The effect of organofunctional nanosilica on the cross-linking process and thermal resistance of UF resin

The paper investigates the effect of surface modification of fumed nanosilica with (3-aminopropyl)triethoxysilane (APTES) on the kinetics and thermal stability of urea-formaldehyde (UF) resin. In the course of the investigation, nanoparticles were modified with APTES in the ratio 1, 2, 3, 4 and 5 part by weight (PBW) per 100 PBW of SiO₂. The parameters of curing kinetics of the resin, the conversion degree and its thermal stability were determined with use of differential scanning calorimetry (DSC) and thermogravimetric analysis (TG). The effect of nanosilica silanization on the curing process of resin was evaluated by determining the gel time at 100 °C and the activation energy (E_a) of the cross-linking process, the initial and final temperature of the reaction (T_onset, T_endset), the maximum value of the exothermic peak (T_p), the amount of emitted heat (ΔH_Tp) and the conversion degree (α_Tp) that responds to T_p. With the maximum level of silica modification, we have noted a decrease in the reactivity of the resin, which is manifested by a slightly longer gel time of the resin as well as an increase in the value of activation energy of the cross-linking process. It is accompanied by a slight decrease of resin conversion degree α_Tp. The modification of silica, regardless of the amount of silane inoculated on its surface, results in the increase in the thermal stability of UF resin.     

Small Alterations in Cobinamide Structure Considerably Influence sGC Activation

Specially designed B‐ring‐modified cobalamin derivatives were synthesized and tested as potential activators of soluble guanylyl cyclase (sGC). Herein, we disclose the influence of substituents at the c‐ and d‐positions in hydrophilic and hydrophobic cobyrinic acid derivatives on their capacities to activate sGC. The presence of the amide group at c‐/d‐position in cobyrinic acid derivatives strongly influence the level of sGC activation. Removal of the d‐position altogether has a profound effect for hydrophobic compounds. In contrast, little differences were observed in hydrophilic ones.     

Effect of Aminated Chitosan-Coated Fe3O4 Nanoparticles with Applicational Potential in Nanomedicine on DPPG,DSPC, and POPC Langmuir Monolayers as Cell Membrane Models

An adsorption process of magnetite nanoparticles functionalized with aminated chitosan (Fe₃O₄-AChit) showing application potential in nanomedicine into cell membrane models was studied. The cell membrane models were formed using a Langmuir technique from three selected phospholipids with different polar head-groups as well as length and carbon saturation of alkyl chains. The research presented in this work reveals the existence of membrane model composition-dependent regulation of phospholipid-nanoparticle interactions. The influence of the positively charged Fe₃O₄-AChit nanoparticles on a Langmuir film stability, phase state, and textures is much greater in the case of these formed by negatively charged 1,2-dipalmitoyl-sn-glycero-3-phospho-rac-(1-glycerol) (DPPG) than those created by zwitterionic 1,2-distearoyl-sn-glycero-3-phosphocholine (DSPC) and 2-oleoyl-1-palmitoyl-sn-glycero-3-phosphocholine (POPC). The adsorption kinetics recorded during penetration experiments show that this effect is caused by the strongest adsorption of the investigated nanoparticles into the DPPG monolayer driven very likely by the electrostatic attraction. The differences in the adsorption strength of the Fe₃O₄-AChit nanoparticles into the Langmuir films formed by the phosphatidylcholines were also observed. The nanoparticles adsorbed more easily into more loosely packed POPC monolayer.     

Ozonation of Polycyclic Aromatic Hydrocarbons in Water Solution

The degradation of three polycyclic aromatic hydrocarbons (PAHs): benzo[a]pyrene (BAP), chrysene (CHR), and fluorene (FLU) in aqueous solution using ozone was investigated. The influence of pH of the reaction mixture, ozone concentration, and the presence of a radical scavenger on the reaction rate was determined. The highest rate of PAHs disappearance was achieved in acidic solutions. The radical scavenger, tert-butanol, effectively inhibited the rate of PAHs destruction. The rate constants of direct reaction of PAHs with ozone were calculated and they were equal to (3.32 ± 0.21) × 10⁴; (1.10 ± 0.15) × 10⁴ and 44.8 ± 1.1 M^?1s^?1 for BAP, CHR, and FLU, respectively. The contributions of direct ozonolysis, and radical reaction to PAHs oxidation in ozonation processes, were evaluated.     

Recommendation on modelling of solar energy incident on a building envelope

It is important to know how to design a building to meet seasonally varying energy needs. In high latitude countries in winter the demand for space heating is high and a building envelope should receive maximum incident solar energy. On the other hand, in summer, walls and roofs exposed to incident solar radiation usually require shading to avoid too much solar gain. Data on solar energy availability are crucial for good building design. However, it is important how the availability of solar radiation is determined. An important aim of the paper presented is to give some results of a comparative analysis of two basic sky models, isotropic: Hottel–Woertz–Liu–Jordan and anisotropic: the HDKR, Hay–Davies–Klucher–Reindl, to recommend one of these models for determination of solar energy availability on a building envelope and to formulate the energy balance of a building. Differences between results obtained from both models increase with the slope of exposed surfaces. The biggest differences (12–15%) are evident for vertical south surfaces, especially in summer. The simplified isotropic sky model is not recommended for evaluation of solar radiation availability on the building envelope. Underestimation of solar gains can lead to the selection of an unsuitable concept and construction of a building and result in poor indoor thermal comfort, i.e. overheating of rooms in summer.     

Polyacrylate anion exchangers in sorption of heavy metal ions with non-biodegradable complexing agents

The polyacrylate anion exchangers are widely used in purification of heavy metal ions from wastewaters and different accompanying complexing agents. Such effluents containing the chelators (EDTA, NTA, HEDTA, DTPA, and IDA) are discharged from relevant industries such as printed circuits boards, plating on plastics, metal finishing and others. The sorption was studied as a function of phase contact time and pH by the batch technique. It was found that the removal of heavy metal ions in the presence of EDTA, NTA and IDA strictly depends on the phase contact time and pH values. Various kinetic models such as the pseudo first-order and the pseudo second-order as well as the intraparticle one were also tested to estimate the sorption rate. The equilibrium capacities of the studied anion exchangers for Cu(II), Zn(II), Co(II), Ni(II), Pb(II) and Cd(II) in the presence of EDTA were the highest for Pb(II) and Cd(II). The order of sorption for Amberlite IRA 458, Amberlite IRA 958 as well as Amberlite IRA 67 can be as follows: Pb(II) > Cd(II) > Zn(II) > Cu(II) > Ni(II) > Co(II). The stability of forming complexes was also compared. The estimation of the capacities of anion exchangers under investigation by the continuous column studies was also carried out.     

MELODY: A completely decentralized adaptive file system for handling real-time tasks in unpredictable environments

We describe the major features of the completely decentralized adaptive file system MELODY which was designed for realizing anintegrated system design for a distributed real-time system working in a hazardous and unpredictable environment. MELODY's adaptivity mechanisms are based on novel services rendered by the distributed operating system DRAGON SLAYER. The file system, in order to both meet real-time constraints and provide for high availability, allows for replicating, relocating, or deleting file copies. Such copies may also bepublic orprivate. At every site aLocal Task Scheduler tries to schedule the arriving critical tasks, based on the availability of resources at this site such that deadline failures are minimized. Depending on the deadline failure history, status changes as well as file replication, deletion, or relocation are analyzed and managed by the cooperatingLocal File Assigners. In order to analyze MELODY's real-time performance we report on simulation experiments in which its capability of minimizing deadline failures of time-critical tasks was compared to other file system models: an idealbest-case model, abaseline model with no file replication, a file system allowingonly for replication ofprivate copies, and a model which allows forreplication and relocation of public copies only. While the best-case is unrealistic for a distributed implementation, the other models embody only part of MELODY's mechanisms yet have the benefit of a considerably smaller communication overhead. We report on the distributed simulation results which unambiguously show MELODY's superior performance, in addition to the built-in sensitivity to changes in the environment. A DRAGON SLAYER/MELODY prototype has been completed in our labs in order to serve as a distributed real-time testbed in our future work with MELODY.This work was partially supported by IBM Endicott (research Agreement No. 6073-86) by the State of Michigan (IMR-87-146751), and by General Dynamics Land Systems (#DEY-605089).     

Analysis of Residual Stresses and Dislocation Density of AA6082 Butt Welds Produced by Friction Sir Welding

Metallurgical and Materials Transactions A - The Friction Stir Welding (FSW) method was employed to join AA6082 sheets. The welds were produced with different tool traverse speed (200 and...