Small molecule interlayer for solution processed phosphorescent organic light emitting device

Using a 4,4′,4′′-tris(N-carbazolyl)-triphenylamine (TCTA) small molecule interlayer, we have fabricated efficient green phosphorescent organic light emitting devices by solution process. Significantly a low driving voltage of 3.0 V to reach a luminance of 1000 cd/m² is reported in this device. The maximum current and power efficiency values of 27.2 cd/A and 17.8 lm/W with TCTA interlayer (thickness 30 nm) and 33.7 cd/A and 19.6 lm/W with 40 nm thick interlayer are demonstrated, respectively. Results reveal a way to fabricate the phosphorescent organic light emitting device using TCTA small molecule interlayer by solution process, promising for efficient and simple manufacturing.     

Stretching‐Induced Growth of PEDOT‐Rich Cores: A New Mechanism for Strain‐Dependent Resistivity Change in PEDOT:PSS Films

It remains a fundamental challenge in the development of stretchable electronics to understand how mechanical strain changes the electrical properties of materials. Although the piezoresistive behavior of poly(3,4‐ethylene‐ dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been observed, its intrinsic origin is not yet fully understood because there are many extrinsic contributing factors and an experimental platform with which to assess such behavior has not been established. Here, systematic analysis shows that the matching Poisson's ratio and elastic modulus between PEDOT:PSS films and their underlying substrates is important in decoupling the factors that affect the material's piezoresistivity, allowing for tunable resistivity. Based on such a fundamental understanding, the conductivity of PEDOT:PSS can be controlled to be invariant and decrease as a function of applied tensile stress. Furthermore, a linear response of the resistivity with respect to mechanical strains of up to 60%, which has never before been realized, is shown. The irreversible conductivity enhancement is primarily caused by the coalescence‐induced growth of conductive PEDOT‐rich cores.     

Local Immune‐Triggered Surface‐Modified Stem Cells for Solid Tumor Immunotherapy

Here, described are additional treatment strategies that make use of human mesenchymal stem cell (hMSC)‐based local immunotherapeutic agents for the treatment of solid tumors. Dibenzocyclooctyne‐poly(ethylene glycol)‐pheophorbide A conjugates are engineered for cell surface conjugation by copper‐free click chemistry and are subsequently conjugated to hMSC (hMSC‐DPP). hMSC‐DPP can recognize and migrate toward cancer lesions, where they secrete pro‐inflammatory cytokines such as interleukin (IL)‐6, IL‐8, and heat shock protein 70 in pursuance of photodynamic therapy‐mediated cell death. The secreted immune factors trigger interferon gamma, IL‐2, IL‐4, IL‐12, and granulocyte‐macrophage colony‐stimulating factor, resulting in the local accumulation of T cells, B cells, natural killer cells, and antigen presenting cells at the tumor site. Treatment with hMSC‐DPP induces the accumulation of cytokines at the cancer site and minimizes systemic immune‐based side effects. This strategy is expected to increase the vulnerability of cancer cells to immune cells and cytokines, thus aiding in the development of a robust treatment platform for cancer immunotherapy.     

Coverage path planning for UAVs based on enhanced exact cellular decomposition method

In this paper, an enhanced exact cellular decomposition method to plan the coverage path of UAVs in a polygon area is proposed. To be more specific, the contributions of the paper are: firstly, the turning motion of UAVs is shown to be less efficient from the viewpoints of route length, duration and energy. Secondly, the problem of coverage Path Planning (CPP) in a convex polygon area is transformed to width calculation of the convex polygon, and a novel algorithm to calculate the widths of convex polygons with time complexity of O(n) is developed. The path of the least number of turns for an UAV based on the widths of convex polygons is devised. Thirdly, a convex decomposition algorithm for minimum width sum based on the greedy recursive method which revolves around decomposing the concave area into convex subregions is developed. It is proved that the algorithm is a polynomial time algorithm. To avoid unnecessary back and forth motion, some entirely adjacent subregions are combined. Finally, comparing different weights of two joint-points, a subregion connection algorithm based on minimum traversal of weighted undirected graph is proposed to connect the coverage paths of the subregions. Simulation results show that the proposed method is feasible and effective.     

Reproducible and Sensitive Plasmonic Sensing Platforms Based on Au-Nanoparticle-Internalized Nanodimpled Substrates

Electromagnetic enhancement effects through localized surface plasmon resonance considerably amplify the intensity of incident light when molecules are positioned in the vicinity of miniscule nanogaps. The aggregation of plasmonic nanoparticles synthesized using bottom-up methods has been extensively used to generate hot spots in solutions. These methods assist in obtaining non-periodic plasmonic signals, because the realization of uniform nanogaps through particle aggregation is difficult. Nanostructured substrates with gaps of 20–100 nm have also been fabricated using the top-down approach. However, the fabrication of smaller nanogap templates using these methods is difficult owing to high costs and low throughput. Therefore, a nanodimple array internalized with AuNPs is developed in this study to mitigate the challenges encountered in the bottom-up and top-down approaches. Precise nanogaps are generated by regularly internalizing AuNPs in the cavities of nanodimples through DNA hybridization. Simulations of the electric field distribution indicate that the incorporation of 80 nm-sized AuNPs into a curved nanodimpled Au substrate generate high-density volumetric hot spots within a detection volume, and result in a high plasmonic enhancement factor of 8.25 × 10⁷. The tremendous potential of the proposed plasmonic platform as an SERS-based biomedical diagnostic device is also verified.     

Study of Methods for Element Data Service for Electronic Documents Related to National R&D Projects

Major countries are supporting new knowledge creation and innovative activities by opening data so that the research results carried out by government budgets can serve as public goods. The Republic of Korea has also made research and development (R&D) reports and papers available in electronic file format, which is the result of national R&D programs for the general public. However, the extraction of meaningful information among unstructured data in text format has not satisfied researchers’ expectations. In order to evolve into a customized service reflecting the opinions of researchers, we investigated the demand for necessary contents and services at the planning stage of R&D projects. This study attempts to propose a method to offer significant information which shows a bigger unit than objects based on trend information with extraction and processing demands focusing on R&D reports based on the results of questionnaire survey and interviews with researchers. This study aims to provide the integration service, tentatively named ‘element data service’, of key sentences and table/figure images with a high demand for the utilization of researchers. The main procedure of the proposed method consists of the subject classification of the R&D report, the extraction of table/figure image, and the extraction of main sentence. We used public reports of the same classification published from 2012 to 2016 for the experiment and utilized the extractive summarization method for the copyright protection of report original text. After realizing the simple prototype, we examined the service possibility through the researcher target reviews.     

Cobalt Assisted Synthesis of IrCu Hollow Octahedral Nanocages as Highly Active Electrocatalysts toward Oxygen Evolution Reaction

Development of oxygen evolution reaction (OER) catalysts with reduced precious metal content while enhancing catalytic performance has been of pivotal importance in cost‐effective design of acid polymer electrolyte membrane water electrolyzers. Hollow multimetallic nanostructures with well‐defined facets are ideally suited for saving the usage of expensive precious metals as well as boosting catalytic performances; however, Ir‐based hollow nanocatalysts have rarely been reported. Here, a very simple synthetic scheme is reported for the preparation of hollow octahedral nanocages of Co‐doped IrCu alloy with readily tunable morphology and size. The Co‐doped IrCu octahedral nanocages show excellent electrocatalytic activity and long‐term durability for OER in acidic media. Notably, their OER activity represents one of the best performances among Ir‐based acidic OER catalysts.     

Efficient Utilization of Available Channels in Dynamic Spectrum Access Networks

In case of dynamic spectrum access networks, how to efficiently utilize the dynamically available bandwidth is very important to enhance the performance of the networks. In this paper, we propose an Error Adaptive MAC protocol which adaptively changes its transmission mode according to the channel status. Using the cognitive radio technology, additional channels are assumed to be randomly available for data transmission. When the channel error rate is relatively high, those additional channels are utilized for error recovery; otherwise, the extra channels can be used to increase the throughput if the wireless medium is stable and reliable. We formulate an analytical model to study the dynamics of our adaptive MAC protocol, and using simulation, show our proposed method can significantly enhance the throughput of dynamic spectrum access networks.     

A single capacitor loop filter phase-locked loop with frequency voltage converter

A novel phase-locked loop that has a loop filter consisting of only one capacitor is designed with a frequency voltage converter (FVC). Simulation and measurement results show that the proposed phase-locked loop (PLL) works stably demonstrating that the FVC works effectively as a resistor. Measurement results of the proposed PLL fabricated in a one-poly six-metal 0.18 μm CMOS process show that the phase noise is ?109 dBc/Hz at 10 MHz offset from 752.7 MHz output frequency.