Self-assembly of highly oriented palladium-based nanowires on mica surface

The self-assembly of various nanostructures is recently attracting a great deal of research attention. In this paper, we demonstrate that a palladium chloride aqueous solution, mixed with a proper ammonia solution, can produce Tetra-amminepalladous chloride (Pd(NH₃)₄Cl₂·H₂O) nanowires. These nanowires can spontaneously form the two-dimensional hexagon-oriented Pd(NH₃)₄Cl₂·H₂O arrays on mica surfaces. We can control the length and height of these nanowires by adjusting their deposit time on the mica substrate. This method can be potentially used in making sensors or in making templates to wire and position nanodevices.     

The Fabrication and Characterization of Single‐Component Polymeric White‐Light‐Emitting Diodes

By using Ni⁰‐mediated polymerization, we have systematically synthesized a series of fluorene‐based copolymers composed of blue‐, green‐, and red‐light‐emitting comonomers with a view to producing polymers with white‐light emission. 2,7‐Dibromo‐9,9‐dihexylfluorene, {4‐(2‐[2,5‐dibromo‐4‐{2‐(4‐diphenylamino‐phenyl)‐vinyl}‐phenyl]‐vinyl)‐phenyl}‐diphenylamine (DTPA), and 2‐{2‐(2‐[4‐{bis(4‐bromo‐phenyl)amino}‐phenyl]‐vinyl)‐6‐tert‐butyl‐pyran‐4‐ylidene}‐malononitrile (TPDCM) were used as the blue‐, green‐, and red‐light‐emitting comonomers, respectively. It was found that the emission spectra of the resulting copolymers could easily be tuned by varying their DTPA and TPDCM content. Thus with the appropriate red/green/blue (RGB) unit ratio, we were able to obtain white‐light emission from these copolymers. A white‐light‐emitting diode using the polyfluorene copolymer containing 3 % green‐emitting DTPA and 2 % red‐emitting TPDCM (PG3R2) with a structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonic acid)/PG3R2/Ca/Al was found to exhibit a maximum brightness of 820 cd m^–2 at 11 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.35), which are close to the standard CIE coordinates for white‐light emission (0.33,0.33).     

Pioneering e-supply chain integration in semiconductor industry: a case study

Taiwan Semiconductor Manufacturing Company (TSMC) is the largest semiconductor foundry in the world. Advanced Semiconductor Engineering Inc. (ASE) is the world’s leader in semiconductor assembly and testing. From 1998 to 2004, the two companies completed electronic integration of 11 key business processes through the Internet. The result is a seamless interface between TSMC, ASE and their joint customers. They can now obtain accurate, timely information on their product status and respond appropriately when needed. While the direct economic benefits are estimated to be around US$ 10 million through productivity increase over a total investment of about US$ 2 million, the indirect benefits of this initiative could be on the order of US $100 million if the joint customers’ benefits are considered. In collaboration with the RosettaNet organization, TSMC and ASE leveraged their pioneering experiences to define three data exchange standards which can then be widely adopted in the semiconductor industry. This case study is a demonstration of how two leading companies in their respective fields can join forces to make a difference in creating value for the entire semiconductor industry, which in turn benefits society at large. With the momentum continuing to build and the sphere of influence continuing to expand, it is anticipated that TSMC, ASE and the entire sector will upgrade their competitiveness in terms of cost, quality, responsiveness and customer orientation.     

Construction of a prediction model for the structural stability of a surface grinder using backpropagation neural network

Learning and prediction capability of the backpropagation neural network (BPNN) have been used to build the prediction model for the structural stability of a surface grinder. The Lagrange energy method is applied to derive the dynamic equation of the lumped parameter model of the surface grinder. The major factors influencing the structural stability of the system can be determined after the ratio of kinetic energy of the sub-structure and the ratio of potential energy of the sub-structure interface are obtained. An orthogonal rotatable central composite design is adopted to dispose the treatment combinations of the major factors. The BPNN model is constructed by the treatment combinations of the training patterns and verified by the treatment combinations of the test patterns. In this paper, a 3-layer BPNN model with a 10-neuron hidden layer which converged after 4,072 learning cycles is selected to predict the structural stability of a surface grinder within the planned ranges. The percentage residuals of both training patterns and test patterns are all within 3.41%, thus the prediction accuracy of the BPNN model is excellent so that the engineering demands are well satisfied.     

高能球磨FeCo+MnO的结构与磁性研究

用高能球磨采用两种方案制备了FeCo MnO体系,并用X射线衍射和振动样品磁强计对其结构和磁性质做了分析.发现采用直接氧化Mn而得到MnO的方法,所得体系的MnO较纯;而通过分解MnCO3得到MnO的体系,MnO纯度较低,有较多Mn3O4杂质,两种方法制备的FeCo MnO体系的矫顽力和剩磁比都比单纯FeCo体系的增加很多,且前一种方法比后一种方法制备的FeCo MnO体系的矫顽力和剩磁比较大.然后研究了球磨时间及退火处理对FeCo MnO体系矫顽力及剩磁比的影响,发现球磨时间为120h体系的矫顽力和剩磁比最大;经过退火处理后,体系的矫顽力和剩磁比都有较大幅度的增加.     

New multifunction filter using an inverting CCII and a voltagefollower

A new multifunction filter using minimum components is presented. This filter which possesses single input and four outputs can simultaneously generate second-order highpass, bandpass, and lowpass filtering functions at individual output terminals. The filter has the following merits; it uses only two grounded capacitors which makes it suitable for integrated circuit implementation, no matching condition is required, offering multifunction outputs and has low passive and active sensitivities. Experimental results agree very well with the theoretical result     

ID-based non-interactive zero-knowledge proof system based on one-out-of-two non-interactive oblivious transfer

In this paper, we propose an ID-based non-interactive zero-knowledge proof system based on the 1-out-of-2 noninteractive oblivious transfer protocol. This zero-knowledge proof system is secure against a newly discovered cheating attack.     

Performance of GaAs-AlGaAs V-grooved inner stripe quantum-well wirelasers with different current blocking configurations

GaAs-AlGaAs V-grooved inner stripe (VIS) quantum-well wire (QWW) lasers grown by metalorganic chemical vapor deposition with different current blocking configurations, n-blocking on p-substrate (VIPS), p-n-p-n blocking on n-substrate (VI(PN)_nS) and p-blocking on n-substrate (VINS) have been fabricated and characterized. The VIPS QWW lasers show the most stable characteristics with effective current confinement: one of the lasers shows fundamental transverse mode, lasing up to 5 mW/facet, typical threshold current of 39.9 mA at 818.5 mm, an external differential quantum efficiency of 24%/facet, and characteristic temperature of 92 K. The current tuning rate was almost linear at 0.031 mm/mA, and the temperature tuning rate was measured to be 0.14 nm/°C. Comparison of the light output versus current characteristics of the lasers with different current blocking configurations is presented here     

Spray deposition process study of SnO2silicon solar cells using orthogonal experimental design

With the “orthogonal experimental design” (OED), the dependence of conductivity and transparency of tin oxide films and open circuit voltage V_oc of SIS solar cells on the spray deposition process factors was studied. The OED technique was found to be a powerful method for realizing the best factor combination. Using OED, curves were obtained which clearly depict the effects of each factor on the SIS characteristics. The results of the experiments also illustrate exactly which variation in fabrication technique most affects the sheet resistance, V_oc, and film transparency. Under the optimal combination of conditions, a thin film doped with NH₄F was obtained, with about 90% transmission and a sheet resistance of about 80 Ω/□, along with an SIS structure with a V_oc of about 0.61 V.     

P-V-T-C equation for epoxy molding compound

The isothermal and isobaric volume shrinkage is measured by a single-plunger-type dilatometer for epoxy molding compound (EMC). This device has been found suitable for measuring volume change of thermosetting materials such as commercial EMC under isothermal and isobaric conditions. Moreover, the degree of cure (conversion) was determined by a differential scanning calorimetry (DSC). Combining volume change and conversion, a mathematic pressure-volume-temperature-cure (P-V-T-C) model is proposed to describe the relationship between volume shrinkage, pressure, temperature and conversion. The P-V-T-C equation can be simply expressed as VS(P,T,C)=F/sub 1/(P,T)/spl middot/C/sup F2(P,T)/. This equation can well describe historical profiles of volume shrinkage under specified isothermal and isobaric states. From the predicted results, volume shrinkage under different pressure levels in any specified temperature can be approximated as and it obeys the principle of linearity. With the help of this model, together with three-dimensional mold filling simulation, engineers will be able to predict warpage and residual stresses for a package after molding.