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61.
Dorota Rutkowska-Zbik Agnieszka Drzewiecka-Matuszek Malgorzata Witko 《Topics in Catalysis》2014,57(10-13):946-952
The present brief review aims at elucidation of the parameters affecting the properties and reactivity of high valent iron(IV) oxo porphyrin complexes, being models of compound II reactive intermediate known from biochemistry of cytochromes and peroxidases. The stress is put on the influence of the axial ligand and porphyrin ring substituents, with special attention on implications for their catalytic activity. 相似文献
62.
Grażyna Budryn Dorota Żyżelewicz Ewa Nebesny Joanna Oracz Wiesława Krysiak 《Food research international (Ottawa, Ont.)》2013,50(1):149-160
This study investigated the influence of antioxidants of green tea aqueous extract (GTE) and green coffee aqueous extract (GCE) in concentrations of 0.25, 0.5 and 1 g·100 g? 1 on the nutritional properties of fine yeast pastry fried products such as donuts. Yeast donuts were made according to the traditional processing technology. In fried donuts physical properties (water activity, pH, hardness and color with the use of instrumental methods) as well as sensory properties were established. Moreover, quality of fat extracted from donuts (composition of fatty acids and peroxide value), content of acrylamide, composition of polyphenols and antioxidant activity were analyzed. Obtained extracts of GTE and GCE contained 26 and 41% of polyphenols, respectively, and the degree of polyphenol degradation during production of donuts was less when the dilution in dough was greater. Both tests indicated that the highest antioxidant activity had donuts with the highest analyzed addition of extract, however depending on the applied test or GTE or GCE had better antioxidant properties. Fatty acid composition was the most beneficial when the addition of GTE and GCE was on a level of 0.25 and 0.5 g·100 g? 1, respectively. In fried donuts relatively low amounts of acrylamide were obtained, amounting to 18–46 μg·kg? 1. Only the lowest addition of GTE and the highest addition of GCE caused an increase of acrylamide content in donuts, while all other levels of added extracts caused a decrease in the content of formed acrylamide. 相似文献
63.
Handover performance in wireless networks is important, especially nowadays, when multimedia services are becoming increasingly available over the wireless devices. However, users expect uncompromised mobility when using the service. Thus, the support of multimedia services is not possible if handover is inefficient. At the same time it is clear that a strict separation between IP Layer and the Link Layer results in built-in sources of delay. The paper discusses the IEEE 802.11 and Mobile IPv4 handover performance in practical scenarios. We introduce a new simultaneous handover scheme with IEEE 802.21 triggers. In order to verify the handover performance, simulation experiments have been conducted, whose results are also presented and discussed. 相似文献
64.
Mackiewicz P Kowalczuk M Mackiewicz D Nowicka A Dudkiewicz M Laszkiewicz A Dudek MR Cebrat S 《Yeast (Chichester, England)》2002,19(7):619-629
We have compared the results of estimations of the total number of protein-coding genes in the Saccharomyces cerevisiae genome, which have been obtained by many laboratories since the yeast genome sequence was published in 1996. We propose that there are 5300-5400 genes in the genome. This makes the first estimation of the number of intronless ORFs longer than 100 codons, based on the features of the set of genes with phenotypes known in 1997 to be correct. This estimation assumed that the set of the first 2300 genes with known phenotypes was representative for the whole set of protein-coding genes in the genome. The same method used in this paper for the approximation of the total number of protein-coding sequences among more than 40 000 ORFs longer than 20 codons gives a result that is only slightly higher. This suggests that there are still some non-coding ORFs in the databases and a few dozen small ORFs, not yet annotated, which probably code for proteins. 相似文献
65.
One lesson learned from the Chernobyl accident was that the spatial distribution of far-field contamination was strongly non-uniform due to local variation of atmospheric conditions, such as wind direction, rain etc. An environmental monitoring system using highly sensitive thermoluminescent LiF:Mg,Cu,P (MCP-N) detectors has been completed and field-tested. The system consists of 3000 MCP-N detectors in 1000 TLD cards (three TLDs per card), two Mikrolab automatic TL readers, heating ovens, and specially developed software which includes a database for rapid evaluation of results. The main dosimetric parameters of MCP-N dosemeters, such as thermally-induced fading, light sensitivity, minimum detectable dose, self-dose, zero-dose, energy response up to 6-7 MeV, influence of annealing and readout conditions on detector stability, have been tested. About 100 locations over an area of about 15,000 km2 in the south of Poland were selected for measurements lasting from 4 days to 3 months. The kerma rates measured over a 4 day screening period agree well with kerma rates determined over a 75 day monitoring period. Results from short- and long-term exposure periods agree well with those performed using MTS-N (LiF:Mg,Ti) over southern Poland in 1985, before the Chernobyl accident. Thus, using the system based on MCP-N detectors, one is able simultaneously to monitor environmental radiation kerma rates at a large number of locations over periods of four days or less. Provided natural background kerma rates at selected monitoring points are available prior to the accident, the system can be applied to assess kerma rates rapidly in the environment, following a nuclear accident. 相似文献
66.
67.
MA Dejun Chung Wo Ong LIU Jianmin & HE Jiawen . Surface Engineering Research Institute CMES Beijing China . Department of Applied Physics Materials Research Center The Hong Kong Polytechnic University Hong Kong China . State Key Laboratory for Mechanical Behavior of Materials Xian Jiaotong University Xian China 《中国科学E辑(英文版)》2004,47(4):398-408
Loadanddepthsensingindentationtechniqueisveryusefulinprobingthemechanicalpropertiesofmaterialsonsmallscales[1—5].Youngsmodulusisoneofthemostcommonlyconcernedmaterialpropertiesmeasuredbythiskindoftechnique.Conventionally,itisachievedonthebasisofthemethodproposedbyOliverandPharr[4]usingthewell-knownrelationship:whereSuistheinitialslopeofunloadingcurve,EristhereducedmodulusandrelatedwiththeYoungsmodulusEandPoissonsratioνoftheindentedmaterialandthose(Ei,ni)oftheindenterbytheequation1/Er=(1-n2… 相似文献
68.
Majczak A Karbowski M Kamiński M Masaoka M Kurono C Niemczyk E Kedzior J Soji T Knap D Hallmann A Wakabayashi T 《Journal of electron microscopy》2004,53(6):635-647
Effects of jasplakinolide (JSP), a stabilizer of F-actin, and latrunculin A (LTA), a destabilizer of F-actin, on a series of events occurring in the execution phase of staurosporine (STS)-induced apoptotic processes were studied using human osteosarcoma 143B cells. Time-dependent apparent increases of the population of cells with collapsed membrane potential of mitochondria (Delta Psi(m)) caused by STS treatment were not due to actual decreases in the Delta Psi(m) per cell, but due to the fragmentation of cells resulting in decreases in the number of active mitochondria per cell. Decreases in the Delta Psi(m) in fragmented cells occurred late in the execution phase. Both JSP and LAT failed to prevent STS-induced release of cytochrome c from mitochondria followed by the activation of caspases 3 and 9, the cleavage of poly (ADP-ribose) polymerase (PARP) and apoptotic nuclear fragmentation. However, both drugs prevented STS-induced apoptotic cell fragmentation and decreases in the Delta Psi(m). These results indicate that physicochemical states of actin filaments play a certain role in the execution phase of STS-induced apoptotic processes. 相似文献
69.
采用Iodogen法对叶酸-青霉素G酰化酶(Folate-conjugated Penicillin G Amidase,F-PGA)和PGA进行125I标记。将纯化后的标记物由尾静脉注入荷SKOV3实体瘤裸鼠体内,观察F-PGA对叶酸受体阳性的SKOV3的靶向性。结果显示:标记产品纯化后放化纯度>95%,且体内外稳定性较好;荷SKOV3肿瘤的裸鼠注射125I-F-PGA后4~24 h肿瘤显像较清晰,而注射125I-PGA组所有时相均未见明显的肿瘤部位放射性浓聚影;125I-F-PGA组的肿瘤与健侧肌肉的摄取比值(T/M)明显高于对照组(F=13.38,P=0.014 6),且在非靶组织中清除较快。表明F-PGA在荷瘤鼠体内能特异性地与叶酸受体阳性的SKOV3实体肿瘤进行靶向结合,其T/NT>1,有望用于靶向治疗。 相似文献
70.
Mechanical flexing of plastic substrates coated with thin film permeation barriers causes stress-induced cracks that may lead to device degradation. This phenomenon is of particular importance for organic light emitting diodes, an emerging display technology that can be implemented on flexible substrates but imposes stringent requirements on the barrier performance. We demonstrate a dry-etch-based method to highlight cracks in thin films of transparent materials and make them visible under a conventional optical microscope on samples in a neutral, relaxed position. This approach allows for rapid evaluation of the mechanical performance of thin film barriers on flexible substrates. 相似文献