The Effects of Embedded Dipoles in Aromatic Self‐Assembled Monolayers

Using a representative model system, here electronic and structural properties of aromatic self‐assembled monolayers (SAMs) are described that contain an embedded, dipolar group. As polar unit, pyrimidine is used, with its orientation in the molecular backbone and, consequently, the direction of the embedded dipole moment being varied. The electronic and structural properties of these embedded‐dipole SAMs are thoroughly analyzed using a number of complementary characterization techniques combined with quantum‐mechanical modeling. It is shown that such mid‐chain‐substituted monolayers are highly interesting from both fundamental and application viewpoints, as the dipolar groups are found to induce a potential discontinuity inside the monolayer, electrostatically shifting the core‐level energies in the regions above and below the dipoles relative to one another. These SAMs also allow for tuning the substrate work function in a controlled manner independent of the docking chemistry and, most importantly, without modifying the SAM‐ambient interface.     

Nanoimprint Lithography Facilitated Plasmonic-Photonic Coupling for Enhanced Photoconductivity and Photocatalysis

Imprint lithography has emerged as a reliable, reproducible, and rapid method for patterning colloidal nanostructures. As a promising alternative to top-down lithographic approaches, the fabrication of nanodevices has thus become effective and straightforward. In this study, a fusion of interference lithography (IL) and nanosphere imprint lithography on various target substrates ranging from carbon film on transmission electron microscope grid to inorganic and dopable polymer semiconductor is reported. 1D plasmonic photonic crystals are printed with 75% yield on the centimeter scale using colloidal ink and an IL-produced polydimethylsiloxane stamp. Atomically smooth facet, single-crystalline, and monodisperse colloidal building blocks of gold (Au) nanoparticles are used to print 1D plasmonic grating on top of a titanium dioxide (TiO₂) slab waveguide, producing waveguide-plasmon polariton modes with superior 10 nm spectral line-width. Plasmon-induced hot electrons are confirmed via two-terminal current measurements with increased photoresponsivity under guiding conditions. The fabricated hybrid structure with Au/TiO₂ heterojunction enhances photocatalytic processes like degradation of methyl orange (MO) dye molecules using the generated hot electrons. This simple colloidal printing technique demonstrated on silicon, glass, Au film, and naphthalenediimide polymer thus marks an important milestone for large-scale implementation in optoelectronic devices.     

2D van der Waals Heterojunction of Organic and Inorganic Monolayers for High Responsivity Phototransistors

Van der Waals (vdW) heterostructures composing of organic molecules with inorganic 2D crystals open the door to fabricate various promising hybrid devices. Here, a fully ordered organic self-assembled monolayer (SAM) to construct hybrid organic–inorganic vdW heterojunction phototransistors for highly sensitive light detection is used. The heterojunctions, formed by layering MoS₂ monolayer crystals onto organic [12-(benzo[b]benzo[4,5]thieno[2,3-d]thiophen-2-yl)dodecyl)]phosphonic acid SAM, are characterized by Raman and photoluminescence spectroscopy as well as Kelvin probe force microscopy. Remarkably, this vdW heterojunction transistor exhibits a superior photoresponsivity of 475 A W⁻¹ and enhanced external quantum efficiency of 1.45 × 10⁵%, as well as an extremely low dark photocurrent in the pA range. This work demonstrates that hybridizing SAM with 2D materials can be a promising strategy for fabricating diversified optoelectronic devices with unique properties.     

SNR enhancement in radial SSFP imaging using partial k-space averaging

The steady-state free precessing (SSFP) sequences, widely used in MRI today, acquire data only during a short fraction of the repetition time (TR). Thus, they exhibit a poor scan efficiency. In this paper, a novel approach to extending the acquisition window for a given TR without considerably modifying the basic sequence is explored for radial SSFP sequences. The additional data are primarily employed to increase the signal-to-noise ratio, rather than to improve the temporal resolution of the imaging. The approach is analyzed regarding its effect on the image SNR (signal to noise ratio) and the reconstruction algorithm. Results are presented for phantom experiments and cardiac functions studies. The gain in SNR is most notable in rapid imaging, since SNR enhancement for a constant repetition time may be used to compensate for the increase in noise resulting from angular undersampling.     

Analytical model for the first and second moments of an adaptiveinterpolated FIR filter using the constrained filtered-X LMS algorithm

The authors present an analytical model for the mean weight behaviour and weight covariance matrix of an adaptive interpolated FIR filter using the LMS algorithm to adapt the filter weights. The particular structure of this adaptive filter determines that special analytical considerations must be used. First, the introduction of an interpolating block cascaded with the adaptive sparse filter requires that the input signal correlations must be considered. It is well known that such correlations are disregarded by the independence theory, which is the basis for the analysis of the LMS algorithm adapting FIR structures. Secondly a constrained analysis is used to deal mathematically with the sparse nature of the adaptive section. Experimental results demonstrate the effectiveness of the proposed analytical models as compared with the results obtained by classical analysis     

Kraftwerkseigenschaften von Windenergieanlagen hinsichtlich Kurzschlussverhalten, Engpass- und Blindleistungsmanagement sowie Spannungsregelung

The increasing number of wind turbines will lead to new demands for transmission and distribution system control in the years to come. In order to ensure a smooth integration of wind energy into an electrical energy system structure, wind farms will have to possess power plant properties and be able to provide ancillary services. The ENERCON concept offers solutions not only for critical situations, such as short-circuits and bottlenecks in the grid, but also for normal operation, such as reactive power management or voltage control. Wind farms will essentially function in a manner similar to conventional power plants and moreover offer additional advantages in the distribution grid.     

Internet traffic engineering

The main goal of Internet traffic engineering is to efficiently optimize the performance of operational networks in order to avoid the well-known shortcomings of the typical destination-based IP routing. Traffic engineering attempts to reduce or even avoid congestion hot spots and to improve resource utilization across the backbone IP network. During the last years traffic engineering has become an inevitable tool concerning performance optimization in large Internet backbones. The core objective of this paper is to give an overview of the architectures and mechanisms for traffic engineering.     

Nichtlinearer digitaler Reibungsbeobachter zur adaptiven Reibungskompensation bei Bewegungsregelungen

Friction can deteriorate the tracking behavior of motion control. By use of a friction observer an estimated value of the friction can be determined and through adaptive compensation of the friction its influence can be weakened. The following article developes a new digital nonlinear friction observer on ground of an already known continuous nonlinear friction observer, which can easily be parametrized. A mechanical model is used to compare this nonlinear friction observer with a linear one during simulations and real time investigation. The investigation shows that the effect of deterioration of the tracking behavior through friction is less significant with the new digital nonlinear friction observer than with the linear friction observer.     

低温地层钻进特点及其钻井液技术现状综述

在低温地层(主要包括冰层、极地、永冻层以及赋存天然气水合物的永冻层)的钻进对于科学研究和矿产与油气资源的勘探开发都非常重要。介绍了低温地层钻进的国内外研究背景,分析了其钻进特点,对相关的低温钻井液的研究现状和应用情况进行了讨论,对低温地层钻进及其钻井液的研究提出了几点建议。     

Electrical and optical properties of oxygen doped GaN grown by MOCVD using N2O

Oxygen doped GaN has been grown by metalorganic chemical vapor deposition using N₂O as oxygen dopant source. The layers were deposited on 2″ sapphire substrates from trimethylgallium and especially dried ammonia using nitrogen (N₂) as carrier gas. Prior to the growth of the films, an AIN nucleation layer with a thickness of about 300? was grown using trimethylaluminum. The films were deposited at 1085°C at a growth rate of 1.0 μm/h and showed a specular, mirrorlike surface. Not intentionally doped layers have high resistivity (>20 kW/square). The gas phase concentration of the N₂O was varied between 25 and 400 ppm with respect to the total gas volume. The doped layers were n-type with carrier concentrations in the range of 4×10¹⁶ cm⁻³ to 4×10¹⁸ cm⁻³ as measured by Hall effect. The observed carrier concentration increased with increasing N₂O concentration. Low temperature photoluminescence experiments performed on the doped layers revealed besides free A and B exciton emission an exciton bound to a shallow donor. With increasing N₂O concentration in the gas phase, the intensity of the donor bound exciton increased relative to that of the free excitons. These observations indicate that oxygen behaves as a shallow donor in GaN. This interpretation is supported by covalent radius and electronegativity arguments.