Eu@C86 isomers: Calculated relative populations

Abstract

Relative populations of four energy-lowest IPR (isolated-pentagon-rule) isomers of Eu@C₈₆ are computed using the Gibbs energy based on characteristics from density functional theory calculations (M06-2X/3-21G?～?SDD entropy term, M06-2X/6-31G*～SDD or B2PLYP(D)/6-31G*～SDD energetics). The calculations confirm that the recently isolated Eu@C₁(7)-C₈₆ species is a major isomer in a relevant temperature region. Relationship to the empty C₈₆ cages is discussed, too.     

Quality of Service in VoIP Communication

The focus of this paper lies in the practical aspects of voice over IP communication. VoIP configurations in the H.323 standard will be presented briefly. Following that, the fundamental protocol procedure of H.323 communication will be briefly explained. A further part of the paper will address the subject QoS (quality of service), and present the common measurement methods used in QoS. Results gained from experiments conducted in a VoIP environment will then follow. The investigations concentrate primarily on the load behavior of voice packets in relation to important parameters of this service. The results obtained are presented and evaluated in diagrams. The paper concludes with a summary.     

Applications of the discrete element method in mechanical engineering

Compared to other fields of engineering, in mechanical engineering, the Discrete Element Method (DEM) is not yet a well known method. Nevertheless, there is a variety of simulation problems where the method has obvious advantages due to its meshless nature. For problems where several free bodies can collide and break after having been largely deformed, the DEM is the method of choice. Neighborhood search and collision detection between bodies as well as the separation of large solids into smaller particles are naturally incorporated in the method. The main DEM algorithm consists of a relatively simple loop that basically contains the three substeps contact detection, force computation and integration. However, there exists a large variety of different algorithms to choose the substeps to compose the optimal method for a given problem. In this contribution, we describe the dynamics of particle systems together with appropriate numerical integration schemes and give an overview over different types of particle interactions that can be composed to adapt the method to fit to a given simulation problem. Surface triangulations are used to model complicated, non-convex bodies in contact with particle systems. The capabilities of the method are finally demonstrated by means of application examples. Commemorative Contribution.     

Entschwefelung von gerührtem und ungerührtem Roheisen mit kalkreicher Schlacke unter oxidierender Gasatmosphäre

Aus Betriebsergebnissen bei der Pfannenentschwefelung ist ein negativer Einfluß oxidierender Gasphasen bekannt. Daher war es das Ziel der eigenen Untersuchungen in einer geeigneten Apparatur die Wirkung oxidierender Bedingungen in der Gasphase sowohl auf den Verlauf des Schwefelabbaues in der Schlacke als auch des Schwefeltransportes aus dem Roheisen in die Schlacke zu untersuchen. Oxidierende Gasphasen erwirken bei der Pfannenentschwefelung an der Phasengrenze Schlacke/Gas eine Oxidation des Schwefels aus der Schlacke, ohne jedoch bei ruhender Schlackenschicht ein Oxidationspotential in der Schlacke aufzubauen, das bis zur Phasengrenze Roheisen/Schlacke durchgreift und dort die Entschwefelung des Roheisens durch die Siliciumgehalte stört. Sowohl die Entschwefelung des Roheisens als auch die Oxidation des Schwefels aus der Schlacke werden durch höhere Temperaturen und durch eine Rührwirkung gefördert. Der Schwefeltransport wird bei den ungerührten wie bei den gerührten Schmelzen durch Diffusionsvorgänge gesteuert und auch hier durch steigende Temperaturen und rührende Kräfte begünstigt.     

Das Twinning-Programm der Europäischen Union: Praktische Erfahrungen in der Umsetzung von veterinärmedizinischen Verwaltungspartnerschaften

Zusammenfassung:  Mit Verwirklichung des gemeinsamen Binnenmarktes ab 01.01.1993 wurde ein freier Warenverkehr innerhalb der Europ?ischen Union mit Wegfall zwischenstaatlicher Kontrollen im tiergesundheitlichen und lebensmittelsicher-heitsrelevanten Bereich realisiert. In allen Mitgliedstaaten soll ein vergleichbares Schutzniveau bzgl. des gesundheitlichen Verbraucherschutzes erfüllt werden. In der Praxis hat sich jedoch gezeigt, dass die Anwendung des EU-Rechtes in den neuen Mitgliedstaaten teilweise noch Schwierigkeiten bereitet. Vor diesem Hintergrund sind von der Kommission verschiedene Fortbildungs- und F?rderma?nahmen mit der Zielsetzung entwickelt worden, vorhandene Defizite in diesem Bereich zu minimieren. Dazu z?hlen die seit 1998 von der Kommission initiierten sog. Twinning-Projekte (Verwaltungspartnerschaften) zwischen Beh?rden alter und neuer Mitgliedstaaten. Seit diesem Zeitpunkt wurden mehr als 1100 Twinning-Projekte durchgeführt, davon fast 300 Projekte unter deutscher Leitung (Schwerpunkt: Landwirtschaftlicher Bereich). Im vorliegenden Artikel werden Bedeutung und Inhalte von Twinning-Projekten im Veterin?r- und Lebensmittelbereich dargestellt. Ihr formales Verfahren sowie die in den Verwaltungspartnerschaften gewonnenen Erfahrungen und M?glichkeiten der Verbesserung werden erl?utert.

---

The Twinning-Programme of the European Union: Experiences in the implementation of Twinning- projects in veterinary and food affairs. Since 01.01.1993 a common market was built up within the EU with cancelling of border controls of foods, animal products and living animals. An equal level of consumer protection should be established in all member states. In practice however, implementation of EU food and feed legislation in the new member states often causes problems. To reduce deficiencies in this field, the EU commission developed several measures of training and strenghtening for new member states. These measures include the so called Twinning-projects between competent authorities of old and new member states, which have been initiated since 1998. More than 1100 Twinning projects have been performed so far, including about 300 projects in Germany (with emphasis on agriculture). This article shows meaning and contents of Twinning-projects in the field of veterinary and food affairs. Formal procedures, experiences and possibilities of improvement of twinning-projects are described.

---

---

Eingegangen: 16. Januar 2008     

Zoonotic Brugian lymphadenitis. An unusual case with florid monocytoid B-cell proliferation

Human infection with a zoonotic Brugia species in the United States is uncommon. Positive identification of the filarial nematode is required for histopathologic diagnosis. Many cases may go unrecognized because of the nonspecific clinical manifestations and the nondiagnostic histologic changes occurring in involved lymph nodes. A case of zoonotic Brugia lymphadenitis is described in a patient from Rhode Island, in which a small nongravid female worm was identified in a lymph node biopsy specimen. The lymph node also showed a spectrum of reaction changes including the presence of florid monocytoid B-cell proliferation, which has not been described in association with zoonotic Brugian filariasis.     

Monitoring, removal and risk assessment of cytostatic drugs in hospital wastewater.

Cytostatic agents are applied in cancer therapy and subsequently excreted into hospital wastewater. As these substances are known to be carcinogenic, mutagenic and toxic for reproduction, they should be removed from wastewater at their source of origin.In this study the fate and effects of the cancerostatic platinum compounds (CPC) cisplatin, carboplatin, oxaliplatin, 5-fluorouracil (5-FU) and the anthracyclines doxorubicin, daunorubicin and epirubicin were investigated in hospital wastewater. Wastewater from the in-patient treatment ward of a hospital in Vienna was collected and monitored for the occurrence of the selected drugs. A calculation model was established to spot the correlation between administered dosage and measured concentrations. To investigate the fate of the selected substances during wastewater treatment, the oncologic wastewater was treated in a pilot membrane bioreactor system (MBR) and in downstream advanced wastewater treatment processes (adsorption to activated carbon and UV-treatment). Genotoxic effects of the oncologic wastewater were assessed before and after wastewater treatment followed by a risk assessment.Monitoring concentrations of the selected cytostatics in the oncologic wastewater were in line with calculated concentrations. Due to different mechanisms (adsorption, biodegradation) in the MBR-system 5 - FU and the anthracyclines were removed < LOD, whereas CPC were removed by 60%. In parallel, genotoxic effects could be reduced significantly by the MBR-system. The risk for humans, the aquatic and terrestrial environment by hospital wastewater containing cytostatic drugs was classified as small in a preliminary risk assessment.     

Darstellung komplexer Betriebsschlacken des LD-Verfahrens im Quasidreistoffsystem

Aus der Darstellung der Schlackenzusammensetzungen im Quasidreistoffsystem ist die Lage der Schlacken zur Kalksättigungslinie deutlich zu erkennen. Die Sublanzenschlacken lassen den Schlackenweg während der letzten Blasminuten erkennen, durch Bodenspülung und Nachspülen wird eine geringe Annäherung an die Kalksättigungslinie erreicht. Aus der Lage der Schlacken im Quasidreistoffsystem läßt sich der Einfluß der Temperatur auf den Verlauf der Kalksättigung entlang unterschiedlicher T-X-Schnitte bestimmen.