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991.
Controlling the Functional Properties of Oligothiophene Crystalline Nano/Microfibers via Tailoring of the Self‐Assembling Molecular Precursors
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Francesca Di Maria Mattia Zangoli Massimo Gazzano Eduardo Fabiano Denis Gentili Alberto Zanelli Andrea Fermi Giacomo Bergamini Davide Bonifazi Andrea Perinot Mario Caironi Vittorio Morandi Giuseppe Gigli Andrea Liscio Giovanna Barbarella 《Advanced functional materials》2018,28(32)
Oligothiophenes are π‐conjugated semiconducting and fluorescent molecules whose self‐assembly properties are widely investigated for application in organic electronics, optoelectronics, biophotonics, and sensing. Here an approach to the preparation of crystalline oligothiophene nano/microfibers is reported based on the use of a “sulfur overrich” quaterthiophene building block, ? T4S4 ? , containing in its covalent network all the information needed to promote the directional, π–π stacking‐driven, self‐assembly of Y‐T4S4‐Y oligomers into fibers with hierarchical supramolecular arrangement from nano‐ to microscale. It is shown that when Y varies from unsubstituted thiophene to thiophene substituted with electron‐withdrawing groups, a wide redistribution of the molecular electronic charge takes place without substantially affecting the aggregation modalities of the oligomer. In this way, a structurally comparable series of fibers is obtained having progressively varying optical properties, redox potentials, photoconductivity, and type of prevailing charge carriers (from p‐ to n‐type). With the aid of density functional theory (DFT) calculations, combined with powder X‐ray diffraction data, a model accounting for the growth of the fibers from molecular to nano‐ and microscale is proposed. 相似文献
992.
The quest for more efficient energy-related technologies is driving the development of porous and high-performance structural materials with exceptional mechanical strength. Natural materials achieve their strength through complex hierarchical designs and anisotropic structures that are extremely difficult to replicate synthetically. We emulate nature's design by direct-ink-write assembling of glass scaffolds with a periodic pattern, and controlled sintering of the filaments into anisotropic constructs similar to biological materials. The final product is a porous glass scaffold with a compressive strength (136 MPa) comparable to that of cortical bone and a porosity (60%) comparable to that of trabecular bone. The strength of this porous glass scaffold is ~100 times that of polymer scaffolds and 4-5 times that of ceramic and glass scaffolds with comparable porosities reported elsewhere. The ability to create both porous and strong structures opens a new avenue for fabricating scaffolds for a broad array of applications, including tissue engineering, filtration, lightweight composites, and catalyst support. 相似文献
993.
Novotny EH deAzevedo ER Bonagamba TJ Cunha TJ Madari BE de M Benites V Hayes MH 《Environmental science & technology》2007,41(2):400-405
The compositions of humic acids (HAs) isolated from cultivated and forested "Terra Preta de Indio" or Amazonian Dark Earth soils (anthropogenic soils) were compared with those from adjacent non-anthropogenic soils (control soils) using elemental and thermogravimetric analyses, and a variety of solid-state nuclear magnetic resonance techniques. The thermogravimetric index, which indicates the molecular thermal resistance, was greater for the anthropogenic soils than for the control soils suggesting polycyclic aromatic components in the former. The cultivated anthropogenic soils were more enriched in C and depleted in H than the anthropogenic soils under forest, as the result of the selective degradation of aliphatic structures and the possible enrichment of H-deficient condensed aromatic structures. The combination of variable amplitude cross-polarization (VACP) and chemical shift anisotropy with total suppression of spinning sidebands experiments with composite pi pulses could be used to quantify the aromaticity of the HAs from the anthropogenic soils. From principal component analysis, using the VACP spectra, it was possible to separate the different constituents of the HAs, such as the carboxylated aromatic structures, from the anthropogenic soils and plant derived compounds. The data show that the HAs from anthropogenic soils have high contents of aryl and ionisable oxygenated functional groups, and the major functionalities from adjacent control soils are oxygenated functional groups from labile structures (carbohydrates, peptides, and with evidence for lignin structures). The anthropogenic soils HAs can be considered to be more recalcitrant, and with more stable reactive functional groups which may, in part, explain their more sustainable fertility due to the organic matter contribution to the soil cation exchange capacity. 相似文献
994.
Inhibitors of lactic acid fermentation in Spanish-style green olive brines of the Manzanilla variety
Eduardo Medina Concepcin Romero Antonio de Castro Manuel Brenes Aranzazu García 《Food chemistry》2008,110(4):932-937
Frequently, a delay or lack of lactic acid fermentation occurs during the processing of Spanish-style green olives, in particular of the Manzanilla variety. Many variables can affect the progress of fermentation such as temperature, nutrients, salt concentration, antimicrobials in brines, and others. In this study, it was demonstrated that an inappropriate alkaline treatment (low NaOH strength and insufficient alkali penetration) allowed for the presence of several antimicrobial compounds in brines, which inhibited the growth of Lactobacillus pentosus. These substances were the dialdehydic form of decarboxymethyl elenolic acid either free or linked to hydroxytyrosol and an isomer of oleoside 11-methyl ester. Olive brines, from olives treated with a NaOH solution of low concentration up to 1/2 the distance to the pit, contained these antimicrobials, and no lactic acid fermentation took place in them. By contrast, a more intense alkaline treatment (2/3 lye depth penetration) gave rise to an abundant growth of lactic acid bacteria without any antimicrobial in brines. Therefore, the precise cause of stuck fermentation in Manzanilla olive brines was demonstrated for the first time and this finding will contribute to better understand the table olive fermentation process. 相似文献
995.
Eduardo Rodríguez-Sandoval Alejandro Fernández-Quintero Angélica Sandoval-Aldana Gerard Cuvelier & Luis A. Bello-Peréz 《International Journal of Food Science & Technology》2009,44(1):138-144
The influence of water (60–70%) and salt (1–2%) content on the viscoelastic properties of cassava dough, reconstituted from cooked flour, was studied using a controlled strain rheometer. Reconstituted cassava dough behaved as a solid-like material with the storage modulus (G') predominant over the loss modulus (G"). As the water content was increased, G' decreased and G" increased; but tan δ was practically independent of the water content. This behaviour suggested that water had plasticising effects, but probably did not change dough structure. The effect of salt content on the dynamic rheological properties of cassava dough was not significant, except for G" values at water contents close to 60%. 相似文献
996.
Eduardo Molina Laszlo Horvath Marshall S. White 《Packaging Technology and Science》2018,31(10):653-663
Considering the effect of packages during pallet design will reduce costs and improve the sustainability of supply chains. Currently, many mechanical interactions between the pallet and the package product are not being considered during the pallet design process. This study investigates the effect of the magnitude and type of interlocking between layers of packaged products. The bending of the pallet supporting a unit load of corrugated boxes was measured under four common support conditions, warehouse rack storage spanning the pallet width and length, fork tine support across the pallet width, and floor stacking. Five different pallet stacking patterns were analyzed from column stacking to fully interlocked stacking. It was determined that interlocking packages reduces pallet deflection up to 53%. This is more significant for lower stiffness pallets and when the payload carried by the pallet is greater than the rated load capacity of the pallet. Increasing the magnitude of the interlocking reduces the deflection of the pallet by 11.6%. These results provide a guideline on improving pallet design and help further the understanding of the interaction between pallets and the orientation of packaged products placed on the pallet. 相似文献
997.
998.
999.
Eduardo Ruiz-Pesini María Pilar Bayona-Bafaluy Teresa Sanclemente Jos Puzo Julio Montoya David Pacheu-Grau 《International journal of molecular sciences》2023,24(1)
Heredity of familial hypercholesterolemia (FH) can present as a dominant monogenic disorder of polygenic origin or with no known genetic cause. In addition, the variability of the symptoms among individuals or within the same families evidence the potential contribution of additional factors than monogenic mutations that could modulate the development and severity of the disease. In addition, statins, the lipid-lowering drugs which constitute the first-line therapy for the disease, cause associated muscular symptoms in a certain number of individuals. Here, we analyze the evidence of the mitochondrial genetic variation with a special emphasis on the role of CoQ10 to explain this variability found in both disease symptoms and statins side effects. We propose to use mtDNA variants and copy numbers as markers for the cardiovascular disease development of FH patients and to predict potential statin secondary effects and explore new mechanisms to identify new markers of disease or implement personalized medicine strategies for FH therapy. 相似文献
1000.
Real-world data are often prepared for purposes other than data mining and machine learning and, therefore, are represented by primitive attributes. When data representation is primitive, preprocessing data before looking for patterns becomes necessary. The low-level primitive representation of real-world problems facilitates the existence of complex interactions among attributes. If lack of domain experts prevents traditional methods to uncover patterns in data due to complex attribute interactions, then the use of soft computing techniques such as genetic algorithms becomes necessary. This article introduces MFE3/GADR, a data reduction method derived from the learning preprocessing system MFE3/GA. The method restructures the primitive data representation by capturing and compacting hidden information into new features in order to highlight regularities to the learner. We thoroughly analyze the empirical results obtained on the poker hand data set. The results show that this approach successfully compacts the set of low-level primitive attributes into a smaller set of highly informative features which outline patterns to the learner; thus, the new approach provides data reduction and yields learning a smaller and more accurate classifier. 相似文献