High-throughput approach to the catalytic combustion of diesel soot

A methodology for the evaluation of diesel soot oxidation catalysts by high-throughput (HT) screening was developed. The optimal experimental conditions (soot amount, catalyst/soot ratio, type of contact, composition and flow rate of gas reactants) ensuring a reliable and reproducible detection of light-off temperatures in a 16 parallel channels reactor were set up. The temperature profile measured in the catalyst/soot bed under TPO conditions when the exothermic combustion of soot takes place was shown to provide an accurate measurement of the ignition. Its reproducibility and relevance were checked. The results obtained with a reference noble metal free catalyst (La_0.8Cr_0.8Li_0.2O₃ perovskite) agree very well with literature data. Qualitative mechanistic features could be derived from these experiments, stressing the likely limiting step of oxygen transfer from catalyst surface to soot particulates to ignite the soot combustion. Ceria material was shown to be more appropriate than perovskite one. From an HT screening of a large diverse library (over 100 mixed oxides catalysts) under optimized conditions, about 10 new formulations were found to perform better than selected noble metal free reference materials.     

Doping-induced broadening of the hole density-of-states in conducting polymers

The density-of-states distribution in conducting polymers reflects the energy disorder caused by electrostatic and steric interactions resulting from the different environment in which each molecule is placed. In case of p-doping (oxidation), the highest occupied molecular orbital (HOMO) manifold spreads in energy following a distribution as a result of long-range electrostatic (dipolar) interactions with the surrounding disordered host. In this paper the repercussion of the dipolar disorder on electrochemical signals of standard polypyrrole films is explored. The analysis is based on the chemical capacitance variation with the applied potential in experiments performed in quasi-equilibrium conditions. In addition to the Gaussian shape of cyclic voltammograms at low-doping levels, the model is able to qualitatively account for the current plateau usually observed at high oxidation potentials. This approach allows to estimating the dipolar moment associated to the polymer/dopant complex.     

Exploded views for volume data

Exploded views are an illustration technique where an object is partitioned into several segments. These segments are displaced to reveal otherwise hidden detail. In this paper we apply the concept of exploded views to volumetric data in order to solve the general problem of occlusion. In many cases an object of interest is occluded by other structures. While transparency or cutaways can be used to reveal a focus object, these techniques remove parts of the context information. Exploded views, on the other hand, do not suffer from this drawback. Our approach employs a force-based model: the volume is divided into a part configuration controlled by a number of forces and constraints. The focus object exerts an explosion force causing the parts to arrange according to the given constraints. We show that this novel and flexible approach allows for a wide variety of explosion-based visualizations including view-dependent explosions. Furthermore, we present a high-quality GPU-based volume ray casting algorithm for exploded views which allows rendering and interaction at several frames per second.     

A novel humid electronic nose combined with an electronic tongue for assessing deterioration of wine

We report herein the use of a combined system for the analysis of the spoilage of wine when in contact with air. The system consists of a potentiometric electronic tongue and a humid electronic nose. The potentiometric electronic tongue was built with thick-film serigraphic techniques using commercially available resistances and conductors for hybrid electronic circuits; i.e. Ag, Au, Cu, Ru, AgCl, and C. The humid electronic nose was designed in order to detect vapours that emanate from the wine and are apprehended by a moist environment. The humid nose was constructed using a piece of thin cloth sewn, damped with distilled water, forming five hollows of the right size to introduce the electrodes. In this particular case four electrodes were used for the humid electronic nose: a glass electrode, aluminium (Al), graphite and platinum (Pt) wires and an Ag-AgCl reference electrode. The humid electronic nose together with the potentiometric electronic tongue were used for the evaluation of the evolution in the course of time of wine samples. Additionally to the analysis performed by the tongue and nose, the spoilage of the wines was followed via a simple determination of the titratable (total) acidity.     

Illustrative context-preserving exploration of volume data

In volume rendering, it is very difficult to simultaneously visualize interior and exterior structures while preserving clear shape cues. Highly transparent transfer functions produce cluttered images with many overlapping structures, while clipping techniques completely remove possibly important context information. In this paper, we present a new model for volume rendering, inspired by techniques from illustration. It provides a means of interactively inspecting the interior of a volumetric data set in a feature-driven way which retains context information. The context-preserving volume rendering model uses a function of shading intensity, gradient magnitude, distance to the eye point, and previously accumulated opacity to selectively reduce the opacity in less important data regions. It is controlled by two user-specified parameters. This new method represents an alternative to conventional clipping techniques, sharing their easy and intuitive user control, but does not suffer from the drawback of missing context information     

Annotation of multiword expressions in the Prague dependency treebank

We describe annotation of multiword expressions (MWEs) in the Prague dependency treebank, using several automatic pre-annotation steps. We use subtrees of the tectogrammatical tree structures of the Prague dependency treebank to store representations of the MWEs in the dictionary and pre-annotate following occurrences automatically. We also show a way to measure reliability of this type of annotation.     

Optimal search path for service in the presence of disruptions

We consider the following basic search path problem: a customer residing at a node of a network needs to obtain service from one of the facilities; facility locations are known and fixed. Facilities may become inoperational with certain probability; the state of the facility only becomes known when the facility is visited. Customer travel stops when the first operational facility is found. The objective is to minimize the expected total travel distance.     

The slope of a transfer function

Exact and approximate equations are derived that relate the magnitude slope of a general transfer function directly to its phase angle. The result is used to derive simple conditions on stabilizability of feedback loops with right half-plane poles and zeros or dead-time.     

Effect of Density and Processing Conditions on Oxide Transformations and Mechanical Properties in Cr–Mo-Alloyed PM steels

To improve the mechanical properties and performances of water-atomized powder metallurgy steels, it is necessary to enhance the density. Consolidating water-atomized steel powders via conventional pressing and sintering to a relative density level > 95 pct involves processing challenges. Consolidation of gas-atomized powders to full density by hot isostatic pressing (HIP) is an established process route but utilizing water-atomized powders in HIP involves challenges that result in the formation of prior particle boundaries due to higher oxygen content. In this study, the effect of density and processing conditions on the oxide transformations and mechanical properties from conventional press and sintering, and HIP are evaluated. Hence, water-atomized Cr–Mo-alloyed powder is used and consolidated into different density levels between 6.8 and 7.3 g cm⁻³ by conventional die pressing and sintering. Fully dense material produced through HIP is evaluated not only of mechanical properties but also for microstructural and fractographic analysis. An empirical model based on power law is fitted to the sintered material properties to estimate and predict the properties up to full density at different sintering conditions. A model describing the mechanism of oxide transformation during sintering and HIP is proposed. The challenges when it comes to the HIP of water-atomized powder are addressed and the requirements for successful HIP processing are discussed.

     

The impact of nuclear analysis on ITER design and licensing

The complexity of nuclear analysis on the design components of ITER is discussed. These analyses include the determination of several nuclear responses and it is shown that these results are not only relevant to the component under examination but have implications for the design of many other, often remote, systems. The contribution of nuclear analysis to the licensing process is discussed. An example is given of how this complexity means that the there is a large set of complementary analyses required to address the concerns of the licensing authorities. It also means that the nuclear analysis must be co-ordinated to ensure that the results are self-consistent and provide an integrated solution.