪声和白噪声;最后,运用分形理论求解电磁环境接收点集合的关联维数,并对计算结果进行仿真分析,表明该方法能从时间、空间和能量上为电磁环境的动态性提供有利支撑。     

Mechanical properties and microstructure of Portland cement concrete prepared with coral reef sand

The feasibility of using coral reef sand (CRS) in Portland cement concrete is investigated by testing the mechanical property and microstructure of concrete. The composition, structure and properties of the CRS are analyzed. Mechanical properties and microstructure of concrete with CRS are studied and compared to concrete with natural river sand. The relationship between the microstructure and performance of CRS concrete is established. The CRS has a porous surface with high water intake capacity, which contributes to the mechanical properties of concrete. The interfacial transition zone between the cement paste and CRS is densified compared to normal concrete with river sand. Hydration products form in the pore space of CRS and interlock with the matrix of cement paste, which increases the strength. The total porosity of concrete prepared with CRS is higher than that with natural sand. The main difference in pore size distribution is the fraction of fine pores in the range of 100 nm.     

我国智慧城市发展现状与问题研究

目前我国智慧城市正处于试点推广阶段,还存在发展导向不明确、建设标准不统一等诸多理论和实践问题.为了更好地服务智慧城市的发展,基于城市结构和功能的再造理念,从城市规划、建设与管理的全过程进行阐释智慧城市的内容,分析智慧城市发展现状,针对智慧城市建设中存在的顶层设计缺位、城市管理效能低下等问题,提出加强一体化顶层设计、优化智慧城市发展环境等建议,从而为我国智慧城市的可持续发展提供参考.     

水平弹性支撑抛物线拱在均布荷载与热载荷作用下的屈曲特性

分析了水平弹性支撑抛物线拱在均布荷载与热负荷共同作用下的屈曲特性,通过变分原理推导了弹性支撑抛物线拱的非线性平衡方程,得到了外荷载与径向位移和轴力的关系,用数值法分析了弹性支撑抛物线拱在均布荷载与热负荷共同作用下屈曲特性。     

群策式智能多联机末端在大学教学楼的设计应用与分析

建筑能耗占全国能耗比重较大,中央空调在公共建筑中使用广泛,滥用无管理使得公共建筑夏季空调能耗很高。本文针对大学中多联机中央空调系统以末端智能调控系统控制策略方向为目的进行基于群策控制智能末端控制改造,达到节能的目的。通过单片机对空调控制面板进行电信号控制,数据判断及传输通过总服务器进行计算。控制方式采用自动控制与群策相结合,由微信公众号进行查询及发送命令,通过网络传输和数据库相连。数据库录入空调系统使用教室信息、工作及学习时段表等相关数据。从调研、设计、模拟来看,节能效果显著,最理想节能量可达84%,在调研过程中大部分学生对此可接受。     

稀薄效应下空气静压主轴动态特性分析及试验研究

针对微尺度下空气静压主轴的动态特性问题,建立了体现稀薄效应的主轴有限元模型,对主轴的模态、谐响应进行了研究。首先,基于有限元法对主轴进行建模,轴承部分采用Combin14弹簧单元建模。接着,通过扰动法得出稀薄效应下以及传统情况下轴承的刚度、阻尼参数,将此参数替代主轴模态分析中采用的弹簧单元的刚度、阻尼参数,结合主轴实际工作状态,进而分析出两种情况下的主轴的模态结果。然后,对主轴进行谐响应分析,校核之前模态分析结果。最后,对主轴进行锤击模态试验,从而检验两种状态下的模态分析结果。实验结果表明：稀薄效应下分析所得主轴1阶固有频率值较试验测量值的误差只有3.6%左右,而传统情况下得出的1阶频率值的误差在15%左右,这对主轴系统以后的优化设计和精度控制方面具有一定的理论依据。     

基于改进的特征图串法识别人体行为

视频的有效表达是识别行为关键与难点。本文提出了一种改进的特征图串的视频表达方法,在动态规划框架下,利用子模优化方法和图匹配技术实现了行为的识别。首先,利用近年来被广泛应用的时空特征点探测器获取视频序列中的关键点;接着引入子模优化方法完成视频在时域上的划分;然后在每个时域区间内以关键点为节点形成图结构,使得行为视频的特征表示转化为有序的特征图串;最后基于重加权随机游走的图匹配方法和动态时间规整实现成对视频的匹配与对齐。通过两组公开数据集（KTH和UT-interaction）上的实验及与其他方法的比较,验证了本文方法是有效的、可行的。