Coupling hydrothermal liquefaction and aqueous phase reforming for integrated production of biocrude and renewable H2

Lignin-rich stream from lignocellulosic ethanol production was converted into biocrude by continuous hydrothermal liquefaction (HTL) while hydrogen was produced by aqueous phase reforming (APR) of the HTL aqueous by-product. The effects of Na₂CO₃ and NaOH were investigated both in terms of processability of the feedstock as well as yield and composition of the obtained products. A maximum biocrude yield of 27 wt% was reached in the NaOH-catalyzed runs. A relevant amount of dissolved phenolics were detected in the co-produced aqueous phase (AP), and removed by liquid–liquid extraction using butyl acetate or diethyl ether, preserving the APR catalyst stability and reaching an hydrogen yield up to 146 mmol H₂ L⁻¹ AP. Preliminary mass balances integrating HTL and APR showed that the hydrogen provided by APR may account for up to 46% of the hydrogen amount theoretically required for upgrading the HTL biocrude, thus significantly improving the process performance and sustainability.     

Ectropy of diversity measures for populations in Euclidean space

Measures to evaluate the diversity of a set of points (population) in Euclidean space play an important role in a variety of areas of science and engineering. Well-known measures are often used without a clear insight into their quality and many of them do not appropriately penalize populations with a few distant groups of collocated or closely located points. To the best of our knowledge, there is a lack of rigorous criteria to compare diversity measures and help select an appropriate one. In this work we define a mathematical notion of ectropy for classifying diversity measures in terms of the extent to which they tend to penalize point collocation, we investigate the advantages and disadvantages of several known measures and we propose some novel ones that exhibit a good ectropic behavior. In particular, we introduce a quasi-entropy measure based on a geometric covering problem, three measures based on discrepancy from uniform distribution and one based on Euclidean minimum spanning trees. All considered measures are tested and compared on a large set of random and structured populations. Special attention is also devoted to the complexity of computing the measures. Most of the novel measures compare favorably with the classical ones in terms of ectropy. The measure based on Euclidean minimum spanning trees turns out to be the most promising one in terms of the tradeoff between the ectropic behavior and the computational complexity.     

A Procedure to Detect Flaws inside Large Sized Marble Blocks by Ultrasound

In the stone and marble industry there is considerable interest in the possibility of using ultrasound diagnostic techniques for non-destructive testing of large sized blocks in order to detect internal flaws such as faults, cracks, and fissures. In this paper we propose a specific diagnostic procedure for non-invasive, non-destructive quality control of marble blocks. Finally, the structure of a measuring set up specifically designed for in-field use is described and the experimental results are reported and discussed.     

AN ENERGY ANALYSIS OF BELT POLISHING PROCESS AND ITS APPLICATIONS TO TIME CYCLE AND TRACKING EFFECTS

Belt polishing is a fine machining process widely used to improve surface texture and to increase wear resistance and fatigue life. Despite the basics of this manufacturing process are not yet well understood, the cycle-time and the belt oscillations frequency are considered as fundamental process variables. In this article, their effects on the surface characterization and on the form aspects are investigated in connection with the principal physical mechanisms activated during the superfinishing operations (cutting, ploughing and sliding). With this aim, an energy approach of the belt polishing process, coupled with SEM observations of the abrasive belt, is introduced. Two belt polishing energetic regimes are identified and then discussed.     

Determination of metals in wine with atomic spectroscopy (flame-AAS, GF-AAS and ICP-AES); a review

Metals in wine occur at the mg l 1 level or less and, though not directly related to the taste of the final product, their content should be determined because excess is undesirable, and in some cases prohibited, due to potential toxicity. Lead content in wine, for example, is restricted in several states by legislation to guarantee consumer health protection. Of several methods for metal determination, techniques of atomic spectroscopy are the most sensitive and rapid. Most of the elements present in wine can be determined with these techniques, at concentrations ranging from the mg l -1 to the μg l -1 level. Here, inductively coupled plasma-atomic emission spectrometry (ICP-AES), flame atomic absorption spectrometry (flame-AAS) and graphite furnace-atomic absorption spectrometry (GF-AAS) are compared for their characteristics as employed in metal determination in wine.     

Significant improvement of the oxygen permeation flux of tubular Ba0.5Sr0.5Co0.8Fe0.2O3 − δ membranes covered by a thin La0.6Sr0.4Ti0.3Fe0.7O3 − δ layer

We present a new method to improve the oxygen flux properties and stability of Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3 − δ tube membrane using a thin layer of La_0.6Sr_0.4Ti_0.3Fe_0.7O_3 − δ as protective coatings. The first relevant result is that the La_0.6Sr_0.4Ti_0.3Fe_0.7O_3 − δ protective layer had an extraordinary positive effect on improving the oxygen permeation flux of the tubular Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3 − δ membranes. La_0.6Sr_0.4Ti_0.3Fe_0.7O_3 − δ-coated Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3 − δ tubular membrane showed the highest oxygen permeability with the flux reaching ~ 3 ml cm⁻² min⁻¹ (oxygen purity > 99%) at 950 °C in static atmospheric pressure through a 1.0 mm thick membrane.     

Lipid peroxidation and antioxidant status in adults receiving lipid-based home parenteral nutrition

BACKGROUND: Infusion of lipid emulsions rich in polyunsaturated fatty acids (PUFAs) may increase lipid peroxidation, which is counteracted mainly by superoxide dismutase (SOD) (a zinc-, copper-, and manganese-dependent enzyme), selenium-dependent glutathione peroxidase (Se-GSHPx), and alpha-tocopherol. OBJECTIVE: We investigated lipid peroxidation and antioxidant status in patients receiving home parenteral nutrition (HPN) providing variable amounts of a lipid emulsion rich in PUFAs, and alpha-tocopherol, zinc, copper, and manganese as recommended by the American Medical Association, and no selenium. DESIGN: Serum malondialdehyde, plasma alpha-tocopherol, selenium, Se-GSHPx, PUFAs, and red blood cell Se-GSHPx and SOD were evaluated in 12 patients and in 25 healthy control subjects. Malondialdehyde was also assessed in a group of 40 healthy control subjects. RESULTS: Patients had significantly higher concentrations of malondialdehyde and SOD and lower alpha-tocopherol concentrations and selenium nutritional status. Linear regression analysis showed that malondialdehyde was associated with the daily PUFA load (r=0.69, P< 0.03) and with plasma alpha-tocopherol (r=-0.59, P< 0.05), but stepwise multiple regression analysis confirmed only the association between malondialdehyde and alpha-tocopherol; plasma alpha-tocopherol was associated with the daily PUFA load (r=-0.65, P< 0.04) and with the duration of HPN (r=-0.74, P< 0.02). CONCLUSIONS: In HPN patients, the peroxidative stress due to lipid emulsions rich in PUFAs is counteracted primarily by alpha-tocopherol. The dosages of alpha-tocopherol, zinc, copper, and manganese recommended by the American Medical Association appear sufficient to sustain SOD activity but inadequate to maintain alpha-tocopherol nutritional status. HPN formulations should be supplemented with selenium.