Chemical cues identify gender and individuality in Giant pandas (Ailuropoda melanoleuca)

The Giant panda communicates with conspecifics by depositing a mixture of volatile compounds (called scent marks) on trees and rocks. Using mass spectrometry, we identified 951 chemical components from scent glands, urine, vaginal secretions, and scent marks made by pandas. The scent marks of the two genders contained a similar array of chemicals but varied in concentration; specifically, males possessed a significantly greater amount of short chain fatty acids (F(1, 29) = 18.4, P = 0.002). Using stepwise discriminate analysis on the relative proportions of a subset of these chemicals, it was possible to classify gender (94% for males and females) and individuality (81% for males and 91% for females) from scent marks. The power to identify individual males was reduced due to the relatedness of two subjects. By cracking the identity code of Giant panda communication, we show insights into how these animals can match individuals with unique chemical profiles. Since radiocollaring is currently banned in China, the techniques described in this paper give field biologists a new means to identify and track pandas in the wild.     

Changes in Ozone Demand of Water During the Treatment Process

The protocol for the measurement of ozone demand of water and the change in the dissolved ozone residual with time, using the Gas Ozone Test (GOT) was applied in monitoring water quality of two water treatment facilities. The change in the ozone concentration of water as a function of time was measured for each sample. The resulting half-time was correlated with the ozone dosage, although this parameter does not appear to be directly linked to the characteristics of the water samples studied. The change in the ozone concentration of water as a function of time and ozone dose, measured by the GOT, has direct applications in the sizing of ozonation reactors.     

IR spectroscopy: Suitable method for determination of curing degree and crosslinking type in melamine–formaldehyde resins

Melamine–formaldehyde (MF) resins are widely used as adhesives and finishing materials in the wood industry. During resin cure, either methylene ether or methylene bridges are formed, leading to the formation of a three-dimensional resin network. Not only the curing degree, but also the chemical species present in the cured resin determine the quality of the final product. Analytical methods allowing a detailed investigation of network formation are of great benefit to manufacturers. In the present work, resin cure of an MF precondensate is studied at different temperatures (100–200 °C) without considering the initial pH as a factor. Isoconversional kinetic analysis based on exothermal curing enthalpies enables calculation of the crosslinking degree at a given time/temperature regime. A semiquantitative determination of the chemical groups present is performed based on solid-state nuclear magnetic resonance data. Fourier transform infrared spectroscopy has shown to be a fast and reliable analytical tool with high sensitivity toward functional groups and with great potential for at-line process control. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47691.     

Isomorphic Implication

We study the isomorphic implication problem for Boolean constraints. We show that this is a natural analog of the subgraph isomorphism problem. We prove that, depending on the set of constraints, this problem is in P, or is NP-complete, or is NP-hard, coNP-hard, and in P_‖^NP. We show how to extend the NP-hardness and coNP-hardness to P_‖^NP-hardness for some cases, and conjecture that this can be done in all cases. Supported in part by grants NSF-CCR-0311021 and DFG VO 630/5-1 and VO 630/5-2. An extended abstract of this paper appears in Proceedings of the 30th International Symposium on Mathematical Foundations of Computer Science (MFCS 2005), pp. 119–130, Springer-Verlag Lecture Notes in Computer Science #3618, August 2005. Work of M. Bauland done in part while visiting CASCI’s Laboratory for Complexity at Rochester Institute of Technology. Work of E. Hemaspaandra done in part while on sabbatical at the University of Rochester.     

Generalized modal satisfiability

It is well known that modal satisfiability is PSPACE-complete (Ladner (1977) [21]). However, the complexity may decrease if we restrict the set of propositional operators used. Note that there exist an infinite number of propositional operators, since a propositional operator is simply a Boolean function. We completely classify the complexity of modal satisfiability for every finite set of propositional operators, i.e., in contrast to previous work, we classify an infinite number of problems. We show that, depending on the set of propositional operators, modal satisfiability is PSPACE-complete, coNP-complete, or in P. We obtain this trichotomy not only for modal formulas, but also for their more succinct representation using modal circuits. We consider both the uni-modal and the multi-modal cases, and study the dual problem of validity as well.     

Algorithms and complexity analysis for some flow problems

Several network-flow problems with additional constraints are considered. They are all special cases of the linear-programming problem and are shown to be -complete. It is shown that the existence of a strongly polynomial-time algorithm for any of these problems implies the existence of such an algorithm for the general linear-programming problem. On the positive side, strongly polynomial algorithms for some parametric flow problems are given, when the number of parameters is fixed. These algorithms are applicable to constrained flow problems when the number of additional constraints is fixed.Work on the paper was done while at Stanford University and IBM Almaden Research Center. This research was partially supported by NSF PYI Grant CCR-8858097.     

Food vacuole proteome of the malarial parasite Plasmodium falciparum

The Plasmodium falciparum food vacuole (FV) is a lysosome-like organelle where erythrocyte hemoglobin digestion occurs. It is a favorite target in the development of antimalarials. We have used a tandem mass spectrometry approach to investigate the proteome of an FV-enriched fraction and identified 116 proteins. The electron microscopy analysis and the Western blot data showed that the major component of the fraction was the FV and, as expected, the majority of previously known FV markers were recovered. Of particular interest, several proteins involved in vesicle-mediated trafficking were identified, which are likely to play a key role in FV biogenesis and/or FV protein trafficking. Recovery of parasite surface proteins lends support to the cytostomal pathway of hemoglobin ingestion as a FV trafficking route. We have identified 32 proteins described as hypothetical in the databases. This insight into FV protein content provides new clues towards understanding the biological function of this organelle in P. falciparum.     

Motor sequencing deficits in schizophrenia: A comparison with Parkinson's disease.

Motor abnormalities occur in schizophrenia (SZ) and may arise from striatal dysfunction. This study examined whether the pattern of performance on simple and complex motor abilities in SZ was similar to that of patients with Parkinson's disease (PD). Quantitative tests of speeded movement and motor and cognitive sequencing were used to assess 25 SZ, 16 PD, and 84 normal controls (NCs). Sequencing performance was also examined with motor rigidity taken into account. Compared with the NC group, the SZ and PD groups were impaired on measures of motor rigidity and motor sequencing. With rigidity accounted for, the SZ group was significantly more impaired than the PD group on motor sequencing; cognitive and motor processes contributed to the motor deficit. Cognitive sequencing performance predicted motor sequencing performance in PD but not SZ. Although both SZ and PD resulted in significant motor and cognitive sequencing deficits, the pattern and correlates of these deficits differ, suggesting that the affected neural systems underlying motor deficits in SZ are different from those involved in PD. (PsycINFO Database Record (c) 2010 APA, all rights reserved)