Electrocatalytic Reduction of Oxygen on a Pd Ad-Layer Modified Au(111) Electrode in Alkaline Solution

Oxygen reduction was studied on palladium, cadmium and zinc ad-atom modified single crystal Au(111) electrodes. The electrodes were modified by underpotential deposition process and their activity towards oxygen reduction was studied in alkaline media by voltammetry. The reduction peaks obtained were compared with those of bare Au(111), Pd disc and bulk deposited Cd electrodes. Enhanced catalytic activity of the Au(111) electrode in the presence of Pd, Cd and Zn ad-layer can be attributed to a change in surface charge and energy by ad-layer formation. In oxygen saturated medium a well defined sharp reduction peak was observed at ?0.12 V for 1/5 ML Pd ad atom modified Au(111) electrode while it was positioned at ?0.18 V on a Pd disk electrode. The best shift in reduction peak potential was obtained with 2/5 ML Pd ad atom modified Au(111) electrode with similar current density of Pd disc electrode.     

REACTIONS OF METHOXY-SUBSTITUTED AROMATIC COAL MOOELS IN SUPERCRITICAL SOLVENTS

Abstract

Reactions of α- and β-methoxy naphthalene and anisole in supercritical benzene and toluene were studied at 420 °C and 3.9-4.4 MPa pressure. The decomposition of these lower rank coal related model compounds in both solvents was found to obey the first order rate law. While naphthols were present in the reaction mixture of methoxy naphthalenes, phenol and cresoles were present in that of anisole. In addition to these products, diphenyl or dibenzyl was also present in the reaction mixture of supercritical benzene or toluene, respectively. The reactions between models and solvents might be explained by free radical and intermolecular rearrangement reaction pathways.     

Electricity restructuring in Turkey and the share of wind energy production

This paper presents the current status of Turkey's electricity power sector, efforts for introducing competition in the Turkey's power industry, and concerns with the restructuring in Turkey. Turkey include long-term high-cost agreements, low quality of power, and therefore restrictions for synchronization with UCTE network, increase in the reliance on imported natural gas, and the urgent need for highly qualified staff that would be capable of fast and reliable implementation of ongoing reforms in the electricity sector. The contribution of the exploiting wind energy potential in Turkey to reconstruction of Turkey electricity structure is investigated. The strong development of wind energy in Turkey is expected to continue in the coming years.     

Enhanced sludge conditioning by enzyme pre-treatment: comparison of laboratory and pilot scale dewatering results.

The effect of enzyme pre-treatment on dewaterability of anaerobically digested sludge was investigated at both laboratory and pilot scale. Our results revealed a significant increase in cake solid content (27% cake solids compared to 18% without enzyme pre-treatment), using an enzyme dose of only 20 mg/L. In order to assess practical application, enzyme pre-treatment was applied at the Wilmington, Delaware (U.S.) wastewater treatment plant, using a pilot-scale centrifuge. However, the efficiency reached in laboratory scale could not be obtained in pilot scale, where the final cake solids content did not exceed 20%. Centrifuge and belt filter press (simulated by Crown Press) dewatering were compared in terms of the process efficiencies in the absence and presence of enzyme pre-treatment. Possible factors that might cause the differences were tested by experimental and statistical comparisons. Results indicated that the higher shear applied in centrifugation is responsible for the lack of improved cake solids. The network strength of sludge determined by rheological measurements revealed that enzymatic treatment weakens the gel structure of the sludge floc through the hydrolysis of extracellular polymeric substances; this allows improved dewatering by filtration processes, but leads to floc deterioration when subjected to high shear during centrifugation.     

Thin film based semi-active resonant marker design for low profile interventional cardiovascular MRI devices

Objectives

A new microfabrication method to produce low profile radio frequency (RF) resonant markers on catheter shafts was developed. A semi-active RF resonant marker incorporating a solenoid and a plate capacitor was constructed on the distal shaft of a 5 Fr guiding catheter. The resulting device can be used for interventional cardiovascular MRI procedures.

Materials and methods

Unlike current semi-active device visualization techniques that require rigid and bulky analog circuit components (capacitor and solenoid), we fabricated a low profile RF resonant marker directly on guiding the catheter surface by thin film metal deposition and electroplating processes using a modified physical vapor deposition system.

Results

The increase of the overall device profile thickness caused by the semi-active RF resonant marker (130 µm thick) was lowered by a factor of 4.6 compared with using the thinnest commercial non-magnetic and rigid circuit components (600 µm thick). Moreover, adequate visibility performance of the RF resonant marker in different orientations and overall RF safety were confirmed through in vitro experiments under MRI successfully.

Conclusion

The developed RF resonant marker on a clinical grade 5 Fr guiding catheter will enable several interventional congenital heart disease treatment procedures under MRI.

     

A fuzzy long-term investment planning model for a GenCo in a hybrid electricity market considering climate change impacts

We study the long-term generation capacity investment problem of an independent power generation company (GenCo) that functions in an environment where GenCos perform business with both bilateral contracts (BC) and transactions in the day-ahead market (DAM). A fuzzy mixed integer linear programming model with a fuzzy objective and fuzzy constraints is developed to incorporate the impacts of imprecision/uncertainty in the economic environment on the calculation of the optimal value of the GenCo’s objective function. In formulating the fuzzy objective function we also include the potential impacts of climate change on the energy output of hydroelectric power plants. In addition to formulating and solving the capacity planning/investment problem, we also performed scenario-based (sensitivity) analysis to explore how investment decisions of the GenCos change when fuzziness (tolerance) in the maximum energy output of hydroelectric units and/or drought expectation increases. The proposed model is novel and investigates the effects of factors like drought expectations of climate changes, hydroelectric power plant investments, and other power generation technology investment options.     

A Pheromonal Artificial Bee Colony (pABC) Algorithm for Discrete Optimization Problems

ABSTRACT

The Artificial Bee Colony (ABC) algorithm, which simulates the intelligent foraging behavior of the honeybee colony, is one of the most preferred swarm intelligence-based metaheuristic methods for combinatorial optimization problems. In this study, the local search ability of the ABC algorithm, which can be spread to different regions of the solution space, is developed with the pheromone approach of ant colony optimization (ACO). The effects of the method, named pheromonal ABC (pABC), to the standard ABC and its competitiveness with other metaheuristic methods was presented with testing with popular benchmark problems in the NP-hard problem class. For 40 different benchmark problems, while 15 results with ABC have reached the most successful results were obtained in the literature, 25 results obtained with pABC have reached to literature. While ABC best results were behind literature with a percentage of up to 1.12%, pABC best results were behind the percentage of up to 0.63%     

Enabling multi-use, multi-tool models of manufacturing systems through an experimental frame expert system

A significant shortcoming of traditional modeling methodologies is the limited access they provide for decision-makers who are not modeling specialists. This paper presents an expert system approach to address this shortcoming. An expert system called the experimental frame expert system (EFES) was developed for this purpose within an advanced modeling environment for manufacturing systems. EFES reduces the dependence upon modeling specialists, and thus, makes models, both analytical and simulation, more accessible to decision-makers. This is accomplished by using two knowledge bases, one related to the manufacturing system specific symptoms and problems, and the other to system analysis and optimization tools. This paper presents the dissertation research effort that led to development of these two knowledge bases as well as the EFES framework within the advanced modeling environment.     

Assessment of anastomotic reliability with pulse oximetry in graded intestinal ischemia: an experimental study in dogs

BACKGROUND/PURPOSE: Pulse oximetry has been proposed as an appropriate and feasible technique in the assessment of intestinal ischemia in recent years. In this study the authors aimed to assess the reliability of anastomoses in the dog small intestine in which there is graded irreversible ischemia as measured by pulse oxymeter. METHODS: In a control group of four dogs, without any devascularization, three small bowel anastomoses were formed in each dog. The study group consisted of 12 dogs. In each animal three intestinal segments with different levels of ischemia were created by ligating the marginal vessels proximally and distally in sequence beginning from the midpoint of the segmental vascular arcade. Preanastomotic pulse oximeter readings between 80% and 90% were assigned to mild ischemia, 70% and 80% to moderate, and 60% and 70% to severe ischemia group. Pulse oximetry measurements were obtained from probes applied to the antimesenteric serosal surfaces at the midpoint of small intestinal segments. A total of 48 intestinal segments (12 nonischemic in the control group and 36 with three different levels of ischemia in the study group) were transected in the midpoint and anastomosed in double layers. Postanastomotic SaO2 values were also noted. The anastomoses were evaluated 48 hours later macroscopically if there was any leakage, and biopsy specimens were obtained for histopathologic ischemic gradings. All results were studied statistically. RESULTS: Histopathologic grades between each group were statistically different (P < .01 for each comparison) except for control and mild ischemia groups (P > .05), worsening as the level of ischemia increased. Pre- and postanastomotic pulse oximetry measurements correlated very well with the histological gradings (r = -0.90, P < .001 and r = -0.93, P < 0.001 respectively). Number of anastomotic leakages were none in control, one in mild, nine in moderate, and 12 (all of the anastomoses) in severe ischemia groups. In the moderate ischemia group with an average preanastomotic pulse reading of 76.75%, each of the leaking anastomoses had a postanastomotic pulse measurement of lower than 70%. The finding that the difference between histopathologic grades of control and mild ischemia groups with average preanastomotic pulse measurements of 96% and 85%, respectively is not statistically significant enables us to suggest that a saturation of at least 85% is necessary for a reliable anastomosis. CONCLUSION: These results suggest clearly that anastomotic reliability can be predicted objectively with pulse oximetry.